The study of alkaline earth metal complexes is experiencing a renaissance, with stable molecular species featuring Mg-Mg bonds being extensively investigated. In addition to the species with Mg-Mg bonds, newly synthesized complexes with Be-Be and Ca-Ca bonds have also gained attention. These studies have revealed a richer and more complex chemistry of the group 2 metals than previously appreciated.
The study of alkaline earth metal complexes is undergoing a renaissance. Stable molecular species featuring Mg-Mg bonds were reported in 2007 and their reactivity has since been intensively investigated. Motivated by this work, efforts have also been devoted to the synthesis of complexes featuring Be-Be and Ca-Ca bonds. These collective endeavours have revealed that the chemistry of the group 2 metals is richer and more complex than had previously been appreciated. Here, a discussion of the nature of homometallic alkaline earth bonding is presented, recent synthetic advances are described, and future directions are considered. A discussion of the nature of homometallic alkaline earth bonding is presented, recent synthetic advances are described, and future directions are considered.
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