☆ 4.7 Review

Recent technologies for glyphosate removal from aqueous environment: A critical review

ENVIRONMENTAL RESEARCH (2024)

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Opportunities and challenges for harvest weed seed control in European cropping systems

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Summary: The paper investigates the potential and challenges of using harvest weed seed control (HWSC) as an alternative non-chemical weed control strategy in Europe. Initial research in Europe has identified several weed species suitable for HWSC, but there are challenges such as inconsistent crop and weed maturity. Further research and development are needed to evaluate and promote the practical adoption of HWSC strategies in European cropping systems.

EUROPEAN JOURNAL OF AGRONOMY (2023)

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Article Green & Sustainable Science & Technology

A combined precipitation-adsorption method for harmless treatment of glyphosate mother liquor

Zhanhui Li et al.

Summary: A combined method of precipitation and resin adsorption was used for the harmless treatment of glyphosate mother liquor. Metal ions of Ca2+ were used for precipitation of phosphorous-based compounds, and 001*7 and D301 resins were used for the removal of excess metal ions and remaining phosphorous compounds. The proposed technology showed great potential in the glyphosate production industry by achieving effective removal of phosphorous compounds and meeting industrial wastewater discharge standards.

JOURNAL OF CLEANER PRODUCTION (2023)

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Article Engineering, Environmental

Design and experimental validation of an optimized microalgae-bacteria consortium for the bioremediation of glyphosate in continuous photobioreactors

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Summary: In this study, a bacterial consortium was designed to remove glyphosate from polluted water with the support of oxygen produced by a microalgal species. The designed consortium demonstrated its ability to adapt to different concentrations of glyphosate and effectively remove it from water.

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Article Environmental Sciences

Global warming and glyphosate toxicity (II): Offspring zebrafish modelling with behavioral, morphological and immunohistochemical approaches

Ekrem Sulukan et al.

Summary: The increase in temperature due to global warming affects the toxicity of pesticides in the aquatic ecosystem, particularly in terms of the sustainability of ecosystems. This study investigated the effects of parental exposure to glyphosate and temperature increase on the next generation using a zebrafish model. The results showed that the offspring exhibited lower survival rate, delayed hatching, increased body malformations, and lower blood flow and heart rate.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

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Article Engineering, Environmental

Enhanced removal of trace pesticides and alleviation of membrane fouling using hydrophobic-modified inorganic-organic hybrid flocculants in the flocculation-sedimentation-ultrafiltration process for surface water treatment

Yunyun Li et al.

Summary: This study evaluated the performance of a new type of water flocculant in removing four different pesticides from Yangtze River water and mitigating membrane fouling. The results showed that the water flocculant had efficient pesticide removal capabilities and reduced membrane fouling, outperforming traditional inorganic coagulants.

WATER RESEARCH (2023)

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Article Chemistry, Multidisciplinary

Glyphosate Adsorption from Water Using Hierarchically Porous Metal-Organic Frameworks

Shaghayegh Naghdi et al.

Summary: Selective removal of one ligand in mixed-ligand MOFs creates hierarchical pore architectures with improved adsorption capacity for glyphosate removal from water. The Ti-OH groups resulting from ligand removal serve as effective anchor points for glyphosate uptake. The introduction of additional mesopores has significantly increased the adsorption capacities, making these MOFs among the best-reported adsorbents.

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Article Environmental Sciences

Application of a novel hybrid MIL-53(Al)@rice husk for the adsorption of glyphosate in water: Characteristics and mechanism of the process

Luis Angel Zambrano-Intriago et al.

Summary: The aim of this study was to investigate the potential of the hybrid material MIL-53(Al)@RH for the adsorption of glyphosate in aqueous solution. The results showed that a maximum adsorption capacity of 296.95 mg g(-1) was achieved in 30 min with a ratio of 0.04 g MIL-53(Al)@RH/50 mL of solution at pH(0) 4. The adsorption kinetics and equilibrium were appropriately described by Avrami and pseudo-second order models, and Langmuir and Sips models respectively. Hydrogen bonds, pi*-pi interactions, and complexation between the metal centers of MIL-53(Al) and the anionic groups of glyphosate were postulated as the adsorption mechanisms.

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Removal of glyphosate from aqueous solution by CuO coated MIL-101(Fe)

Dongmei Jia et al.

Summary: In this study, CuO coated MIL-101(Fe) composite material was successfully prepared and characterized. The results showed that the composite material had good pH adaptivity and high selectivity for adsorption, enabling efficient removal of glyphosate within a short time. The enhanced adsorption performances of the composite material may be attributed to the coordination interaction between CuO and glyphosate.

CANADIAN JOURNAL OF CHEMICAL ENGINEERING (2023)

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Review Microbiology

Bioremediation of the herbicide glyphosate in polluted soils by plant-associated microbes

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Summary: Most productive lands rely on glyphosate-resistant plants for crop production, leading to environmental issues. Soil bioremediation technologies utilizing microorganism degradation of glyphosate have been explored as potential solutions. Recently, the use of bacteria that interact with plants has been considered for the removal of glyphosate herbicide, offering additional benefits such as plant growth promotion.

CURRENT OPINION IN MICROBIOLOGY (2023)

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Review Environmental Sciences

A review of PFAS adsorption from aqueous solutions: Current approaches, engineering applications, challenges, and opportunities

Xiaobo Lei et al.

Summary: Per- and polyfluoroalkyl substances (PFAS) have attracted significant attention due to their widespread presence in water bodies and harmful effects on human health. Adsorption is a promising treatment technique for meeting the stringent environmental and health standards for PFAS. This paper provides a systematic review of current approaches to PFAS adsorption using different adsorbents in drinking water and wastewater. Adsorbents with large mesopores and high specific surface area exhibit faster and more effective PFAS adsorption under low pH conditions. The mechanisms of PFAS adsorption include electrostatic attraction, hydrophobic interaction, anion exchange, and ligand exchange. However, challenges such as organic solvent requirements for regeneration, low adsorption selectivity, and complicated adsorbent preparations need to be addressed before large-scale implementation. The use of decision-making tools such as response surface methodology, techno-economic assessment, life cycle assessment, and multicriteria decision analysis is recommended for engineering applications to determine the economic feasibility and sustainability of specific adsorption processes.

ENVIRONMENTAL POLLUTION (2023)

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MOF-based composites as photoluminescence sensing platforms for pesticides: Applications and mechanisms

Romina Yousefi et al.

Summary: Metal-organic frameworks (MOFs) have gained significant attention for their unique properties and applications in sensing toxic compounds. This article focuses on MOF-based fluorescence sensors for specific detection of hazardous compounds, particularly pesticides, in order to meet the continuous demands for monitoring environmental pollution. It discusses recent advances in MOF-based platforms for pesticide fluorescence detection, including the influence of guest incorporation in MOFs and the potential of novel MOF composites for fluorescence sensing. The article also highlights the mechanistic insights of specific detection techniques in food safety and environmental protection.

ENVIRONMENTAL RESEARCH (2023)

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Roles of reactive species in photocatalysis: effect of scavengers and inorganic ions on dye removal from wastewater

A. Ahmadian et al.

Summary: This study investigates the incorporation of zinc oxide nanoparticles onto activated carbon from banana peel in order to enhance the photocatalytic degradation of Acid Blue 25. The results show that cation Al3+ and anion NO3- have the strongest inhibition effect on the photocatalytic degradation.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2023)

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Article Green & Sustainable Science & Technology

Efficient adsorption of ammonia on activated carbon from hydrochar of pomelo peel at room temperature: Role of chemical components in feedstock

Fei Zhu et al.

Summary: This study investigated the effect of chemical components (cellulose, xylan, pectin, and lignin) on the physicochemical properties and adsorption performance of activated carbon derived from pomelo peel. The results showed that lignin-added activated carbon had the highest adsorption capacity, followed by cellulose-added and xylan-added activated carbon. These findings provide insights into the correlations between the feedstock components and the ammonia adsorption styles of activated carbon, which can guide the selection of appropriate materials for efficient ammonia removal.

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To tax or to ban? A discrete choice experiment to elicit public preferences for phasing out glyphosate use in agriculture

Amalie Bjornavold et al.

Summary: In 2023, the European Union will vote on the reauthorization of glyphosate use, and our study investigated citizens' preferences for phasing out glyphosate. While the general public initially supported a ban, our experimental results showed a preference for earmarked taxation schemes that led to a strong reduction in glyphosate use with a smaller increase in food price compared to a ban. This suggests that when weighing glyphosate reduction against its costs, a tax may be a preferred alternative to a ban.

PLOS ONE (2023)

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Glyphosate, glufosinate ammonium, and AMPA occurrences and sources in groundwater of hilly vineyards

Nicoleta Suciu et al.

Summary: Monitoring and modeling results indicate the high concentrations of glyphosate and its degradation product AMPA in groundwater in Italian vineyards, possibly due to agricultural practices and water source contamination. This study highlights the importance of groundwater monitoring and suggests strategies to mitigate contamination drivers.

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A comprehensive review of recent advances in the synthesis and application of metal-organic frameworks (MOFs) for the adsorptive sequestration of pollutants from wastewater

Andrew Nosakhare Amenaghawon et al.

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Large-Scale Agriculture and Environmental Pollution of Ground and Surface Water and Sediment by Pesticides in the Brazilian Amazon: the Case of the Santarem Region

Moema Guimaraes de Azeredo Morgado et al.

Summary: The current development model of agriculture in Brazil may lead to negative environmental impacts, including pollution of aquatic ecosystems. A study in the Santarem region of the Brazilian Amazon found pesticide residues in water and sediment samples near large soybean crops. The presence of herbicides and organochlorine insecticides suggests the need for further research on the pollution effects of large-scale soybean crops on the Amazon rainforest.

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Article Microbiology

Characterization of a New Pseudomonas Putida Strain Ch2, a Degrader of Toxic Anthropogenic Compounds Epsilon-Caprolactam and Glyphosate

Tatiana Z. Esikova et al.

Summary: In this work, a new strain named Ch2 was isolated from polluted soils and found to have the unique capability of utilizing toxic compounds like CAP and GP as carbon and energy sources. Analysis of Ch2's 16S rRNA gene revealed its belonging to the Pseudomonas putida species. The strain could degrade CAP through a megaplasmid, and intensive GP utilization occurred during active growth with unique changes in the cytoplasm, indicating the potential role of metabolosomes. Additionally, Ch2 showed the ability to produce PHAs, highlighting its potential in bioremediation and the production of bioplastics.

MICROORGANISMS (2023)

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Article Environmental Sciences

Herbicides in Water Sources: Communicating Potential Risks to the Population of Mangaung Metropolitan Municipality, South Africa

Innocent Mugudamani et al.

Summary: High concentrations of herbicides, particularly simazine, were detected in rivers, dams/reservoirs, and treated drinking water in Mangaung Metropolitan Municipality, South Africa. The presence of these pollutants poses significant ecological and human health risks. This study emphasizes the need for pesticide pollution management and risk reduction strategies in the municipality.

TOXICS (2023)

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Recent advances in advanced oxidation processes (AOPs) for the treatment of nitro- and alkyl-phenolic compounds

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Summary: The presence of phenolic compounds in water poses severe risks, and nitro- and alkyl-phenolic compounds have been categorized as precedence contaminants by the US EPA. Therefore, efficient treatment methods for wastewater containing these compounds are urgently needed.

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The politics of expertise in assessing alternatives to glyphosate in France

Fiona Kinniburgh

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Article Agricultural Engineering

Production of biochar and activated carbon from oil palm biomass: Current status, prospects, and challenges

Mohd Rafein Zakaria et al.

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Article Engineering, Environmental

Adsorption of glyphosate and metabolite aminomethylphosphonic acid (AMPA) from water by polymer-based spherical activated carbon (PBSAC)

Phuong Bich Trinh et al.

Summary: Glyphosate and its main metabolite, aminomethylphosphonic acid, are commonly found in ground and surface waters, causing human diseases. Polymer-based spherical activated carbon has shown efficient adsorption of these pollutants, overcoming the limitations of traditional treatment methods. The study demonstrates that the size, activation level, and surface charge of the polymer-based spherical activated carbon greatly influence the removal efficiency. The pH and temperature also play important roles in the adsorption process. While the European guideline concentration for glyphosate can be met, the required level of aminomethylphosphonic acid removal could not be achieved.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Article Environmental Sciences

In situ growth of NH2-MIL-101 metal organic frameworks on biochar for glyphosate adsorption

Qi Wang et al.

Summary: Researchers developed a new adsorbent by growing NH2-MIL-101 metal-organic framework on biochar derived from waste rice husk to remove glyphosate in solution. The modified amino group improved the adsorption performance of the material significantly. The maximum adsorption capacity of the adsorbent for PMG was 186.71 mg g-1, and the PMG adsorption occurred through ligand exchange and inner-sphere surface complex formation. Rating: 8 out of 10.

CHEMOSPHERE (2023)

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Article Engineering, Environmental

Glyphosate adsorption performances of polymer-derived SiC/C aerogels

Andrea Zambotti et al.

Summary: This paper presents the synthesis of a nanocrystalline silicon carbide aerogel for removing glyphosate from polluted water. The aerogel was synthesized using allylhydridopolycarbosilane as a precursor and showed a high specific surface area of 215 m(2)center dot g(-1) after pyrolysis at 1500 degrees C. Testing on glyphosate herbicide revealed a remarkable adsorption of 0.607 mg center dot g(-1) and a removal of 93% of the pollutant in solution. The Elovich kinetics adsorption and Langmuir isotherm models were found to accurately describe the mechanism of glyphosate capture.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

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Article Environmental Sciences

Ferrihydrite-loaded water hyacinth-derived biochar for efficient removal of glyphosate from aqueous solution

Wenchao Meng et al.

Summary: Ferrihydrite-loaded water hyacinth-derived biochar (FH/WHBC) prepared by in-situ precipitation method showed a high adsorption capacity (116.8 mg/g) for glyphosate in wastewater treatment. The FH/WHBC maintained excellent adsorption performance under high acidity and presence of co-existing ions. It also demonstrated good regenerability and maintained high removal efficiency for glyphosate, reducing its concentration to a level lower than the Chinese groundwater quality standard. The adsorption mechanism was primarily attributed to electrostatic adsorption and the formation of inner-sphere complexes.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

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Article Environmental Sciences

Adsorption of 2,4-dichlorophenoxyacetic acid and glyphosate from water by Fe3O4-UiO-66-NH2 obtained in a simple green way

Xiaoting Zhang et al.

Summary: In this study, a green adsorbent (Fe3O4-UiO-66-NH2) was synthesized using a co-precipitation method and showed excellent adsorption performance for 2,4-D and GP. The adsorbent demonstrated a wide pH range, high salt tolerance, and good regeneration performance. It can effectively remove 2,4-D and GP from water.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

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Review Environmental Sciences

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Sewoon Kim et al.

Summary: Adsorption-membrane hybrid systems are effective in removing contaminants from water, but further research is needed to understand the removal mechanisms and effects of operating conditions on contaminant transport.

CHEMOSPHERE (2022)

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Article Chemistry, Multidisciplinary

Adsorption behavior and adsorption mechanism of glyphosate in water by amino-MIL-101(Fe)

Ruijie Liu et al.

Summary: Two metal-organic framework (MOF) materials, MIL-101(Fe) and amine-modified MIL-101(Fe), have been synthesized and evaluated for glyphosate adsorption in eutrophic water. NH2-MIL-101(Fe) shows enhanced adsorption properties and selectivity for the phosphate group of glyphosate in weakly acidic media, indicating the improvement by NH2 groups. The adsorption mechanism on MIL-101(Fe) has been proposed based on Fourier-transform infrared (FTIR) spectra and zeta potential measurements.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2022)

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Article Environmental Sciences

Application of chemical coagulation to phosphorus removal from glyphosate wastewater

D. Liu et al.

Summary: The study showed that phosphorus can be efficiently recovered from glyphosate-rich wastewater through chemical coagulation.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2022)

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Article Biochemistry & Molecular Biology

Isolation of a degrading strain of Fusarium verticillioides and bioremediation of glyphosate residue

Jing Guo et al.

Summary: Glyphosate-resistant fungus Fusarium verticillioides was found and characterized in this study. It could grow in a medium containing glyphosate and its epsps gene was cloned, which showed low expression levels and belonged to class I genes naturally sensitive to glyphosate. Additionally, the strain C-2 was highly effective in degrading glyphosate and could be potentially used for bioremediation of contaminated soil.

PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY (2022)

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Review Environmental Sciences

Microbial bioremediation strategies with wastewater treatment potentialities - A review

Muhammad Usama Saeed et al.

Summary: The demand for innovative waste treatment techniques has increased due to strict waste discharge guidelines. Wastewater treatment is a significant process, requiring high activities and densities of microorganisms. Improperly treated waste from the pharmaceutical industry has harmful impacts on the environment and public health. Bioremediation utilizing microorganisms is a promising technology to remove heavy metals from polluted water and soil. Microorganisms play a crucial role in heavy metal bioremediation. The use of microorganisms in nanoparticle synthesis can reduce industry expenses and contribute to sustainable production.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Microbiology

Isolation and optimization of a glyphosate-degrading Rhodococcus soli G41 for bioremediation

Ngoc Tuan Nguyen et al.

Summary: This study isolated a bacteria strain capable of efficiently degrading glyphosate and optimized its degradation conditions. The results showed that the strain has the potential to serve as an in-situ candidate for bioremediation of glyphosate-polluted environments.

ARCHIVES OF MICROBIOLOGY (2022)

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Article Environmental Sciences

Photocatalytic oxidation of glyphosate and reduction of Cr(VI) in water over ACF-supported CoNiWO4-gCN composite under batch and flow conditions

Umair Alam et al.

Summary: Photocatalytic treatment of wastewater using nanomaterials is an efficient energy saving technology. In this study, CNW-gCN/ACF nanocomposite is synthesized and used as a photo catalyst for efficient removal of glyphosate and Cr(VI) from water. The photocatalytic efficiency of CNW-gCN/ACF in the simultaneous removal of both pollutants from co-contaminated feed is found to be greater than that in single feed system under identical experimental conditions.

CHEMOSPHERE (2022)

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Article Environmental Sciences

Developmental toxicity of glyphosate on embryo-larval zebrafish (Danio rerio)

Zhihui Liu et al.

Summary: Glyphosate exposure in zebrafish larvae induces developmental toxicity, characterized by premature hatching, reduced heartbeats, and body deformities. This is likely due to disrupted thyroid function and abnormal expression of growth hormone/insulin-like growth factor axis-related genes. Additionally, glyphosate treatment leads to oxidative damage, endoplasmic reticulum stress, inflammatory reactions, and apoptosis.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2022)

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Article Engineering, Environmental

Characterization of a novel glyphosate-degrading bacterial species, Chryseobacterium sp. Y16C, and evaluation of its effects on microbial communities in glyphosate-contaminated soil

Wenping Zhang et al.

Summary: The study successfully isolated a novel bacterial strain, Y16C, which efficiently degrades glyphosate and its main metabolite AMPA. The strain was also found to tolerate and degrade AMPA at high concentrations and accelerate glyphosate degradation in soil by inducing changes in soil microbial community. This suggests that strain Y16C may be a potential microbial agent for bioremediation of glyphosate-contaminated soil.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Environmental Sciences

Glyphosate, AMPA and glufosinate in soils and earthworms in a French arable landscape

C. Pelosi et al.

Summary: The widespread presence of glyphosate and its metabolites, AMPA and glufosinate, in arable landscapes in France raises concerns about soil contamination, exposure to earthworms, and bioaccumulation in terrestrial food webs.

CHEMOSPHERE (2022)

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Article Environmental Sciences

Characterization of glyphosate-induced cardiovascular toxicity and apoptosis in zebrafish

Jian Lu et al.

Summary: Glyphosate, the most widely used herbicide, poses new hazards to human health, particularly cardiovascular toxicity. Research on zebrafish embryos exposed to glyphosate showed developmental abnormalities, including mortality, hatching issues, body length reduction, cardiac malformations, and impaired angiogenesis. Mechanistically, apoptosis occurred in the heart and vascular regions, with altered expression levels of apoptosis-related genes. This study provides evidence linking glyphosate exposure to cardiovascular developmental toxicity.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Environmental Sciences

Wastewater toxicity removal: Integrated chemical and effect-based monitoring of full-scale conventional activated sludge and membrane bioreactor plants

Giorgio Bertanza et al.

Summary: Current literature lacks effect-based monitoring studies on full-scale membrane bioreactor plants. This research conducted a monitoring campaign at a full-scale wastewater treatment facility and used bioassays to complement the investigation. The results showed better performance of MBR in removing organic pollutants and suspended solids, with no major differences in chemical analyses between CAS and MBR. Both treatment lines complied with effluent discharge standards, but residual biological activity was detected.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Environmental Sciences

Efficient removal of glyphosate from aqueous solutions by adsorption on Mg-Al-layered double oxides: thermodynamic, kinetic, and mechanistic investigation

Emanoel Hottes et al.

Summary: Up to 90% of glyphosate was efficiently removed by a 2:1 Mg2Al-layered double oxide (LDO) at pH 10 in 40 minutes. The adsorption kinetics followed a pseudo-second-order law, and the adsorption isotherms were of type L. The Langmuir model best described the experimental data, revealing the maximum adsorption capacity of glyphosate at 25 degrees C. Furthermore, the study investigated the interaction of glyphosate with LDO surface and the influence of different anionic species on glyphosate removal.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022)

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Article Environmental Sciences

Highly efficient removal of glyphosate from water by hierarchical-pore UiO-66: Selectivity and effects of natural water particles

Yue Tao et al.

Summary: This study achieved the selective removal of glyphosate from water environments using hierarchical-pore metal-organic framework materials. The materials exhibited high adsorption capacity and suitable selective adsorption performance, allowing for rapid and effective removal of glyphosate in complex aqueous environments.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

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Article Engineering, Environmental

Photo-electrochemical oxidation herbicides removal in stormwater: Degradation mechanism and pathway investigation

Zhaozhi Zheng et al.

Summary: This study explored the potential and application of advanced oxidation processes (AOPs) in urban stormwater treatment. It was found that photoelectrochemical oxidation (PECO) and electrochemical oxidation (ECO) showed good removal performance for diuron, with superoxide radical being the dominant reactive species. Additionally, hydroxyl radical and free chlorine also supported the degradation reactions. The proposed degradation pathways identified several intermediate products. PECO demonstrated higher oxidation capacity compared to ECO and photocatalytic oxidation (PCO), which resulted in more complete decomposition of stormwater herbicides.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Chemistry, Applied

Insights into glyphosate adsorption on Lewis acidic zeolites from theoretical modelling

Jarinya Sittiwong et al.

Summary: The adsorption process is an important route for removing glyphosate, and this study investigated the adsorption of glyphosate on Lewis acidic zeolites through density functional theory calculations. It was found that Hf-BEA zeolite had the highest adsorption energy and ordered Lewis acidity, and there was a linear scaling relationship between glyphosate and ammonia adsorption energies. The zeolite pore structures also affected the adsorption activity, and water and hydrolysis of metal-substituted active sites played a significant role in glyphosate adsorption.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

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Article Environmental Sciences

Petroleum in Pesticides: A Need to Change Regulatory Toxicology

Gérald Jungers et al.

Toxics (2022)

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Evaluation of Synthesis Method of Fe Loaded Amorphous Silica on the Adsorption of Glyphosate

Onsulang Sophiphun et al.

Current Applied Science and Technology (2022)

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Article Engineering, Environmental

Incorporating simultaneous effect of initial concentration and sorbent dose into removal prediction model using glyphosate experimental data and theoretical analysis

Anahita Esmaeilian et al.

Summary: Glyphosate, the most used herbicide in the world, poses a serious threat to terrestrial and aquatic ecosystems. In this study, magnetic nanosorbents coated with humic acid were used to investigate the removal of glyphosate through adsorption. The results showed that the humic acid coated magnetic nanomaterials exhibited a high adsorption capacity for glyphosate and the adsorption process followed pseudo second-order kinetic and Langmuir isotherm models. The modeling approach using dimensional analyses with the application of Buckingham's pi theorem showed excellent agreement between predicted and experimental results.

CHEMICAL ENGINEERING JOURNAL (2022)

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Electrocoagulation and electrooxidation technologies for pesticide removal from water or wastewater: A review

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Summary: This review discusses the application of electrochemical methods for pesticide removal, focusing on mechanisms, influencing factors, efficiency, and characteristics. It provides valuable information for researchers in this field.

CHEMOSPHERE (2022)

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Removal of organic micropollutans by adsorptive membrane

Gulmire Ilyasoglu et al.

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CHEMOSPHERE (2022)

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Review Environmental Sciences

A critical and recent developments on adsorption technique for removal of heavy metals from wastewater-A review

Saravanan Rajendran et al.

Summary: This review quantitatively describes the viability of nano-adsorbent processing in wastewater detoxification by extracting heavy metal ions. It comprehensively evaluates the impact of nano-adsorbent functionalities on essential attributes and analyzes their limited resistance to adsorb some heavy metal ions. The study investigates experimental variables and separate models to understand the mechanism behind adsorption. The review highlights the different nano-based techniques and their potential applications in environmental remediation.

CHEMOSPHERE (2022)

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Article Agriculture, Multidisciplinary

Effects of Free or Immobilized Bacterium Stenotrophomonas acidaminiphila Y4B on Glyphosate Degradation Performance and Indigenous Microbial Community Structure

Jiayi Li et al.

Summary: A novel strain Y4B was isolated, which efficiently degraded glyphosate and its major metabolite. Y4B showed strong competitiveness in degrading glyphosate in different soils, indicating its potential for bioremediation of glyphosate-contaminated sites. The immobilized cells of Y4B demonstrated excellent biodegradation efficiency in a sediment-water system.

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2022)

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Review Environmental Sciences

The state-of-the-art development of photocatalysts for the degradation of persistent herbicides in wastewater

M. H. Hazaraimi et al.

Summary: This review evaluates the degradation performance of photocatalysts in the treatment of herbicides in wastewater. The key factors in photocatalyst engineering, such as charge separation and enhanced light absorption, are discussed. The limitations and challenges of photocatalysis technology in practical applications are identified, and future research directions are recommended.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Engineering, Environmental

Microcosm test for pesticide fate assessment in planted water filters: 13C,15N-labeled glyphosate as an example

Yuying Jing et al.

Summary: This study conducted a microcosm test to simulate the fate of pesticides in planted filters, and found that the presence of planted filters can enhance the degradation and adsorption of pesticides.

WATER RESEARCH (2022)

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Article Environmental Sciences

Selective recovery of glyphosine from glyphosate mother liquor using a modified biosorbent: Competitive substitution adsorption

Yuanping Guo et al.

Summary: In this study, an easy to prepare, environmentally friendly, and highly efficient biosorbent was synthesized for the selective recovery of glyphosine from glyphosate mother liquor. The biosorbent exhibited fast adsorption rate and high adsorption capacity toward glyphosine and performed better under acidic conditions. It could be easily regenerated using an alkaline solution and maintained high removal efficiency even after 5 adsorption-desorption cycles. Competitive adsorption experiments revealed that the biosorbent showed higher adsorption affinity toward glyphosine compared with glyphosate and phosphorous acid, enabling the selective recycling of glyphosine. The adsorption mechanism was found to be associated with electrostatic attraction and hydrogen bonding between -NH3+ and glyphosine. The biosorbent can be considered an excellent candidate for the selective recovery of glyphosine from complicated industrial wastewater systems.

ENVIRONMENTAL RESEARCH (2022)

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Article Environmental Sciences

Insights into the microbial degradation and resistance mechanisms of glyphosate

Yongsheng Chen et al.

Summary: Glyphosate, a broad-spectrum herbicide, is widely distributed and poses a serious threat to human safety and ecology. Microbial degradation has emerged as a promising method for treating glyphosate due to its efficiency and environmental friendliness. Microorganisms can utilize glyphosate as a nutrient source and degrade it into harmless products by cleaving specific bonds. However, the enzymes and functional genes involved in glyphosate degradation and the resistance mechanisms of microorganisms to glyphosate are not well understood.

ENVIRONMENTAL RESEARCH (2022)

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Review Engineering, Environmental

Critical review on the role of mass spectrometry in the AOP based degradation of contaminants of emerging concern (CECs) in water

Sunil Paul M. Menacherry et al.

Summary: Elimination of organic contaminants is crucial for environmental protection. Advanced oxidation processes may generate similar transformation products. Mass spectrometry based investigations are important for understanding the degradation mechanism.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Engineering, Environmental

Screening of hierarchical porous UiO-67 for efficient removal of glyphosate from aqueous solution

Fei Fang et al.

Summary: Defect engineering plays a crucial role in enhancing the adsorption performance of metal-organic frameworks (MOFs). By controlling defect levels, hierarchical porous UiO-67(Zr) was successfully obtained and exhibited superior chemoselective capture of glyphosate from water, with high adsorption capacity and selectivity.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

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Article Biotechnology & Applied Microbiology

Biodegradation of Organophosphorus Pollutants by Soil Bacteria: Biochemical Aspects and Unsolved Problems

A. V. Sviridov et al.

Summary: The study found significant differences in the degradation of stable organophosphorus pollutants among different bacterial strains, with bacteria adapted to glyphosate showing higher consumption rates of other phosphonates. Additionally, the discovery of new highly efficient degrading strains provides new insights into the decomposition of glyphosate in soil. Further research on the microbial metabolism of glyphosate and the development of effective bioremediation preparations for soils contaminated with organophosphonates is discussed.

APPLIED BIOCHEMISTRY AND MICROBIOLOGY (2021)

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Review Environmental Sciences

A state-of-the-art review on wastewater treatment techniques: the effectiveness of adsorption method

Ruhma Rashid et al.

Summary: Water contamination from toxic pollutants like dyes, heavy metals, and surfactants has become a global challenge, leading to increasing efforts to develop effective wastewater treatment techniques. Various methods such as chemical oxidation, physical adsorption, and biological treatments have been recognized. Among these, adsorption is considered a simple, sustainable, cost-effective, and environmentally friendly technique for wastewater treatment, but further research and development are needed for practical implementation in a wide range of applications.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

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Article Water Resources

Ultrafiltration for removal of glyphosate and aminomethylphosphonic acid in drinking water

Edumar Ramos Cabral Coelho et al.

Summary: Glyphosate, a non-selective herbicide, was evaluated for removal in fortified surface water using direct ultrafiltration. The removal efficiency of glyphosate was affected by pH, concentration, and the presence of natural organic matter, with adsorption onto the membrane surface/pores as the main retention mechanism. However, the ultrafiltration process was not effective for removing aminomethylphosphonic acid.

ENGENHARIA SANITARIA E AMBIENTAL (2021)

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Review Environmental Sciences

Is glyphosate toxic to bees? A meta-analytical review

Lucas Battisti et al.

Summary: Glyphosate, originally considered non-toxic to bees, has been shown to negatively impact their survival and behavior even at recommended doses. Meta-analysis of studies on GLY toxicity to bees revealed an increase in bee mortality rates, suggesting its toxic effects.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Article Engineering, Chemical

Insights into the glyphosate removal efficiency by using magnetic powder activated carbon composite

Peng Yu et al.

Summary: In this study, Fe3O4-PAC and MnFe2O4-PAC were prepared using co-precipitation for the treatment of glyphosate pesticide wastewater. It was found that MnFe2O4-PAC had a higher adsorption capacity than the original PAC, and the adsorption behavior was in accordance with the Langmuir adsorption isotherm. The adsorption capacity of Fe3O4-PAC and MnFe2O4-PAC for glyphosate exhibited a similar trend.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Microbiology

Isolation, Biochemical and Genomic Characterization of Glyphosate Tolerant Bacteria to Perform Microbe-Assisted Phytoremediation

Francisco Massot et al.

Summary: The study isolated bacteria from a site chronically exposed to glyphosate, evaluated their plant-colonizing, glyphosate-tolerant, and -degrading abilities, and demonstrated their potential for remediation of glyphosate contaminated agronomic soils through experimental tests.

FRONTIERS IN MICROBIOLOGY (2021)

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Article Chemistry, Physical

Development and Characterization of Composite Carbon Adsorbents with Photocatalytic Regeneration Ability: Application to Diclofenac Removal from Water

Velma Beri Kimbi Yaah et al.

Summary: This study developed a carbon composite for water purification, with the best removal results achieved under UV-B irradiation with a composite containing TiO2, carbon, and W. Good removal efficiency was also observed under visible light conditions. Adjusting the activation temperature affected surface functional groups and removal efficiency.

CATALYSTS (2021)

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Article Chemistry, Physical

Engineered nanoscale schwertmannites as Fenton-like catalysts for highly efficient degradation of nitrophenols

Xing-Xing Qiao et al.

Summary: The study fabricated engineered nanoscale schwertmannite (nano-SCH) through a PVP-assisted room-temperature synthesis and found that the optimized nano-SCH-0.125 showed excellent degradation efficiency for 4-NP in Fenton-like processes, attributed to its abundant reactive sites and hierarchical structure.

APPLIED SURFACE SCIENCE (2021)

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Article Environmental Sciences

Degradation and mineralization of ofloxacin by ozonation and peroxone (O3/H2O2) process

Hai Chen et al.

Summary: The study found that the degradation and mineralization of ofloxacin by ozonation and peroxone process were effective, with peroxone process showing a significantly better mineralization effect compared to ozonation alone. The dosage of H2O2 and O-3 was crucial for process performance, and the presence of HCO3- and PO43- enhanced mineralization while Cl- and NO3- had a negative impact on mineralization efficiency.

CHEMOSPHERE (2021)

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Article Engineering, Environmental

Enhanced photocatalytic degradation of glyphosate over 2D CoS/BiOBr heterojunctions under visible light irradiation

Qiang-Yong Tang et al.

Summary: This study developed 2D heterojunction photocatalysts with enhanced photocatalytic performance by depositing CoS nanoparticles on BiOBr nanosheets. The photocatalyst showed excellent degradation efficiency for glyphosate under visible-light irradiation and exhibited good reusability and stability. This work provides new insights for the design and development of 2D heterojunction photocatalysts.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Engineering, Environmental

Hybrid carbon materials: Synthesis, characterization, and application in the removal of pharmaceuticals from water

Velma Beri Kimbi Yaah et al.

Summary: Hydrothermal carbonization was used to develop novel carbon-based hybrids for the removal of diclofenac and amoxicillin from water. The synthesized materials showed beneficial oxygen-containing surface functional groups, with tungsten improving the photocatalytic activity of the material. An interaction between W, C and TiO2 was observed, influencing the photocatalytic performance.

JOURNAL OF WATER PROCESS ENGINEERING (2021)

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Article Environmental Sciences

Glyphosate: How do ongoing controversies, market characteristics, and funding influence the global research landscape?

Doris Klingelhofer et al.

Summary: Glyphosate, the most widely used herbicide globally, has sparked controversy over its effects on human health and the environment. Research output has grown in line with consumption, with different countries showing varying levels of interest and investment in glyphosate studies. Market and agricultural interests drive research incentives, with the need to expand the international research network to include developing economies for a more comprehensive understanding of glyphosate use.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Review Environmental Sciences

Critical review of advanced oxidation processes in organic wastewater treatment

Dengsheng Ma et al.

Summary: With the development of industrial society, organic wastewater from industrial manufacturing has caused environmental issues, necessitating efficient treatment methods. Advanced oxidation processes (AOPs) are recognized for their high efficiency and lack of secondary pollution, and are widely studied and applied in the treatment of organic wastewater.

CHEMOSPHERE (2021)

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Review Biochemistry & Molecular Biology

Characterization Techniques as Supporting Tools for the Interpretation of Biochar Adsorption Efficiency in Water Treatment: A Critical Review

Michele Castiglioni et al.

Summary: Biochar has gained significant attention in environmental applications, especially in water purification. Its porous structure is similar to activated carbon, a commonly used sorbent in water treatment. Studies suggest that current characterization methods limit the understanding of the correlation between the physicochemical features of biochar and pollutant removal.

MOLECULES (2021)

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Article Environmental Sciences

Recent Advances on Coagulation-Based Treatment of Wastewater: Transition from Chemical to Natural Coagulant

Muhammad Burhanuddin Bahrodin et al.

Summary: The use of conventional chemical coagulants in treating wastewater has raised concerns due to the negative impacts on human health and the environment. Transitioning to natural coagulants has been suggested as a strategy to mitigate these drawbacks, with research showing comparable or even better performance. However, further research is needed to address key aspects such as active coagulant agents, extraction, and optimization for different wastewater characteristics in order to fully realize the potential of natural coagulants for sustainable wastewater treatment.

CURRENT POLLUTION REPORTS (2021)

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Review Engineering, Environmental

Natural flocculants for the treatment of wastewaters containing dyes or heavy metals: A state-of-the-art review

Jamila El-Gaayda et al.

Summary: This review provides insights into the recent developments in natural flocculants for the removal of dyes or heavy metals from aqueous solutions. It covers the types, characteristics, toxicity, performances, and mechanisms of natural flocculants, as well as their economic analysis and future prospects. Conducting more in-depth scientific research on natural flocculants has the potential to enhance global water security in the long term.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Engineering, Environmental

Sequential recycle of valuable phosphorus compounds of glyphosine, glyphosate, and phosphorous acid from glyphosate mother liquor by D301 resin through sorbent dosage control

Yi Wang et al.

Summary: The study demonstrated the efficient removal and regeneration capabilities of D301 resin for glyphosate, glyphosine, and phosphorous acid from glyphosate mother liquor, providing important theoretical and practical guidance for the recycling of valuable phosphorus compounds.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Engineering, Environmental

Using banana peel waste to synthesize BPAC/ZnO nanocomposite for photocatalytic degradation of Acid Blue 25: Influential parameters, mineralization, biodegradability studies

Sajad Ahmadi et al.

Summary: In this study, the removal of Acid Blue 25 (AB25) using a nanocomposite of banana peel activated carbon (BPAC) and zinc oxide (ZnO) through photocatalytic degradation was investigated. The optimal conditions led to a removal efficiency of 94% after 150 minutes, with low energy consumption and good removal rates for COD and TOC. The study also found that the nanocomposite showed decreasing degradation efficiency after multiple reuse cycles.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Engineering, Environmental

Carbon nanotubes impregnated with metallic nanoparticles and their application as an adsorbent for the glyphosate removal in an aqueous matrix

Julia C. Diel et al.

Summary: The multi-walled carbon nanotubes modified with metal nanoparticles through green synthesis successfully removed the herbicide glyphosate from water through adsorption. The adsorption process showed high removal efficiency and capacity. Thermodynamic behavior indicated the process is spontaneous and favorable.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Soil Science

Optimization and modeling of glyphosate biodegradation by a novel Comamonas odontotermitis P2 through response surface methodology

Sadiqa Firdous et al.

PEDOSPHERE (2020)

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Article Environmental Sciences

Physicochemical properties and sorption capacities of sawdust-based biochars and commercial activated carbons towards ethoxylated alkylphenols and their phenolic metabolites in effluent wastewater from a textile district

Massimo Del Bubba et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Article Engineering, Environmental

Glyphosate and aminomethylphosphonic acid (AMPA) are commonly found in urban streams and wetlands of Melbourne, Australia

Elena Okada et al.

WATER RESEARCH (2020)

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Review Agricultural Engineering

Bioremediation of heavy metals using microalgae: Recent advances and mechanisms

Yoong Kit Leong et al.

BIORESOURCE TECHNOLOGY (2020)

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Article Chemistry, Multidisciplinary

Behavior of Glyphosate in Wastewater Treatment Plants

Thomas Poiger et al.

CHIMIA (2020)

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Article Environmental Sciences

The global environmental hazard of glyphosate use

Federico Maggi et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Review Ecology

Prospectives and challenges of wastewater treatment technologies to combat contaminants of emerging concerns

Aamir Ishaq Shah et al.

ECOLOGICAL ENGINEERING (2020)

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Review Environmental Sciences

Controversies over human health and ecological impacts of glyphosate: Is it to be banned in modern agriculture?

Islam Md. Meftaul et al.

ENVIRONMENTAL POLLUTION (2020)

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Article Engineering, Environmental

Removal of hazardous substances in municipal wastewater treatment plants

Vallo Korgmaa et al.

WATER SCIENCE AND TECHNOLOGY (2020)

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Article Engineering, Chemical

Novel Z-scheme In2S3/BiVO4 composites with improved visible-light photocatalytic performance and stability for glyphosate degradation

Qiang-Yong Tang et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2020)

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Review Environmental Sciences

Herbicide Glyphosate: Toxicity and Microbial Degradation

Simranjeet Singh et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2020)

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Article Environmental Sciences

Determination of Glyphosate in Water from a Rural Locality in Mexico and Its Implications for the Population Based on Water Consumption and Use Habits

Eduardo C. Reynoso et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2020)

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Article Chemistry, Physical

Heterogeneous Photocatalysis Scalability for Environmental Remediation: Opportunities and Challenges

Sherif A. Younis et al.

CATALYSTS (2020)

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Review Engineering, Environmental

Role of electrocoagulation in wastewater treatment: A developmental review

Amina Tahreen et al.

JOURNAL OF WATER PROCESS ENGINEERING (2020)

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Review Engineering, Chemical

Adsorption as a Process for Produced Water Treatment: A Review

Roghayeh Yousef et al.

PROCESSES (2020)

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Review Materials Science, Multidisciplinary

Challenges and approaches towards upscaling the assembly of hybrid perovskite solar cells

Ahmed Esmail Shalan

MATERIALS ADVANCES (2020)

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Article Engineering, Environmental

The use of artificial intelligence models in the prediction of optimum operational conditions for the treatment of dye wastewaters with similar structural characteristics

Alain R. Picos-Benitez et al.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2020)

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Article Biochemical Research Methods

Validation of a simple ion chromatography method for simultaneous determination of glyphosate, aminomethylphosphonic acid and ions of Public Health concern in water intended for human consumption

Sergio Dovidauskas et al.

JOURNAL OF CHROMATOGRAPHY A (2020)

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Article Engineering, Environmental

Cyclodextrins grafted MoS2/g-C3N4 as high-performance photocatalysts for the removal of glyphosate and Cr (VI) from simulated agricultural runoff

Zhansheng Wu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Review Environmental Sciences

Treatment technologies and degradation pathways of glyphosate: A critical review

Dan Feng et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Article Green & Sustainable Science & Technology

Magnetite nanoparticles as efficient materials for removal of glyphosate from water

Hyoungwon Park et al.

NATURE SUSTAINABILITY (2020)

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Article Environmental Sciences

Indiscriminate use of glyphosate impregnates river epilithic biofilms in southern Brazil

Gracieli Fernandes et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2019)

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Article Environmental Sciences

Organic micropollutants in a large wastewater treatment plant: What are the benefits of an advanced treatment by activated carbon adsorption in comparison to conventional treatment?

Ronan Guillossou et al.

CHEMOSPHERE (2019)

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Review Environmental Sciences

Fate, eco-toxicological characteristics, and treatment processes applied to water polluted with glyphosate: A critical review

Cristina Alejandra Villamar-Ayala et al.

CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2019)

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Article Environmental Sciences

Meta-analysis of glyphosate contamination in surface waters and dissipation by biofilms

Louis Carles et al.

ENVIRONMENT INTERNATIONAL (2019)

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Article Environmental Sciences

Monitoring of Glyphosate, Glufosinate-ammonium, and (Aminomethyl) phosphonic acid in ambient air of Provence-Alpes-Cote-d'Azur Region, France

Sylvain Ravier et al.

ATMOSPHERIC ENVIRONMENT (2019)

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Article Engineering, Environmental

Efficient photocatalytic degradation of herbicide glyphosate in water by magnetically separable and recyclable BiOBr/Fe3O4 nanocomposites under visible light irradiation

Lidong Cao et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Environmental Sciences

Statistical optimization of glyphosate adsorption by biochar and activated carbon with response surface methodology

Gayana Anjali Dissanayake Herath et al.

CHEMOSPHERE (2019)

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Article Environmental Sciences

Investigation of the presence of glyphosate and its major metabolite AMPA in Greek soils

Helen Karasali et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2019)

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Article Engineering, Environmental

Degradation of clofibric acid by UV, O3 and UV/O3 processes: Performance comparison and degradation pathways

Yan Wang et al.

JOURNAL OF HAZARDOUS MATERIALS (2019)

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Article Engineering, Environmental

Kinetic study of the biodegradation of glyphosate by indigenous soil bacterial isolates in presence of humic acid, Fe(III) and Cu(II) ions

Simranjeet Singh et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2019)

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Article Environmental Sciences

Advanced oxidation of commercial herbicides mixture: experimental design and phytotoxicity evaluation

Alejandro Lopez et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2018)

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Article Environmental Sciences

Removal of glyphosate and aminomethylphosphonic acid from synthetic water by nanofiltration

Jiang Yuan et al.

ENVIRONMENTAL TECHNOLOGY (2018)

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Review Biotechnology & Applied Microbiology

Recent advances in glyphosate biodegradation

Hui Zhan et al.

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY (2018)

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Review Engineering, Environmental

Insight into electro-Fenton and photo-Fenton for the degradation of antibiotics: Mechanism study and research gaps

Xiaocheng Liu et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Engineering, Environmental

Comparative study of glyphosate removal on goethite and magnetite: Adsorption and photo-degradation

Ying Yang et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Chemistry, Physical

Mechanism of glyphosate removal by biochar supported nano-zero-valent iron in aqueous solutions

Xianying Jiang et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2018)

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Article Environmental Sciences

Modification of zeolite 4A for use as an adsorbent for glyphosate and as an antibacterial agent for water

Siamak Zavareh et al.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2018)

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Article Environmental Sciences

Herbicides in river water across the northeastern Italy: occurrence and spatial patterns of glyphosate, aminomethylphosphonic acid, and glufosinate ammonium

Mauro Masiol et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2018)

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Article Environmental Sciences

Adsorption performance and mechanism of magnetic reduced graphene oxide in glyphosate contaminated water

Yajuan Li et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2018)

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Article Environmental Sciences

Kinetic study on biodegradation of glyphosate with unacclimated activated sludge

Djaber Tazdait et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL HEALTH RESEARCH (2018)

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Article Environmental Sciences

Distribution of glyphosate and aminomethylphosphonic acid (AMPA) in agricultural topsoils of the European Union

Vera Silva et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2018)

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Article Chemistry, Physical

Two-step hydrothermal synthesis of peanut-shaped molybdenum diselenide/bismuth vanadate (MoSe2/BiVO4) with enhanced visible-light photocatalytic activity for the degradation of glyphosate

Xiu-Li Luo et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2018)

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Article Multidisciplinary Sciences

Glyphosate perturbs the gut microbiota of honey bees

Erick V. S. Motta et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

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Article Materials Science, Multidisciplinary

Fabrication of the annular photocatalytic reactor using large-sized freestanding titania-silica monolithic aerogel as the catalyst for degradation of glyphosate

Tao Long et al.

MATERIALS & DESIGN (2018)

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Review Public, Environmental & Occupational Health

Ignoring Adjuvant Toxicity Falsifies the Safety Profile of Commercial Pesticides

Robin Mesnage et al.

FRONTIERS IN PUBLIC HEALTH (2018)

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Article Toxicology

Toxicity of formulants and heavy metals in glyphosate-based herbicides and other pesticides

N. Defarge et al.

TOXICOLOGY REPORTS (2018)

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Article Environmental Sciences

Glyphosate and AMPA, pseudo-persistent pollutants under real world agricultural management practices in the Mesopotamic Pampas agroecosystem, Argentina

Jezabel E. Primost et al.

ENVIRONMENTAL POLLUTION (2017)

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Article Environmental Sciences

Electrochemical degradation and mineralization of glyphosate herbicide

Nam Tran et al.

ENVIRONMENTAL TECHNOLOGY (2017)

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Article Thermodynamics

Removal of Glyphosate from Aqueous Solution Using Nanosized Copper Hydroxide Modified Resin: Equilibrium Isotherms and Kinetics

Changyin Zhou et al.

JOURNAL OF CHEMICAL AND ENGINEERING DATA (2017)

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Article Materials Science, Multidisciplinary

Visible-light photocatalytic degradation of glyphosate over BiVO4 prepared by different co-precipitation methods

Rui Huo et al.

MATERIALS RESEARCH BULLETIN (2017)

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Article Biochemical Research Methods

Pathway and rate-limiting step of glyphosate degradation by Aspergillus oryzae A-F02

Gui-ming Fu et al.

PREPARATIVE BIOCHEMISTRY & BIOTECHNOLOGY (2017)

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Article Chemistry, Multidisciplinary

Effective removal of glyphosate from water by resin-supported double valent nano-sized hydroxyl iron oxide

D. M. Jia et al.

RSC ADVANCES (2017)

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Article Environmental Sciences

Glyphosate Residues in Groundwater, Drinking Water and Urine of Subsistence Farmers from Intensive Agriculture Localities: A Survey in Hopelchen, Campeche, Mexico

Jaime Rendon-von Osten et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2017)

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Article Engineering, Chemical

Ability of filamentous fungi to degrade four emergent water priority pollutants

R. Bouchiat et al.

DESALINATION AND WATER TREATMENT (2016)

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Article Engineering, Environmental

Triclosan removal by NF from a real drinking water source - Effect of natural organic matter

Abdullah Ogutverici et al.

CHEMICAL ENGINEERING JOURNAL (2016)

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Article Engineering, Environmental

Magnetic MnFe2O4-graphene hybrid composite for efficient removal of glyphosate from water

Natalia Ueda Yamaguchi et al.

CHEMICAL ENGINEERING JOURNAL (2016)

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Article Engineering, Environmental

Degradation of herbicide (glyphosate) using sunlight-sensitive MnO2/C catalyst immediately fabricated by high energy electron beam

Min Wang et al.

CHEMICAL ENGINEERING JOURNAL (2016)

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Article Environmental Sciences

Water quality of the main tributaries of the Parana Basin: glyphosate and AMPA in surface water and bottom sediments

A. E. Ronco et al.

ENVIRONMENTAL MONITORING AND ASSESSMENT (2016)

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Article Thermodynamics

Comparative adsorption of glyphosate from aqueous solution by 2-aminopyridine modified polystyrene resin, D301 resin and 330 resin: Influencing factors, salinity resistance and mechanism

Guqing Xiao et al.

FLUID PHASE EQUILIBRIA (2016)

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Article Chemistry, Applied

Mechanistic modeling of glyphosate interaction with rice husk derived engineered biochar

Indika Herath et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2016)

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Article Agronomy

Glyphosate residues in rural groundwater, Nottawasaga River Watershed, Ontario, Canada

Dale R. Van Stempvoort et al.

PEST MANAGEMENT SCIENCE (2016)

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Article Engineering, Environmental

An activated carbon fiber cathode for the degradation of glyphosate in aqueous solutions by the Electro-Fenton mode: Optimal operational conditions and the deposition of iron on cathode on electrode reusability

Huachun Lan et al.

WATER RESEARCH (2016)

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Review Biotechnology & Applied Microbiology

Bioremediation techniques-classification based on site of application: principles, advantages, limitations and prospects

Christopher Chibueze Azubuike et al.

WORLD JOURNAL OF MICROBIOLOGY & BIOTECHNOLOGY (2016)

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Article Environmental Sciences

Co-Formulants in Glyphosate-Based Herbicides Disrupt Aromatase Activity in Human Cells below Toxic Levels

Nicolas Defarge et al.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2016)

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Article Environmental Sciences

Trends in glyphosate herbicide use in the United States and globally

Charles M. Benbrook

ENVIRONMENTAL SCIENCES EUROPE (2016)

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Article Chemistry, Analytical

Magnetic solid phase extraction of glyphosate and aminomethylphosphonic acid in river water using Ti4+-immobilized Fe3O4 nanoparticles by capillary electrophoresis

Ya-lei Dong et al.

ANALYTICAL METHODS (2015)

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Article Biotechnology & Applied Microbiology

Microbial Degradation of Glyphosate Herbicides (Review)

A. V. Sviridov et al.

APPLIED BIOCHEMISTRY AND MICROBIOLOGY (2015)

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Review Toxicology

Evaluation of carcinogenic potential of the herbicide glyphosate, drawing on tumor incidence data from fourteen chronic/carcinogenicity rodent studies

Helmut Greim et al.

CRITICAL REVIEWS IN TOXICOLOGY (2015)

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Review Engineering, Chemical

A review on RO membrane technology: Developments and challenges

Seema S. Shenvi et al.

DESALINATION (2015)

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Review Engineering, Chemical

Nanofiltration membranes review: Recent advances and future prospects

A. W. Mohammad et al.

DESALINATION (2015)

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Article Environmental Sciences

Removal of glyphosate herbicide from water using biopolymer membranes

Rafael T. A. Carneiro et al.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2015)

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Article Engineering, Environmental

A novel route to graphite-like carbon supporting SnO2 with high electron transfer and photocatalytic activity

Xianjie Chen et al.

JOURNAL OF HAZARDOUS MATERIALS (2015)

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Article Multidisciplinary Sciences

Seed coating with a neonicotinoid insecticide negatively affects wild bees

Maj Rundlof et al.

NATURE (2015)

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Article Biochemistry & Molecular Biology

Modeling of degradation kinetic and toxicity evaluation of herbicides mixtures in water using the UV/H2O2 process

Melisa L. Mariani et al.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2015)

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Article Engineering, Chemical

Environmental evaluation of bipolar membrane electrodialysis for NaOH production from wastewater: Conditioning NaOH as a CO2 absorbent

Wenyuan Ye et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2015)

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Article Engineering, Environmental

Event-based quantification of emerging pollutant removal for an open stormwater retention basin - Loads, efficiency and importance of uncertainties

C. Sebastian et al.

WATER RESEARCH (2015)

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Article Engineering, Environmental

Surrogates for herbicide removal in stormwater biofilters

Kefeng Zhang et al.

WATER RESEARCH (2015)

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Article Nanoscience & Nanotechnology

Effective Adsorption and Enhanced Removal of Organophosphorus Pesticides from Aqueous Solution by Zr-Based MOFs of UiO-67

Xiangyang Zhu et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

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Article Agricultural Engineering

Sequential anaerobic-aerobic treatment of pharmaceutical wastewater with high salinity

Xueqing Shi et al.

BIORESOURCE TECHNOLOGY (2014)

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Article Engineering, Chemical

Techno-economic analysis of resource recovery of glyphosate liquor by membrane technology

Jiangnan Shen et al.

DESALINATION (2014)

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Article Ecology

The validation of stormwater biofilters for micropollutant removal using in situ challenge tests

Kefeng Zhang et al.

ECOLOGICAL ENGINEERING (2014)

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Article Environmental Sciences

Biofiltration vs conventional activated sludge plants: what about priority and emerging pollutants removal?

R. Mailler et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2014)

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Article Thermodynamics

Study on behavior of alkalescent fiber FFA-1 adsorbing glyphosate from production wastewater of glyphosate

C. R. Zhou et al.

FLUID PHASE EQUILIBRIA (2014)

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Article Engineering, Chemical

Enhanced Glyphosate Removal by Montmorillonite in the Presence of Fe(III)

Zhong Ren et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2014)

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Article Environmental Sciences

Glyphosate persistence in seawater

Philip Mercurio et al.

MARINE POLLUTION BULLETIN (2014)

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Review Microbiology

Utilization of Glyphosate as Phosphate Source: Biochemistry and Genetics of Bacterial Carbon-Phosphorus Lyase

Bjarne Hove-Jensen et al.

MICROBIOLOGY AND MOLECULAR BIOLOGY REVIEWS (2014)

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Article Nanoscience & Nanotechnology

Fabrication of Ag/TiO2 nanotube array with enhanced photo-catalytic degradation of aqueous organic pollutant

Jie Ma et al.

PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES (2014)

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Article Biochemistry & Molecular Biology

Photocatalytic Degradation of Glyphosate in Water by N-Doped SnO2/TiO2 Thin-Film-Coated Glass Fibers

Peerawas Kongsong et al.

PHOTOCHEMISTRY AND PHOTOBIOLOGY (2014)

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Article Chemistry, Applied

Synthesis and characterization of cross-linked molecularly imprinted polyacrylamide for the extraction/preconcentration of glyphosate and aminomethylphosphonic acid from water samples

Kamilla da Mata et al.

REACTIVE & FUNCTIONAL POLYMERS (2014)

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Review Engineering, Environmental

A review on application of flocculants in wastewater treatment

Chai Siah Lee et al.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2014)

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Article Engineering, Environmental

Microbial pesticide removal in rapid sand filters for drinking water treatment - Potential and kinetics

Mathilde J. Hedegaard et al.

WATER RESEARCH (2014)

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Article Engineering, Environmental

Stormwater retention basin efficiency regarding micropollutant loads and ecotoxicity

Christel Sebastian et al.

WATER SCIENCE AND TECHNOLOGY (2014)

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Proceedings Paper Engineering, Chemical

Synthesis of Calcium Peroxide Microparticles and Its Application in Glyphosate Wastewater Pretreatment

Jian Zhai et al.

CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING III, PTS 1-3 (2014)

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Proceedings Paper Engineering, Chemical

Mineralization of organophosphorous pesticides by electro-generated oxidants

Olga Kukurina et al.

XV INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (2014)

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Article Environmental Sciences

Can rainwater induce Fenton-driven degradation of herbicides in natural waters?

Junhao Qin et al.

CHEMOSPHERE (2013)

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Article Environmental Sciences

Transport and attenuation of dissolved glyphosate and AMPA in a stormwater wetland

Gwenael Imfeld et al.

CHEMOSPHERE (2013)

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Article Chemistry, Physical

Degradation of glyphosate and AMPA (amino methylphosphonic acid) solutions by thin films of birnessite electrodeposited: A new design of material for remediation processes?

M. Ndjeri et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2013)

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Review Toxicology

Review of genotoxicity studies of glyphosate and glyphosate-based formulations

Larry D. Kier et al.

CRITICAL REVIEWS IN TOXICOLOGY (2013)

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Article Microbiology

The Effect of Glyphosate on Potential Pathogens and Beneficial Members of Poultry Microbiota In Vitro

Awad A. Shehata et al.

CURRENT MICROBIOLOGY (2013)

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Article Engineering, Chemical

Pretreatment of membrane separation of glyphosate mother liquor using a precipitation method

Zhiying Liu et al.

DESALINATION (2013)

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Article Ecology

Field evaluation of a new biphasic rain garden for stormwater flow management and pollutant removal

Hanbae Yang et al.

ECOLOGICAL ENGINEERING (2013)

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Article Environmental Sciences

The application of microfiltration-reverse osmosis/nanofiltration to trace organics removal for municipal wastewater reuse

N. Garcia et al.

ENVIRONMENTAL TECHNOLOGY (2013)

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Article Environmental Sciences

EFFECTS OF SELENIUM ON DEVELOPMENT, SURVIVAL, AND ACCUMULATION IN THE HONEYBEE (APIS MELLIFERA L.)

Kristen R. Hladun et al.

ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY (2013)

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Article Environmental Sciences

Effectiveness evaluation of glyphosate oxidation employing the H2O2/UVC process: Toxicity assays with Vibrio fischeri and Rhinella arenarum tadpoles

Celina M. Junges et al.

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES (2013)

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Article Engineering, Environmental

Oxygen isotope signature of UV degradation of glyphosate and phosphonoacetate: Tracing sources and cycling of phosphonates

Edward H. Sandy et al.

JOURNAL OF HAZARDOUS MATERIALS (2013)

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Article Chemistry, Applied

Polyaniline and its composites with zeolite ZSM-5 for efficient removal of glyphosate from aqueous solution

Maja Milojevic-Rakic et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2013)

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Review Engineering, Civil

Removal and degradation of glyphosate in water treatment: a review

Joergen Joensson et al.

JOURNAL OF WATER SUPPLY RESEARCH AND TECHNOLOGY-AQUA (2013)

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Article Environmental Sciences

Performance of UK wastewater treatment works with respect to trace contaminants

Mike Gardner et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2013)

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Article Environmental Sciences

Cost-performance indicator for comparative environmental assessment of water treatment plants

Elorri Igos et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2013)

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Article Pharmacology & Pharmacy

Ethoxylated adjuvants of glyphosate-based herbicides are active principles of human cell toxicity

R. Mesnage et al.

TOXICOLOGY (2013)

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Article Engineering, Environmental

Herbicide mitigation in microcosms simulating stormwater basins subject to polluted water inputs

P. Bois et al.

WATER RESEARCH (2013)

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Article Engineering, Environmental

Retention of pesticide Endosulfan by nanofiltration: Influence of organic matter-pesticide complexation and solute-membrane interactions

Annalisa De Munari et al.

WATER RESEARCH (2013)

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Article Engineering, Environmental

Composite hollow fiber nanofiltration membranes for recovery of glyphosate from saline wastewater

Jianfeng Song et al.

WATER RESEARCH (2013)

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Proceedings Paper Engineering, Chemical

Kinetics of Glyphosate Adsorption on Composite Resin from Aqueous Solution

Zhenzhen Kong et al.

FRONTIERS OF CHEMICAL ENGINEERING, METALLURGICAL ENGINEERING AND MATERIALS II (2013)

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Article Biotechnology & Applied Microbiology

Distribution of glyphosate and methylphosphonate catabolism systems in soil bacteria Ochrobactrum anthropi and Achromobacter sp

Alexey V. Sviridov et al.

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY (2012)

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Article Toxicology

Cytotoxic and DNA-damaging properties of glyphosate and Roundup in human-derived buccal epithelial cells

Verena J. Koller et al.

ARCHIVES OF TOXICOLOGY (2012)

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Article Agricultural Engineering

Membrane bioreactor and nanofiltration hybrid system for reclamation of municipal wastewater: Removal of nutrients, organic matter and micropollutants

Kangmin Chon et al.

BIORESOURCE TECHNOLOGY (2012)

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Article Agricultural Engineering

Effect of biostimulation on community level physiological profiles of microorganisms in field-scale biopiles composed of aged oil sludge

Xiang Wang et al.

BIORESOURCE TECHNOLOGY (2012)

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Article Engineering, Environmental

Treatment of combined sewer overflows by ballasted flocculation: Removal study of a large broad spectrum of pollutants

Johnny Gasperi et al.

CHEMICAL ENGINEERING JOURNAL (2012)

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Article Engineering, Chemical

The feasible study on the reclamation of the glyphosate neutralization liquor by bipolar membrane electrodialysis

Xin-xin Wang et al.

DESALINATION (2012)

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Article Environmental Sciences

Preparation and adsorption performance of MnO2/PAC composite towards aqueous glyphosate

Hao Cui et al.

ENVIRONMENTAL TECHNOLOGY (2012)

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Article Engineering, Civil

Factors controlling micropollutant removal during riverbank filtration

Florian R. Storck et al.

JOURNAL AMERICAN WATER WORKS ASSOCIATION (2012)

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Article Environmental Sciences

Modeling biodegradation and kinetics of glyphosate by artificial neural network

Mohsen M. Nourouzi et al.

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES (2012)

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Article Environmental Sciences

Photocatalytic mineralization of glyphosate in a small-scale plug flow simulation reactor by UV/TiO2

Jian Q. Chen et al.

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES (2012)

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Article Environmental Sciences

Dissipation of glyphosate and aminomethylphosphonic acid in water and sediment of two Canadian prairie wetlands

Dani Degenhardt et al.

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES (2012)

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Article Engineering, Environmental

Drinking water obtaining by nanofiltration from waters contaminated with glyphosate formulations: Process evaluation by means of toxicity tests and studies on operating parameters

Hugo Saitua et al.

JOURNAL OF HAZARDOUS MATERIALS (2012)

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Article Engineering, Environmental

Nanofiltration process of glyphosate simulated wastewater

Z. Y. Liu et al.

WATER SCIENCE AND TECHNOLOGY (2012)

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Article Biochemical Research Methods

Effect of suppressor current intensity on the determination of glyphosate and aminomethylphosphonic acid by suppressed conductivity ion chromatography

Ioannis K. Dimitrakopoulos et al.

JOURNAL OF CHROMATOGRAPHY A (2010)

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Article Engineering, Chemical

Combining MBR and NF/RO membrane filtration for the removal of trace organics in indirect potable water reuse applications

Abdulhakeem Ali Alturki et al.

JOURNAL OF MEMBRANE SCIENCE (2010)

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Article Biochemical Research Methods

Studies on glyphosate-induced carcinogenicity in mouse skin: A proteomic approach

Jasmine George et al.

JOURNAL OF PROTEOMICS (2010)

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Article Pharmacology & Pharmacy

Glyphosate-based herbicides are toxic and endocrine disruptors in human cell lines

Celine Gasnier et al.

TOXICOLOGY (2009)

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Review Agronomy

Fate of glyphosate in soil and the possibility of leaching to ground and surface waters: a review

Ole K. Borggaard et al.

PEST MANAGEMENT SCIENCE (2008)

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Review Engineering, Chemical

Drawbacks of applying nanofiltration and how to avoid them: A review

B. Van der Bruggen et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2008)

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Article Environmental Sciences

Urban contributions of glyphosate and its degradate AMPA to streams in the United States

DW Kolpin et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2006)

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Article Agronomy

Glyphosate-resistant crops: history, status and future

GM Dill

PEST MANAGEMENT SCIENCE (2005)

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Review Engineering, Environmental

Factors affecting the rejection of organic solutes during NF/RO treatment - a literature review

C Bellona et al.

WATER RESEARCH (2004)

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Article Agriculture, Multidisciplinary

Comparison of the nutritional profile of glyphosate-tolerant corn event NK603 with that of conventional corn (Zea mays L.)

WP Ridley et al.

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2002)

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Review Medicine, Legal

Safety evaluation and risk assessment of the herbicide Roundup and its active ingredient, glyphosate, for humans

GM Williams et al.

REGULATORY TOXICOLOGY AND PHARMACOLOGY (2000)

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