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Heterometallic cages: synthesis and applications

CHEMICAL SOCIETY REVIEWS (2024)

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Article Chemistry, Multidisciplinary

Elaborating E/Z-Geometry of Alkenes via Cage-Confined Arylation Catalysis of Terminal Olefins

Yuanfan Wang et al.

Summary: A visible light photosensitizing metal-organic cage is used as an artificial supramolecular reactor to control the reaction of aryl radicals with terminal olefins, resulting in the selective transformation of geometrically defined E/Z-alkenes. The hydrophobic cage efficiently includes aromatic substrates, promoting Meerwein arylation and protecting E-isomeric products, while benzonitrile induces efficient E -> Z isomerization. In addition to pi-pi stacking, hydrogen bonding and halogen bonding interactions play a role in controlling the arylation of aliphatic terminal olefins. This switchable cage-confined arylation catalysis has been demonstrated in the syntheses of Tapinarof and a marine natural product, achieving controllable E/Z selectivity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Article Chemistry, Multidisciplinary

Effector Regulated Catalytic Cyclization of Alkynoic Acids Using Pt2L4 Cages

Eduard O. O. Bobylev et al.

Summary: Inspired by catalytic regulation in living cells, we developed a Pt2L4 cage whose activity can be controlled by binding effector molecules. The cage shows catalytic activity in the lactonization reaction, with the rate depending on the bound effector guest. Some effector guests enhance the rate by up to 19-fold, while one decreases it by 5-fold. When specific substrate mixtures are used, both starting materials and products act as guests, enhancing catalytic activity for one substrate and reducing it for the other. The addition of effector molecules enables the development of more complex, metabolic-like catalyst systems.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Article Chemistry, Multidisciplinary

The application of M12L24 nanocages as cell-specific siRNA delivery agents in vitro

Eduard O. Bobylev et al.

Summary: By introducing M12L24 cages as siRNA delivery agents, we successfully prepared stable 130 nm nanocage/siRNA assemblies and achieved cell-specific siRNA delivery and silencing effects based on the choice of metal used for nanocage formation. The ability to tune the delivery efficiency and stability of nanocages by different building blocks and metals shows potential for future siRNA delivery applications.

CHEM (2023)

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Review Chemistry, Multidisciplinary

Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis

Rens Ham et al.

Summary: Because sunlight is abundant and can generate excited states, it has great potential for practical applications in sustainable energy supply and organic synthesis. Photosensitizers and supramolecular coordination cages play crucial roles in harnessing light energy and facilitating close proximity of different components for photocatalysis. This review focuses on the application of supramolecular cages in artificial photosynthesis, organic photo(redox) catalysis, and provides inspiration for the future design of photocatalytic supramolecular host-guest systems.

CHEMICAL REVIEWS (2023)

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Article Chemistry, Multidisciplinary

Spin Crossover Induced by Changing the Identity of the Secondary Metal Ion from PdII to NiII in a Face-Centered FeII8MII6 Cubic Cage

Hyunsung Min et al.

Summary: Discrete spin crossover (SCO) heteronuclear cages have potential applications in molecular transport and catalysis. Substitution of the secondary metal center in the face of the cage resulted in SCO behavior, observed through magnetic susceptibility, Mossbauer spectroscopy, and single crystal X-ray diffraction. Comparisons of the structural differences between the two cages shed light on the interplay of inter- and intramolecular interactions associated with SCO in the Ni-II analogue.

CHEMISTRY-A EUROPEAN JOURNAL (2023)

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Article Chemistry, Multidisciplinary

Constructing Ultrastable Metallo-Cages via In Situ Deprotonation/Oxidation of Dynamic Supramolecular Assemblies

Pingru Su et al.

Summary: Coordination-driven self-assembly allows for the spontaneous construction of highly precise metallo-supramolecules through dynamic and reversible metal-ligand interactions. However, the dynamic nature of coordination often leads to structural instability in many metallo-supramolecular assembly systems. In this study, an acid-/base-responsive tridentate ligand is incorporated into multitopic building blocks to achieve self-assembly reversibility and structural stability in metallo-supramolecular cages. The in situ transformation of these dynamic assemblies provides a reliable approach to manipulate the kinetic features and stability of metallo-supramolecules and enables modulation of encapsulation and release behaviors when utilizing nanoscale quantum dots (QDs) as guest molecules.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

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Article Chemistry, Multidisciplinary

Creating Dynamic Nanospaces in Solution by Cationic Cages as Multirole Catalytic Platform for Unconventional C(sp)-H Activation Beyond Enzyme Mimics

Kang Li et al.

Summary: In this study, we demonstrate the accomplishment of multirole and multi-way cage-confined catalysis by creating dynamic nanospaces in solution using highly charged positive coordination cage of [Pd-6(RuL3)(8)](28+). The biomimetic cage effect enables versatile functions and anomalous reactivities, and the amphoteric heterogeneity generated by partial deprotonation of imidazole-NHs on cage sphere enhances cavity-basicity against solution-acidity. The synergistic actions of cage hydrophobicity, host-guest electrostatic interactions, and imidazole-N coordination facilitate various catalytic reactions and phase transfers, providing a useful catalytic protocol that combines the merits of different types of catalysis.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Heterotrimetallic Double Cavity Cages: Syntheses and Selective Guest Binding

Lynn S. Lisboa et al.

Summary: A strategy for generating heterotrimetallic double cavity cages and their interactions with different guest molecules were reported. The structures of the cages and their selective binding behavior were studied through various spectroscopic techniques. The results provide insights into the design and synthesis of multifunctional host-guest systems.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Review Chemistry, Inorganic & Nuclear

Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances

Marta Viciano-Chumillas et al.

Summary: The synthesis of mixed-component metal-organic frameworks (MOFs) is a rapidly growing research field, offering unique possibilities to incorporate multiple functionalities and properties that are not simply the sum of each component. Despite challenges, promising ways to utilize the intrinsic properties of mixed-components MOFs for breakthroughs in catalysis and nanotechnology are presented through exemplary cases.

COORDINATION CHEMISTRY REVIEWS (2022)

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Review Chemistry, Multidisciplinary

Zirconium Metal-Organic Cages: Synthesis and Applications

El-Sayed M. El-Sayed et al.

Summary: In recent years, the synthesis of porous crystalline materials, such as metal-organic frameworks and organic cages, with tunable atomic structures has shown great potential in various fields. Discrete metal-organic cages, in particular, have attracted attention due to their molecular nature and solution-processability. The zirconium MOC family, known for its robust nature and high hydrothermal stability, holds significant potential for expanding applications. This Account highlights recent advances in synthesizing zirconium MOCs and their applications in higher-dimensional frameworks.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

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Article Chemistry, Inorganic & Nuclear

Self-Assembly of a Pd4Cu8L8 Cage for Epoxidation of Styrene and Its Derivatives

Xian-Chao Zhou et al.

Summary: We report a discrete heterometallic Pd4Cu8L8 cage with a tubular structure, which was synthesized by the assembly of copper metalloligands and PdII ions in a stepwise manner. The cage exhibited excellent catalytic activity in the epoxidation of styrene and its derivatives under conditions without using additional solvent, providing potential materials for catalyzing oxidation reactions.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Incorporation of a Phosphino(pyridine) Subcomponent Enables theFormation of Cages with Homobimetallic and Heterobimetallic Vertices

John P. Carpenter et al.

Summary: This article demonstrates the preparation of metal-organic cages containing either homobimetallic or heterobimetallic vertices. The researchers successfully prepared two different structures of cages in the experiment, showcasing novel multimetallic assemblies.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Review Chemistry, Multidisciplinary

Post-synthetic modifications of metal-organic cages

Jinjin Liu et al.

Summary: This review explores the post-synthetic modification strategies for metal-organic cages (MOCs) and details the effects of newly introduced functional groups on MOCs. The development of this research provides systematic approaches for the development and characterization of MOC families and offers insights into the structure-function relationships for future developments.

NATURE REVIEWS CHEMISTRY (2022)

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Article Biochemistry & Molecular Biology

Bioinorganic supramolecular coordination complexes and their biomedical applications

Guillermo Moreno-Alcantar et al.

Summary: Bioinorganic supramolecular chemistry is an emerging research field focusing on the metal-based supramolecules formed through coordination-driven self-assembly. These versatile materials have broad applications in biomedicine, including molecular recognition, biosensing, therapy, imaging, and drug delivery. This review provides an overview of the state-of-the-art use of these systems in biomedicine, along with selected representative examples and future directions.

FEBS LETTERS (2022)

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Article Chemistry, Multidisciplinary

Differentiable Formation of Chiroptical Lanthanide Heterometallic LnnLn'4-n(L6) (n=0-4) Tetrahedra with C2-Symmetrical Bis(tridentate) Ligands

King-Him Yim et al.

Summary: Construction of chiral lanthanide heterometallic tetrahedra was achieved by crystallization of a mixture of [Eu2L3] and [Ln(2)L(3)] (Ln=Gd, Tb and Dy) helicates. Selective formation of heterometallic tetrahedron was observed due to the sensitivity to ionic radii and the ratio of the two helicates used in the crystallization.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

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Article Chemistry, Inorganic & Nuclear

Assembly of a Heterometallic Cu(II)-Pd(II) Cage by Post-assembly Metal Insertion

Mei Tieng Yong et al.

Summary: This study presents the self-assembly and structure of a multi-metallic motif-based Cu-II metal-organic cage (MOC) functionalized with free bis(pyrazolyl)methane sites. PdII chloride can be quantitatively inserted into the MOC, resulting in a heterometallic cage structure. The choice of solvent in the metalation process determines the solid-state isomerism of the cage, providing a means to control the MOC's structural diversity and permanent porosity.

INORGANIC CHEMISTRY (2022)

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Article Biochemistry & Molecular Biology

Size-Induced Highly Selective Synthesis of Organometallic Rectangular Macrocycles and Heterometallic Cage Based on Half-Sandwich Rhodium Building Block

Li-Long Dang et al.

Summary: The controlled synthesis of organometallic supramolecular macrocycle cages is still an interesting and challenging work. In this study, two tetranuclear rectangular macrocycles and one octuclear cage were successfully designed and synthesized using a rigid and functionalized pillar linker. The size and spacing of the building blocks directly influenced the structure of the products. The octuclear cage displayed significant characteristics of heterogeneous metal-assembling compounds and exhibited host-guest behavior.

MOLECULES (2022)

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Review Chemistry, Inorganic & Nuclear

Coordination/metal-organic cages inside out

Tomoki Tateishi et al.

Summary: Cage-like molecules formed by the coordination of metal ions and organic links have unique chemical properties and design flexibility, and are pushing the boundaries of science. This review article compares coordination cages (CCs) and metal-organic cages (MOCs) from two distinct chemistry communities, highlighting their similarities and differences. The article provides insights into synthetic conditions and identifies new research directions in the field.

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Chemistry, Inorganic & Nuclear

Stereocontrolled Self-Assembly of Ln(III)-Pt(II) Heterometallic Cages with Temperature-Dependent Luminescence

Qiang-Yu Zhu et al.

Summary: This study demonstrates the stereocontrolled syntheses of a series of LnIII-PtII heterometallic cages through coordination-driven self-assembly. The designed alkynylplatinum ligands extend the excitation window for sensitized near-infrared (NIR) luminescence and show potential applications as luminescent temperature sensors.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Inorganic & Nuclear

Hydrazone- and imine-containing [PdPtL4]4+ cages: a comparative study of the stability and host-guest chemistry

Lynn S. Lisboa et al.

Summary: A new [PdPtL4](4+) heterobimetallic cage containing hydrazone linkages was synthesized using the sub-component self-assembly approach. The cage showed stimulus-responsive behavior and was more stable against hydrolysis compared to a previously synthesized imine-containing cage. It interacted with cisplatin, while the smaller imine cage interacted with 5-fluorouracil and oxaliplatin.

DALTON TRANSACTIONS (2022)

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Article Chemistry, Multidisciplinary

Self-Assembly of a Rare High Spin FeII/PdII Tetradecanuclear Cubic Cage Constructed via the Metalloligand Approach

Hyunsung Min et al.

Summary: In this study, a new tetradecanuclear heterobimetallic coordination cage was synthesized and characterized. The tripodal high-spin Fe(II) metalloligand was prepared using the metalloligand approach and used to form the coordination cage structure. Magnetic and structural analyses provided insight into the structural changes and transfer of the magnetic environment.

CHEMISTRY-SWITZERLAND (2022)

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Review Chemistry, Multidisciplinary

Progress in the catalytic reactions of CO2 and epoxides to selectively provide cyclic or polymeric carbonates

Gulzar A. Bhat et al.

Summary: Sustainability requires the reuse of carbon sources from CO2 emissions, making carbon capture and utilization essential. Coupling of oxiranes (epoxides) with CO2 can generate cyclic carbonates and polymeric materials, providing a potential solution. It is important to use epoxides derived from renewable resources for a sustainable process.

GREEN CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

Transformation networks of metal-organic cages controlled by chemical stimuli

Elie Benchimol et al.

Summary: The flexibility of biomolecules and coordination cages allows them to undergo adaptive and stimuli-triggered transformations, leading to various applications. This review highlights recent advances in the transformation of coordination cages using chemical and external stimuli, and presents new perspectives on designing transformation networks.

CHEMICAL SOCIETY REVIEWS (2022)

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Review Chemistry, Multidisciplinary

Metallosupramolecular cages: from design principles and characterisation techniques to applications

Anna J. McConnell

Summary: This tutorial review introduces the principles for designing metallosupramolecular cages, with a focus on the design of large and lower symmetry cages. The characterization and identification of cages rely on complementary techniques such as NMR spectroscopy, mass spectrometry, X-ray crystallography, and computational methods. Finally, examples of cages are discussed where these design principles and characterization techniques are applied for specific applications or functions of the cages.

CHEMICAL SOCIETY REVIEWS (2022)

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Article Chemistry, Multidisciplinary

Backbone-Bridging Promotes Diversity in Heteroleptic Cages

Kai Wu et al.

Summary: By introducing covalent backbone bridges, the assembly structure can be diversified, and with the solvent and guest effects, it can modulate nuclearity, topology, and number of cavities. The nature of the linker in ligands would affect the structure of the assembly under different solvent conditions, resulting in different structural forms.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Metal-organic cages for molecular separations

Dawei Zhang et al.

Summary: Metal-organic cages, formed via coordination-driven self-assembly, show great promise as separation agents by selectively binding and distinguishing substances in solution through precise control of their structure. The use of cages as absorbents or incorporation into polymer membranes can enhance the efficiency and selectivity of separation processes. Challenges and potential future developments in using metal-organic cages for separations are also discussed.

NATURE REVIEWS CHEMISTRY (2021)

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Article Biochemistry & Molecular Biology

[(Cr8Ni6II)-Ni-III](n+) Heterometallic Coordination Cubes

Helen M. O'Connor et al.

Summary: Three new heterometallic coordination cubes have been synthesized using a paramagnetic metalloligand and corresponding Ni-II salt, showing weak ferromagnetic interactions between Cr-III and Ni-II ions. These compounds expand the structurally related family of heterometallic cubes containing Cr-III and Ni-II ions, demonstrating a modular approach to building related polymetallic complexes.

MOLECULES (2021)

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Review Chemistry, Multidisciplinary

Supramolecular Coordination Complexes as Optical Biosensors

Nilanjan Dey et al.

Summary: In recent years, luminescent supramolecular coordination complexes have been used for biomolecular analysis, with tunable structures for great selectivity and sensitivity. The research aims to explore the application of these complexes in detecting various biomolecules effectively.

CHEMPLUSCHEM (2021)

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Article Chemistry, Multidisciplinary

Gridlike 3d-4f heterometallic macrocycles for highly efficient conversion of CO2 into cyclic carbonates

Huan Yang et al.

Summary: The study successfully constructed two unique gridlike 3d-4f heterometallic structures Ln8Zn4L6, which greatly increased the efficiency of CO2 fixation and promoted the catalysis of CO2 at greener conditions. This heterometallic design also showed enhanced stability without being influenced by moisture and impurities.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Multidisciplinary

A Family of Heterobimetallic Cubes Shows Spin-Crossover Behaviour Near Room Temperature

Matthias Hardy et al.

Summary: The study utilized 4-(4 '-pyridyl)aniline as an organic building block in combination with three different aldehyde components and metal(II) salts to synthesize three different Fe8Pt6-cubes and their corresponding Zn8Pt6 analogues through the subcomponent self-assembly approach. The structures obtained using iron(II) salts exhibited spin-crossover behavior in solution, while the ones obtained using zinc(II) salts were diamagnetic. The spin-transition temperature T-1/2 was found to vary depending on the aldehyde component used, providing a construction kit for the deliberate synthesis of spin-crossover compounds with tailored transition properties.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

High-Throughput Computational Evaluation of Low Symmetry Pd2L4 Cages to Aid in System Design**

Andrew Tarzia et al.

Summary: Research shows that unsymmetrical ditopic ligands can form Pd2L4 metallo-cages, but mixtures of cage isomers may occur, highlighting the need to design components that preferentially form a single isomer. Computational workflow can accurately predict whether unsymmetrical ligands will preferentially form a single cage isomer, reducing the need for trial-and-error synthetic approaches.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

How to Prepare Kinetically Stable Self-assembled Pt12L24 Nanocages while Circumventing Kinetic Traps

Eduard O. Bobylev et al.

Summary: Supramolecular coordination-based self-assembled nanostructures have been widely studied, with a focus on designing kinetically stable Pt12L24 nanospheres. It was found that the rigidity of the ditopic ligand is a key parameter in the controlled formation of these nanospheres. Coordination additives are needed to selectively form Pt12L24 assemblies, which are stable in the presence of chloride, amines and acids unlike their palladium analogues.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Coordination of a Potentially Tritopic Ligand via Phosphorus, Nitrogen and Oxygen: From Ligand Design to Heterobimetallic Metal-Organic Frameworks and Supramolecules

Hans Gildenast et al.

Summary: The tritopic heterofunctional ligand combines hard, soft, and very soft donor groups in one molecule, selectively binding to different metal cations to form discrete aggregates and extended structures. The structures of the resulting complexes with different metal cations were characterized using spectroscopic methods, showcasing a variety of coordination sites and porous metal-organic frameworks.

CRYSTAL GROWTH & DESIGN (2021)

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Article Chemistry, Inorganic & Nuclear

Controlling the Self-Assembly of Metal-Cages organic and transdermal drug delivery

Xiao-Chang Liu et al.

Summary: The metallacages described in this study contain 1,2,3-triazole-4,5-dicarboxylic acid ligands with different linkers, exhibiting flexible coordination modes. Metallamacrocycles with h3tzdc ligands are rarely documented, as are metallacages with coordinate modes involving three metal centers. Further synthesis of complexes and analysis of their in vitro drug release and skin penetration are needed to establish definitive structure-function correlations.

INORGANIC CHEMISTRY COMMUNICATIONS (2021)

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Review Chemistry, Inorganic & Nuclear

Structural variation of self-assembled lanthanide supramolecular complexes induced by reaction conditions

King-Him Yim et al.

Summary: The chemistry of lanthanide supramolecular self-assembly has attracted much attention, with the discovery of extraordinary structures due to unique photophysical properties. Recent investigations have shown the sensitivity of these structures to different stimuli, leading to the preparation of specific properties in desired supramolecular topologies. Additionally, transformation from lower to higher order supramolecular systems has been observed due to the labile nature of lanthanide ions.

INORGANIC CHEMISTRY FRONTIERS (2021)

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Review Chemistry, Multidisciplinary

Recent developments in organocatalysed transformations of epoxides and carbon dioxide into cyclic carbonates

Liping Guo et al.

Summary: This review focuses on the rapidly evolving field of organocatalysed cyclic carbonate synthesis, covering mechanisms, catalyst systems, key parameters, and future challenges. The importance of green metrics and catalyst requirements are highlighted throughout the article.

GREEN CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

The rise of metal-organic polyhedra

Soochan Lee et al.

Summary: Metal-organic polyhedra, as a type of metal-organic material, are emerging porous platforms used in energy and bio-related sciences, but have been less explored compared to their framework counterparts. This review covers the topologies and classification of metal-organic polyhedra and provides suggestions for future directions in this rapidly growing field that may benefit synthetic chemists.

CHEMICAL SOCIETY REVIEWS (2021)

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Visible-Light Photocatalysis of Asymmetric [2+2] Cycloaddition in Cage-Confined Nanospace Merging Chirality with Triplet-State Photosensitization

Jing Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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The Redox Coupling Effect in a Photocatalytic RuII-PdII Cage with TTF Guest as Electron Relay Mediator for Visible-Light Hydrogen-Evolving Promotion

Kai Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Dynamic Complex-to-Complex Transformations of Heterobimetallic Systems Influence the Cage Structure or Spin State of Iron(II) Ions

Matthias Hardy et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Metal-Organic Cages (MOCs): From Discrete to Cage-based Extended Architectures

El-Sayed M. El-Sayed et al.

CHEMISTRY LETTERS (2020)

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A Rare Example of a Complete, Incomplete, and Non-Occurring Spin Transition in a [Fe2L3]X4 Series Driven by a Combination of Solvent and Halide-Anion-Mediated Steric Factors

Alexander R. Craze et al.

INORGANIC CHEMISTRY (2020)

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A Reduced-Symmetry Heterobimetallic [PdPtL4]4+ Cage: Assembly, Guest Binding, and Stimulus-Induced Switching

Lynn S. Lisboa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Guest Binding Drives Host Redistribution in Libraries of CoII4L4 Cages

Marion Kieffer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Better Together: Functional Heterobimetallic Macrocyclic and Cage-like Assemblies

Matthias Hardy et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Planar 2-Pyridyl-1,2,3-triazole Derived Metallo-ligands: Self-assembly with PdCl2 and Photocatalysis

Natalie R. Lagesse et al.

CHEMISTRY-AN ASIAN JOURNAL (2020)

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No, Not That Way, the Other Way: Creating Active Sites in Self-Assembled Host Molecules

Richard J. Hooley

SYNLETT (2020)

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Heterometallic Titanium-Organic Frameworks by Metal-Induced Dynamic Topological Transformations

Natalia M. Padial et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Metallo-Supramolecular Self-Assembly with Reduced-Symmetry Ligands

James E. M. Lewis et al.

CHEMPLUSCHEM (2020)

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One-/Two-Photon Excited Cell Membrane Imaging and Tracking by a Photoactive Nanocage

Ya-Ping Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Covalent Post-Assembly Modification: A Synthetic Multipurpose Tool in Supramolecular Chemistry

Haoxiang Zeng et al.

CHEMPLUSCHEM (2020)

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Metal-Organic Frameworks and Metal-Organic Cages - A Perspective

Ben S. Pilgrim et al.

CHEMPLUSCHEM (2020)

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Cage-confined photocatalysis for wide-scope unusually selective [2+2] cycloaddition through visible-light triplet sensitization

Jing-Si Wang et al.

NATURE COMMUNICATIONS (2020)

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Reversible regulation of esterase activity via host-guest molecular recognition at the nanoparticle surface

Meenakshi Pahwa et al.

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LaIII and ZnII Cooperatively Template a Metal-Organic Capsule

Dong Yang et al.

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Coordination cages in catalysis

Rebecca J. Severinsen et al.

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Postsynthetic Covalent and Coordination Functionalization of Rhodium(II)-Based Metal-Organic Polyhedra

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Photosubstitution reactions in ruthenium(II) trisdiimine complexes: Implications for photoredox catalysis

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Post-assembly Modification of Phosphine Cages Controls Host-Guest Behavior

Charlie T. McTernan et al.

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Redox-Guest-Induced Multimode Photoluminescence Switch for Sequential Logic Gates in a Photoactive Coordination Cage

Kai Wu et al.

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Stabilizing Metal-Organic Polyhedra (MOP): Issues and Strategies

Samraj Mollick et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

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Navigated Self-Assembly of a Pd2L4 Cage by Modulation of an Energy Landscape under Kinetic Control

Tomoki Tateishi et al.

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CO2 hydrogenation to high-value products via heterogeneous catalysis

Run-Ping Ye et al.

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Metalloligand Strategies for Assembling Heteronuclear Nanocages - Recent Developments

Feng Li et al.

AUSTRALIAN JOURNAL OF CHEMISTRY (2019)

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Redox active [Pd2L4]4+ cages constructed from rotationally flexible 1,1′-disubstituted ferrocene ligands

Roan A. S. Vasdev et al.

CHEMICAL COMMUNICATIONS (2019)

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Review Chemistry, Inorganic & Nuclear

Heterometallic grids: synthetic strategies and recent advances

Qianqian Yang et al.

DALTON TRANSACTIONS (2019)

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Review Chemistry, Multidisciplinary

Photoactive supramolecular cages incorporating Ru(ii) and Ir(iii) metal complexes

Diego Rota Martir et al.

CHEMICAL COMMUNICATIONS (2019)

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Self-assembly of discrete cyclic nanostructures mediated by transition metals

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