期刊
PARTICUOLOGY
卷 88, 期 -, 页码 116-127出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.partic.2023.08.020
关键词
Cathode slurry; Dispersion mechanism; Lithium-ion battery (LIB)
This paper presents the effects of PVDF/CB ratio and mixing time on the dispersion mechanism of the cathode slurry of lithium-ion battery. The study reveals that under specific conditions, a stable gel structure and conductive network can be formed, which can improve the performance of the battery.
This paper presents the effects of both poly vinylidene fluoride (PVDF)/carbon black (CB) ratio (mPVDF:mCB) and mixing time t on the dispersion mechanism of the cathode slurry of lithium-ion battery (LIB). The dispersion mechanism is deduced from the electrochemical, morphological and rheological properties of the cathode slurry by using electrical impedance spectroscopy (EIS), scanning electron microscopy and rheology methods, respectively. From the perspective of EIS method, static simulation models are established in the COMSOL Multiphysics software; meanwhile, the simulated results are used to verify the correctness of the electrochemical properties of the cathode slurry. As a result, the following conclusions are able to be obtained. Firstly, in the case of the mass ratio mPVDF:mCB= 5:10, LiCoO2 particles are completely coated by the mixture of CB and PVDF to form a stable polymer gel structure. Higher or lower mPVDF:mCB leads to the larger impedance and worse dispersion status for the cathode slurry. Secondly, when t = 6 min, a good gel-like conductive network structure is formed by coating the thinner evenly dispersed CB-PVDF double layer around LiCoO2 particles. Finally, a strategy regarding to both mPVDF:mCB and t in experimental scale is proposed, which has the capability of improving the performance of LIB. (c) 2023 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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