期刊
WASTE MANAGEMENT
卷 172, 期 -, 页码 335-346出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2023.11.001
关键词
Shredder light fraction; Waste Electrical and Electronic Equipment; WEEE Recycling; Pyrolysis; Thermal treatment
This study focuses on the recycling of Shredder Light Fraction (SLF) from Waste Electrical and Electronic Equipment (WEEE) using pyrolysis treatment. The research successfully recovered valuable metals from SLF and transformed it into a valuable product for industrial use. Additionally, the study found that the non-condensable gas produced during pyrolysis has potential as an alternative energy source or reducing agent.
The surge in Waste Electrical and Electronic Equipment (WEEE) generation, reaching 53.6 million metric tons (Mt) in 2019, demands efficient recycling solutions. This study focuses on the Shredder Light Fraction (SLF), a material stream derived from the mechanical pre-processing of WEEE, which is considered municipal waste. SLF constitutes 4.2% of the output material and is rich in metals like copper, tin, lead, zinc, silver, and gold.Pyrolysis treatment was applied to SLF, enabling recyclability. Both batch and continuous setups were employed for materials flow analysis and technical evaluation of the resource potential. The research evaluates the impact of pyrolysis technology on solid fraction metal content and pyrolysis gas/oil energy potential. Scaling up the process addressed material heterogeneity and increased the reliability of the obtained results.An innovative pyrometallurgical extraction approach was suggested, to recover valuable metals in SLF which otherwise could be lost via energy recovery methods. The resulting solid product after pyrolysis showed enriched concentrations of copper, zinc, lead, and precious metals with concentrations acceptable for industrial use. Additionally, it displayed reduced mass and diminished hazardous constituents.The non-condensable gas, rich in hydrogen, carbon monoxide, and methane, exhibited potential as an alter-native energy source or reducing agent in the metallurgical sector.This research advances metal recycling from SLF, offering valuable insights for environmental impact mitigation as waste was transformed into a valuable by-product for potential use in the copper industry.
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