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Article
Chemistry, Physical
Yihan Yang et al.
Summary: By designing an aqueous electrolyte with a weakly solvating effect, a durable anion-derived solid electrolyte interface (SEI) with high ion conduction properties is constructed, which significantly restrains dendrite formation and adverse reactions on the Zn anode surface, leading to high reversibility of deposition/stripping, ultra-long lifespan over 5000 h, and exceptional cumulative capacity. The formation mechanism of SEI and the composition distribution of anion-derived inorganic-rich SEI are clarified in detail. Furthermore, the Zn//Prussian blue analogue (PBA) full battery exhibits a high voltage platform of 2.1 V and delivers 99.3% capacity retention after 5000 cycles, benefiting from the synergy of the elaborate SEI and regulated electrolyte environment.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Haijian Huang et al.
Summary: In this study, the addition of CMC electrolyte additive in AZICs successfully addresses the performance issues caused by zinc deposition and parasitic reactions. The CMC additive can adsorb onto the (101) facet of zinc, preventing the formation of zinc dendrites. Moreover, the interaction of CMC with Zn2+ alters the solvation structure and suppresses water-induced side reactions. This strategy significantly improves the cyclic stability of the zinc anode at both low and high rates, thus promoting the comprehensive performance of AZICs.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Guojin Liang et al.
Summary: A highly effective solid-electrolyte interphase (SEI) for improving the reversibility of the Zn metal anode (ZMA) was constructed using a bisolvent electrolyte, and its composition/structure was resolved by cryogenic transmission electron microscopy. The resulting SEI is highly fluorinated with amorphous inorganic ZnFx uniformly distributed in the organic matrix, which is different from common mosaic and multilayer SEIs with crystalline inorganics. This SEI exhibits improved structural integrity, mechanical toughness, and Zn2+ ion conductivity, leading to excellent reversibility of the ZMA.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Shuo Jin et al.
Summary: Polymers can spontaneously adsorb onto high-energy substrates from liquid solutions, forming configurationally complex and durable phases with higher durability than expected. Controlling the physical, chemical, and transport properties of these interphases is crucial for advancing energy storage technology. In this study, the interfacial adsorption of oligomeric polyethylene glycol (PEG) chains in different liquid electrolytes was analyzed, revealing an optimum polymer molecular weight of approximately 400 Da for achieving the highest columbic efficiency in both Zn and Li deposition. These findings provide a simple and versatile approach for extending battery lifetime.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Cong Huang et al.
Summary: This study proposes a molecular design strategy for developing solid electrolyte interphase (SEI)-forming additives for zinc (Zn) anodes. The sulfonamide-containing additives enhance the cycle stability and lifespan of Zn anodes by forming a robust SEI layer. The experimental results demonstrate the versatility of this strategy in different electrolytes and electrode materials.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Zixuan Zhou et al.
Summary: Designed an antifreeze hydrogel electrolyte for low-temperature Zn||LFP battery, which exhibits stable charging/discharging, high elasticity, and high ionic conductivity. The battery displays outstanding cycle stability, subzero-temperature operation, and mechanical safety.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Peixun Xiong et al.
Summary: A stable Zn5(CO3)2(OH)6 solid electrolyte interphase (SEI) was formed on the surface of Zn anodes using hybrid electrolytes, resulting in dendrite-free Zn plating/stripping. The Zn5(OH)6(CO3)2-contained SEI exhibited high ionic conductivity and fast Zn2+ migration, enabling the development of stable Zn-ion hybrid capacitors with high performance at various temperatures. The hybrid capacitors showed excellent capacity retention and Coulombic efficiency over a large number of cycles.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Yu Liu et al.
Summary: In this study, glycine is used as an additive to modulate the solvation shell structure and enhance the interfacial stability of aqueous Zn ion batteries. The results show that the cycle life of the symmetrical cells reaches over 3200 h in glycine-containing electrolytes, and the Zn//NVO full cell exhibits exceptional cycling stability for 3000 cycles at 5 A g-1. Therefore, the proposed strategy for interfacial chemistry modulation, represented by glycine, has considerable potential in promoting the commercialization progress of aqueous batteries.
Article
Chemistry, Multidisciplinary
Yang Yang et al.
Summary: A SiO2 reinforced-sodium alginate (SA) hybrid film is designed to regulate the solid-liquid interaction energy and spatial distribution of species in the electric double layer (EDL) near the Zn electrode. The reconfigured EDL ensures dendrite-free Zn deposition and eliminates interface parasitic side reactions.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Wei Zhang et al.
Summary: In this study, a multifunctional additive NHP was introduced to regulate zinc deposition and suppress side reactions in aqueous electrolyte. The results showed that the NHP additive enabled highly reversible Zn plating/stripping behaviors, and improved the electrochemical performances of zinc-ion batteries and zinc-based capacitors.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Zefang Yang et al.
Summary: This study presents the design of a semi-solid zinc slurry anode consisting of zinc powder and zincophilic tin additive, which addresses some issues of zinc metal anodes and has the potential to extend the lifespan of the battery in practical applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Dan Xie et al.
Summary: A high-quality and ZnF2-riched inorganic/organic hybrid solid electrolyte interface (SEI) layer was constructed on the surface of Zn metal anode (ZMA) by introducing multifunctional fluoroethylene carbonate (FEC) into aqueous electrolyte. The addition of FEC effectively regulated the solvated structure of Zn2+ and hindered the formation of dendrites, thus suppressing dendrites growth and parasitic reactions. The ZMA in FEC-included ZnSO4 electrolyte exhibited a long cycle life and stable coulombic efficiency.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Sailin Liu et al.
Summary: To stabilize the zinc anode in zinc metal batteries, researchers have developed a controlled electrolytic method using a high dipole moment solvent dimethyl methylphosphonate (DMMP) to create a monolithic solid electrolyte interphase (SEI). This DMMP-based electrolyte generates a homogeneous and robust phosphate SEI (Zn-3(PO4)(2) and ZnP2O6). With the protection provided by this in situ monolithic SEI, the zinc electrode exhibits long-term cycling performance and high Coulombic efficiency in both zinc|zinc and zinc|copper cells. The use of a DMMP-H2O hybrid electrolyte in a full V2O5|zinc battery also results in high capacity retention following a large number of cycles.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Environmental
Hongyan Yuan et al.
Summary: To address the issues of self-corrosion and uneven deposition of zinc anode in alkaline nickel-zinc batteries, polyethylene glycol (PEG-300) was introduced as an electrolyte additive. PEG-300 can selectively adsorb on the zinc anode to form a protective layer, inhibiting the tip effect and limiting the lateral diffusion of [Zn(OH)4]2-. Moreover, the long-chain molecules of PEG suppress the diffusion of [Zn(OH)4]2- from the surface of zinc anode to the bulk electrolyte, thereby inhibiting self-corrosion. Experimental results demonstrate that the assembled Ni-Zn battery with 2% PEG additive exhibits an ultra-long cycling life and excellent performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Tingting Wei et al.
Summary: Guided by metal-coordination chemistry, a multifunctional electrolyte additive, sulfolane (SL), is introduced into aqueous ZnSO4 electrolyte to achieve stable and reversible zinc-ion batteries. The SL molecules can simultaneously modulate Zn2+ solvation structure and anode/electrolyte interface, leading to improved stability and performance. This electrolyte engineering technique protects the Zn anode from detrimental side-reactions and enables high reversibility and outstanding stability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Aosai Chen et al.
Summary: The researchers developed a multifunctional coating called PVA@SR-ZnMoO4 on the Zn anode, which consists of an outer layer PVA@SR to enhance flexibility and Zn2+ mobility, and an inner layer ZnMoO4 to inhibit dendrite growth and side reactions. The cooperation between these layers improved the performance of the Zn anode.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Review
Chemistry, Multidisciplinary
Pengchao Ruan et al.
Summary: This review comprehensively summarizes the rational design strategies of high-energy-density zinc batteries, critically analyzes the positive effects and potential issues of these strategies, and outlines the challenges and perspectives for further development.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Rui Yao et al.
Summary: This study introduces a dual-function electrolyte additive to address severe side reactions over zinc metal anodes in aqueous zinc metal batteries, resulting in stable cycling for over 2145 hours. The strategy also enhances the reversibility of energy storage devices based on manganese dioxide and activated carbon.
ADVANCED ENERGY MATERIALS
(2022)
Article
Multidisciplinary Sciences
Bingyao Zhang et al.
Summary: This study effectively addresses the issues of dendrite growth and side reactions in zinc-ion batteries by using a highly-confined tannic acid modified sodium alginate composite gel electrolyte. The modified electrolyte guides and regulates zinc deposition, resulting in steady zinc plating/stripping behavior and high cycle stability.
Article
Chemistry, Multidisciplinary
Xueyu Nie et al.
Summary: It is reported that introducing cholinium cations into aqueous electrolytes enables a compact and non-dendritic Zn electrode with excellent electrochemical performances. The bulky cholinium cations create a leveling effect to homogenize Zn deposition and disrupt the original H-bonded network of water, reducing side reactions and promoting Zn2+ de-solvation. The optimized electrolyte shows remarkable Coulombic efficiency and cycling stability in Zn batteries.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jin-Lin Yang et al.
Summary: A polyanionic hydrogel film is introduced as a protective layer on the Zn anode. It balances the transport of zinc ions and effectively suppresses hydrogen evolution and dendrite formation, enabling stable and reversible Zn stripping/plating.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Hongyang Wang et al.
Summary: In this study, a robust flexible aqueous zinc-ion hybrid supercapacitor (ZHSC) was fabricated using an anti-freezing and anti-drying organohydrogel electrolyte. The electrolyte showed good conductivity and stable flexibility, and the ZHSC exhibited resistance to mechanical damage. It achieved high energy and power densities, broad temperature adaptability, and retained capacitance after storage and cycling tests.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Chang Li et al.
Summary: This study introduces a novel additive that effectively solves the issues in aqueous zinc-metal batteries, leading to excellent cycling performance and efficient zinc deposition.
Article
Chemistry, Physical
Zefang Yang et al.
Summary: This study demonstrates that surface heterogeneity mainly affects zinc dendrite formation at low current density, and proposes a method to reconstruct the electrochemical interface to achieve more uniform zinc deposition and dissolution, thereby improving the cycling stability and Coulombic efficiency of zinc anodes.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Yi Liu et al.
Summary: By adding phosphoric acid to zinc electrolyte, the growth of zinc electrode can be made more uniform and reversible. This approach not only improves the cycling stability and rate capability of zinc-MnO2 batteries, but also makes aqueous zinc metal batteries competitive for practical applications.
ENERGY STORAGE MATERIALS
(2022)
Article
Engineering, Environmental
Huibo Yan et al.
Summary: By introducing an artificial solid electrolyte interphase (SEI) with a rich electron-donating functional group (cyano group), the desolvation process of zinc anode in aqueous zinc ion batteries (AZIBs) can be improved, leading to lower polarization, higher cycling efficiency, and longer cycle life.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Kang Zhao et al.
Summary: This study demonstrates the potential of cyclodextrins (CDs) as electrolyte additives for rechargeable Zn batteries. The addition of alpha-CD improves the stability and kinetics of Zn plating and stripping by adsorbing on the Zn surface and suppressing water-induced side reactions. This finding provides insight into the use of supramolecular macrocycles for enhancing the performance of aqueous battery chemistry.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Nanoscience & Nanotechnology
Ruoqian Lin et al.
Summary: This study investigates the interface structure and chemistry of lithium-polyacrylate electrolyte using advanced cryo-EM imaging and spectroscopic techniques, finding that no protective interphase forms as previously believed. The introduction of additive engineering effectively protects the lithium metal surface against corrosion and improves the cycle life of batteries.
NATURE NANOTECHNOLOGY
(2022)
Article
Multidisciplinary Sciences
Lin Ma et al.
Summary: Research shows that using methanol as an electrolyte solvent in rechargeable zinc metal batteries improves performance and stability, effectively solving issues in the battery, and has good cycle life at extreme temperatures.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Chemistry, Physical
Jizhang Chen et al.
Summary: In this study, an ionic liquid, 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([BMIM]OTF), was used as an additive in aqueous zinc-ion batteries to improve their performance at low temperatures. The additive preferentially adsorbs on the zinc electrode, forming a zincophilic and hydrophobic organic/inorganic hybrid solid electrolyte interphase layer. This layer reduces the nucleation overpotential of zinc plating, enhances interfacial charge transfer kinetics, and inhibits parasitic side reactions.
ENERGY STORAGE MATERIALS
(2022)
Article
Multidisciplinary Sciences
Ruirui Zhao et al.
Summary: Researchers propose a new electrolyte formulation for aqueous zinc batteries, which involves the addition of lanthanum nitrate to improve the surface morphology of the electrode, enhancing the battery performance and cycle life.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Chao Meng et al.
Summary: This study proposes an effective strategy for improving the performance of rechargeable aqueous zinc-ion batteries by adding β-cyclodextrin (β-CD) as an electrolyte additive. The simulation results show that β-CD can control the diffusion and deposition of zinc ions, preventing dendrite formation and the generation of insulating by-products. Experimental results demonstrate that the addition of β-CD enables ultra-long stable cycling and remarkable stability.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Huibo Wang et al.
Summary: By introducing sericin molecules as an electrolyte additive, a stable solid-electrolyte-interface (SEI) layer is constructed to modulate the Zn nucleation and overpotential of hydrogen evolution in order to improve the performance of aqueous zinc-ion batteries (ZIBs). The Zn|Zn symmetric cells with sericin additives exhibit an extremely prolonged cycling lifetime and high Coulombic efficiency, while the assembled full cells using Na2V6O16 center dot 3H(2)O cathodes also demonstrate good cycling stability.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Meijia Qiu et al.
Summary: By introducing beta-cyclodextrin as an anion-trap agent in zinc batteries, the deposition and migration behaviors of zinc anodes are improved, leading to enhanced stability and capacity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Bo Liu et al.
Summary: Designing a stable water-deficient solvation sheath through ligand substitution can protect the zinc metal anode and achieve fast nucleation/dissolution while suppressing the HER. The solvation energy shows a strong correlation with Zn nucleation/dissolution kinetics and HER inhibition ability, displaying a classic volcano behavior.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Dongdong Wang et al.
Summary: N-methyl pyrrolidone (NMP) is developed as a bifunctional electrolyte additive to improve the electrochemical performance of Zn anode, protecting it from corrosion and facilitating uniform plating/stripping of Zn.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Yanqun Lv et al.
Summary: This study demonstrates the use of zwitterionic ionic liquids (ZIL) to construct a self-adaptive electric double layer (EDL) in zinc metal batteries, enabling dendrite-free plating/stripping and high zinc utilization. The Zn//NaV3O8 center dot 1.5H(2)O full battery exhibits superfast charging/discharging and high areal capacity.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Jiahui Zhou et al.
Summary: By synthesizing a nitrogen-doped graphene oxide film on zinc foil, this study effectively suppresses hydrogen evolution reactions and passivation, improving the electrochemical performance of aqueous Zn-ion batteries. This research provides a new method for enhancing the application of high-specific-energy AZIBs.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Cong Huang et al.
Summary: The research shows that saccharin (Sac) as an electrolyte additive can regulate the electrical double layer (EDL) structure on the zinc anode, forming a unique solid electrolyte interphase (SEI) that effectively modulates zinc deposition behavior and prevents side reactions, thus improving battery performance.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Longsheng Cao et al.
Summary: By using a eutectic electrolyte with tin chloride additive, a zincophilic/zincophobic Sn/Zn-5(OH)(8)Cl-2•H2O bilayer interphase is formed, overcoming the challenges of Zn dendritic growth and poor low-temperature performance in aqueous Zn batteries. The eutectic electrolyte enables high Coulombic efficiency and steady charge/discharge performance at low temperatures, showing great potential for practical applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Engineering, Chemical
Samira Jabbarvand Behrouz et al.
Summary: In this study, CMC/PES thin-film composite nanofiltration membranes were fabricated using a dip-coating method with GA as the crosslinking agent. The optimized membrane with specific CMC concentration, crosslinking degree, and dipping time showed high rejection efficiency and improved fouling resistance compared to the PES support membrane. This membrane exhibited promising potential for water treatment applications.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Doudou Feng et al.
Summary: DMSO is demonstrated as an effective additive in ZnSO4 electrolyte for suppressing dendrites growth and improving the performance, stability, and cycling life of aqueous batteries at low temperatures. This work provides a facile and feasible strategy for designing high-performance and dendrite-free aqueous Zn-ion batteries for various temperatures.
Article
Chemistry, Multidisciplinary
Daliang Han et al.
Article
Chemistry, Multidisciplinary
Longsheng Cao et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Multidisciplinary Sciences
Jingxu Zheng et al.
Article
Chemistry, Physical
Shuilin Wu et al.
ADVANCED ENERGY MATERIALS
(2019)
Article
Chemistry, Physical
Zhuo Wang et al.
Article
Engineering, Chemical
Linh T. Cuba-Chiem et al.
MINERALS ENGINEERING
(2008)
