期刊
BATTERIES-BASEL
卷 9, 期 11, 页码 -出版社
MDPI
DOI: 10.3390/batteries9110558
关键词
silicon; p2D model; parametrization; validation; half-cell balancing
Silicon-dominant anode in lithium-ion batteries lacks an electrochemical model, and this work presents a validated parametrization for it. The model is based on electrode manufacturing values, lab cell measurements, and literature data, and is validated through charge/discharge tests.
Silicon is a promising anode material and can already be found in commercially available lithium-ion cells. Reliable modeling and simulations of new active materials for lithium-ion batteries are becoming more and more important, especially regarding cost-efficient cell design. Because literature lacks an electrochemical model for silicon-dominant electrodes, this work aims to close the gap. To this end, a Newman p2D model for a lithium-ion cell with a silicon-dominant anode and a nickel-cobalt-aluminum-oxide cathode is parametrized. The micrometer silicon particles are partially lithiated to 1200 mAh gSi-1. The parametrization is based on values from the electrode manufacturing process, measured values using lab cells, and literature data. Charge and discharge tests at six different C-rates up to 2C serve as validation data, showing a root-mean-squared error of about 21 mV and a deviation in discharge capacity of about 1.3%, both during a 1 C constant current discharge. Overall, a validated parametrization for a silicon-dominant anode is presented, which, to the best of our knowledge, is not yet available in literature. For future work, more in-depth studies should investigate the material parameters for silicon to expand the data available in the literature and facilitate further simulation work.
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