4.8 Article

Rejuvenating propylene carbonate-based electrolytes by regulating the coordinated structure toward all-climate potassium-ion batteries

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Building K-C Anode with Ultrahigh Self-Diffusion Coefficient for Solid State Potassium Metal Batteries Operating at-20 to 120 °C

Jian-Fang Wu et al.

Summary: A fused-modeling strategy using potassiophilic carbon allotropes molted with potassium is demonstrated to enhance the electrochemical performance and stability of solid-state potassium metal batteries. This strategy improves potassium diffusion kinetics, suppresses dendrite growth, and maintains mechanical/thermal stability. The resulting homogeneous/stable potassium stripping/plating enables high current density and record-high areal capacity.

ADVANCED MATERIALS (2023)

Article Chemistry, Multidisciplinary

Taming Solvent-Solute Interaction Accelerates Interfacial Kinetics in Low-Temperature Lithium-Metal Batteries

Cheng-Bin Jin et al.

Summary: Lithium (Li)-metal batteries suffer severe capacity deterioration at extreme temperatures due to increased kinetic barrier of interfacial processes. This study quantitatively probes the interfacial kinetics in three different electrolytes and reveals that desolvation is the limiting step dominating the cell impedance and capacity at low temperature. The use of a 1,3-dioxolane-based electrolyte with tamed solvent-solute interaction facilitates fast desolvation and enables practical Li|LiNi0.5Co0.2Mn0.3O2 cells at -40 degrees C to retain 66% of room-temperature capacity and withstand fast charging rates. The barrier of desolvation dictated by solvent-solute interaction environments is quantitatively uncovered, and regulating this interaction emerges as a promising solution to low-temperature batteries.

ADVANCED MATERIALS (2023)

Article Multidisciplinary Sciences

Electrolyte design for Li-ion batteries under extreme operating conditions

Jijian Xu et al.

Summary: This study introduces an electrolyte design strategy based on soft solvents, which can meet various requirements of the widely used LiNi0.8Mn0.1Co0.1O2 (NMC811)||graphite lithium-ion batteries, such as high voltage, fast charging, wide temperature range for charging/discharging, and non-flammability. This design principle can also prevent lithium plating at low temperatures.

NATURE (2023)

Review Chemistry, Multidisciplinary

Recent Advances in Electrolytes for Potassium-Ion Batteries

Yifan Xu et al.

Summary: This review summarizes recent advances in potassium-ion battery (KIB) electrolytes and design strategies. The study found that organic liquid electrolytes can improve battery performance by changing salts/solvents, adding additives, and increasing concentration. Water-in-salt electrolytes and solid-state electrolytes are also potential choices for electrolytes.

ADVANCED FUNCTIONAL MATERIALS (2023)

Review Chemistry, Multidisciplinary

Critical Review on Low-Temperature Li-Ion/Metal Batteries

Nan Zhang et al.

Summary: This article presents a comprehensive research on the key factors contributing to the poor low-temperature performance of LIBs and proposes strategies and solutions to improve it.

ADVANCED MATERIALS (2022)

Article Chemistry, Physical

A High-Voltage Organic Framework for High-Performance Na- and K-Ion Batteries

Jiande Wang et al.

Summary: The organic metal-ion battery field faces challenges in the lack of high-voltage alkali-cation reservoir cathode materials. In this study, the versatile benzene-1,2,4,5-tetrayltetrakis methylsulfonyl-amide (PTtSA) tetra-anionic framework demonstrated universal performance for alkali cation storage. Comparative analysis of Li-, Na-, and K-ion phases revealed the impact of alkali cation on the physicochemical properties.

ACS ENERGY LETTERS (2022)

Article Chemistry, Physical

Dual strategy with Li-ion solvation and solid electrolyte interphase for high Coulombic efficiency of lithium metal anode

Shengdong Zhu et al.

Summary: The research utilizes a mix of DOL and TTE solvents to enhance the stability and electrochemical performance of the lithium metal anode, improving the electrochemical stability of the electrolyte, resulting in better lithium plating-stripping effect.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

Predictive Characterization of SEI Formed on Graphite Negative Electrodes for Efficiently Designing Effective Electrolyte Solutions

Yasuhito Aoki et al.

Summary: The solid electrolyte interphase (SEI) formed on graphite in highly concentrated electrolyte solutions was thoroughly characterized by a combined experimental and computational study. The study revealed that the chemical composition and reduction vulnerability of SEI can be predicted through a profound understanding of density functional theory (DFT) calculations. The results indicate the potential for efficient design of electrolyte solutions by utilizing DFT calculations to predict the physicochemical properties of SEI.

ACS APPLIED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Predicting the Ion Desolvation Pathway of Lithium Electrolytes and Their Dependence on Chemistry and Temperature

John Holoubek et al.

Summary: This study investigates the influence of electrolyte chemistry on the ion-desolvation portion of charge-transfer using free-energy sampling techniques. The simulations focus on diethyl ether (DEE) and 1,3-dioxoloane/1,2-dimethoxyethane (DOL/DME) electrolytes, which have different solvation structures. The findings suggest that ion-paired structures are advantageous for reaching the inner Helmholtz layer, and the coordination number of the Li+ ion needs to reach 3.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2022)

Article Materials Science, Multidisciplinary

Advanced polyanionic electrode materials for potassium-ion batteries: Progresses, challenges and application prospects

Kai-Yang Zhang et al.

Summary: Although potassium-ion batteries (KIBs) are considered promising, their development still faces challenges. Polyanionic compounds, with unique structural advantages, are viable electrode materials for high-performance KIBs. However, they need to withstand severe structural deformation caused by K+ ion insertion/extraction. This paper summarizes current advancements in polyanionic compounds for KIBs and proposes solutions for electrode material design.

MATERIALS TODAY (2022)

Article Chemistry, Multidisciplinary

Enhancing Li+ Transport in NMC811||Graphite Lithium-Ion Batteries at Low temperatures by Using Low-Polarity-Solvent Electrolytes

Bo Nan et al.

Summary: Using low-polarity-solvent electrolytes is proposed as a strategy to reduce the capacity loss of lithium-ion batteries at low temperatures. The weak interactions between solvents and Li+ ions in the electrolyte help to reduce charge transfer resistance and facilitate Li+ transport. Experiments show that this electrolyte enables high capacity retention at low temperatures and stable cycling performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Review Multidisciplinary Sciences

Designing better electrolytes

Y. Shirley Meng et al.

SCIENCE (2022)

Article Chemistry, Multidisciplinary

Synthesis of KVPO4F/Carbon Porous Single Crystalline Nanoplates for High-Rate Potassium-Ion Batteries

Jiaying Liao et al.

Summary: In this study, carbon-coated KVPO4F nanoplates were synthesized using a simple one-step sintering process, where the V-F-C bond generated by fluorinated-polymer-derived carbon at the interface of KVPO4F/C nanoplates reduced F loss and improved the electronic conductivity and ion migration ability of KVPO4F. The as-synthesized KVPO4F/C cathode exhibited excellent capacity and rate capability, and the KVPO4F/C//soft carbon full cell showed a high energy density.

NANO LETTERS (2022)

Article Chemistry, Applied

Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite

Jiesong Zhang et al.

Summary: The poor cycling stability of graphite in traditional ester electrolyte limits its applications as anodes for potassium ion batteries. This study demonstrates that the introduction of cyclic ether co-solvents into ester electrolytes can remarkably enhance the cycling stability of graphite anodes. The addition of tetrahydrofuran promotes the generation of conductive K2CO3 and mechanically robust PEO, leading to more uniform, conductive, and stable solid electrolyte interphases (SEIs) on graphite.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Multidisciplinary Sciences

Advanced flame-retardant electrolyte for highly stabilized K-ion storage in graphite anode

Hao-Jie Liang et al.

Summary: By introducing a flame-retardant localized high-concentration electrolyte, a rational solid electrolyte interphase was tailored, effectively preventing solvent decomposition and improving resistance against K-ion transport. As a result, the graphite anode exhibited prolonged cycling capability and excellent capacity retention of up to 92.4% over 1400 cycles.

SCIENCE BULLETIN (2022)

Review Chemistry, Physical

The timescale identification decoupling complicated kinetic processes in lithium batteries

Yang Lu et al.

Summary: Comprehensive understanding of multiple Li kinetics in batteries is crucial for studying mechanisms and designing materials. Time scale information in batteries can provide insights into various kinetic processes, such as ionic conductions, charge transfer, and diffusion. Time scale characterization, combined with non-destructive impedance characterization, can be a powerful tool for online battery monitoring.
Article Chemistry, Multidisciplinary

High performance Li-, Na-, and K-ion storage in electrically conducting coordination polymers

Jiande Wang et al.

Summary: We report a new class of conducting alkali-cation reservoir coordination polymers with high electrical conductivity and redox potential, suitable for lithium-ion, sodium-ion, and potassium-ion batteries. Detailed studies on their structure, composition, physicochemical properties, and performance were conducted using experimental and computational analyses.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

High-efficiency cathode potassium compensation and interfacial stability improvement enabled by dipotassium squarate for potassium-ion batteries

Shuoqing Zhao et al.

Summary: This study presents an economic and facile potassium compensation strategy using a self-sacrificial agent (K2C4O4) on cathodes to enhance the performance of potassium-ion batteries. The addition of K2C4O4 significantly improves the initial Coulombic efficiency and promotes the formation of a thin and F-rich cathode electrolyte interphase layer, leading to improved kinetics and interfacial stability. A potassium-compensated full cell shows three times higher energy density and enhanced capacity retention compared to a cell without any pre-potassiation treatment.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Electrolyte design implications of ion-pairing in low-temperature Li metal batteries

John Holoubek et al.

Summary: In this study, we report the development of >4 V Li metal full cell batteries capable of charging and discharging at extremely low temperatures. By introducing cation/anion pairs in the electrolyte, significant improvements in the performance of the batteries were observed. This ion-pairing effect was found to enhance both the cathode and anode, resulting in improved Coulombic efficiencies and oxidative stability of the Li metal.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Electrolytes and Interphases in Potassium Ion Batteries

Mengfan Zhou et al.

Summary: Potassium ion batteries are considered a promising candidate for future energy storage devices due to their cost-effectiveness, high-voltage, and high-power operation. In addition to electrode materials, electrolytes also play a crucial role in determining cell performance. This Progress Report summarizes the research progress of electrolytes in PIBs and provides comprehensive guidance on the design of electrolyte systems for high performance PIBs.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

A Low-Strain Phosphate Cathode for High-Rate and Ultralong Cycle-Life Potassium-Ion Batteries

Jiaying Liao et al.

Summary: A controllable synthesis method for a novel low-strain phosphate material K-3(VO)(HV2O3)(PO4)(2)(HPO4) (referred to as KVP) nanoruler was introduced as an efficient cathode for PIBs, demonstrating excellent cycling performance, rate capability, and capacity retention. The outstanding potassium storage capability of KVP nanoruler cathode is attributed to its low-strain K+ uptake/removal mechanism, inherent semiconductor characteristic, and small K+ migration energy barrier.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Mildly-expanded graphite with adjustable interlayer distance as high-performance anode for potassium-ion batteries

Xiaojing Li et al.

Summary: A low cost mildly-expanded graphite anode with adjustable interlayer lattice distance was synthesized for potassium-ion batteries, showing stable intercalation/deintercalation plateaus and outstanding cyclic stability and rate performance. By optimizing the mass ratio, the anode delivered high capacity and retention rate under different current densities, demonstrating promising potential for PIBs.

CARBON (2021)

Article Chemistry, Multidisciplinary

Design of a LiF-Rich Solid Electrolyte Interphase Layer through Highly Concentrated LiFSI-THF Electrolyte for Stable Lithium Metal Batteries

Thuy Duong Pham et al.

Summary: A highly concentrated LiFSI-THF electrolyte system has been introduced, allowing for high CE cycling of lithium metal anodes without dendrite growth. The excellent charge-discharge performance is attributed to the increased cation-anion associated complexes in the electrolyte.
Editorial Material Multidisciplinary Sciences

Learning from biology: biomimetic carbon cells promote high-power potassium ion batteries

Wenchao Zhang et al.

NATIONAL SCIENCE REVIEW (2021)

Article Energy & Fuels

Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature

John Holoubek et al.

Summary: This study highlights the importance of the solvation structure of the electrolyte in charge-transfer behavior at ultra-low temperatures for lithium metal batteries. By designing an electrolyte to enable low-temperature operations, stable performance and high efficiency can be achieved for Li-metal batteries.

NATURE ENERGY (2021)

Article Chemistry, Multidisciplinary

A Low-Strain Potassium-Rich Prussian Blue Analogue Cathode for High Power Potassium-Ion Batteries

Lin Li et al.

Summary: This study introduces a low-strain potassium-rich cathode material KNiHCF for potassium ion batteries, which exhibits superior discharge capacity and cycling stability due to its low-strain de-/intercalation mechanism, intrinsic semiconductor property, and low potassium diffusion energy barrier.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Effects of fluoroethylene carbonate-induced solid-electrolyte-interface layers on carbon-based anode materials for potassium ion batteries

Seung Uk Yoon et al.

Summary: This study investigated the effects of fluoroethylene carbonate (FEC)-induced solid-electrolyte-interface (SEI) layers on carbon-based anode materials for potassium ion batteries (PIBs) and achieved a remarkable enhancement of cycling performance. By adding a small amount of FEC (0.2 wt%) in a carbonate-based electrolyte system, a well-balanced organic-inorganic hybrid SEI layer was formed, effectively blocking additional electrolyte decomposition and significantly improving Coulombic efficiency and capacity retention. Additionally, the FEC additive reduced the self-discharge rate, demonstrating its beneficial effect on cycling stabilities.

APPLIED SURFACE SCIENCE (2021)

Review Chemistry, Physical

Prospects of Electrode Materials and Electrolytes for Practical Potassium-Based Batteries

Ling Fan et al.

Summary: This review focuses on high-performance electrode materials and electrolytes for potassium-ion batteries (PIBs), evaluating their potential and challenges for market penetration. Discussions include the current status of PIBs in terms of safety, energy density, power density, cyclability, and sustainability, as well as future research directions for electrode materials, electrolytes, and electrode-electrolyte interfaces in order to commercialize potassium-based full batteries in the near future.

SMALL METHODS (2021)

Article Multidisciplinary Sciences

Defect-free potassium manganese hexacyanoferrate cathode material for high-performance potassium-ion batteries

Leqing Deng et al.

Summary: The potassium-ion battery shows great potential as a post-Li-ion energy storage system, but the lack of high-performance cathode materials has been a barrier to practical applications. In this study, defect-free potassium manganese hexacyanoferrate is investigated as a cathode active material for high-energy and long-lasting potassium-based cells.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Ethylene Carbonate-Free Propylene Carbonate-Based Electrolytes with Excellent Electrochemical Compatibility for Li-Ion Batteries through Engineering Electrolyte Solvation Structure

Xingwei Liu et al.

Summary: This study introduces a simple and effective strategy to prepare electrochemically compatible PC-based electrolytes, utilizing a weakly coordinating diethyl carbonate co-solvent to enhance the reduction tolerance of PC solvent. By incorporating a film-forming additive, an electrochemically stable PC-based electrolyte that allows reversible Li+ intercalation on the graphite electrode is obtained.

ADVANCED ENERGY MATERIALS (2021)

Article Multidisciplinary Sciences

Robust high-temperature potassium-ion batteries enabled by carboxyl functional group energy storage

Xianlu Lu et al.

Summary: A new high-temperature potassium-ion battery with a carboxyl functional group energy storage mechanism shows improved cycle stability by allowing intercalation/de-intercalation reactions to take place through surface reactions. The p-phthalic acid (PTA) electrode demonstrates good initial discharge and charge specific capacities at 62.5 degrees C, with excellent retention rates after multiple cycles under both low and high current densities.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2021)

Review Electrochemistry

Recent Advances in Stability of Carbon-Based Anodes for Potassium-Ion Batteries

Jiali Wang et al.

Summary: The modification strategies for graphite anodes in potassium-ion batteries, such as microstructure regulation, heteroatom doping, and building stable solid electrolyte interphase were summarized. The opportunities and challenges faced by these improvement methods, as well as the use of carbon-based materials in enhancing the performance of other anodes, are discussed in the text.

BATTERIES & SUPERCAPS (2021)

Article Chemistry, Multidisciplinary

An Intrinsically Non-flammable Electrolyte for High-Performance Potassium Batteries

Sailin Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Research Development on K-Ion Batteries

Tomooki Hosaka et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

New Concepts in Electrolytes

Matthew Li et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Physical

A long lifespan potassium-ion full battery based on KVPO4F cathode and VPO4 anode

Jiaying Liao et al.

JOURNAL OF POWER SOURCES (2020)

Article Multidisciplinary Sciences

A fluoroxalate cathode material for potassium-ion batteries with ultra-long cyclability

Bifa Ji et al.

NATURE COMMUNICATIONS (2020)

Review Chemistry, Physical

Fundamentals and Challenges of Lithium Ion Batteries at Temperatures between-40 and 60 °C

Junbo Hou et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Understanding High-Rate K+-Solvent Co-Intercalation in Natural Graphite for Potassium-Ion Batteries

Lin Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Sulfur-Rich (NH4)2Mo3S13 as a Highly Reversible Anode for Sodium/Potassium-Ion Batteries

Shuangshuang Ding et al.

ACS NANO (2020)

Review Chemistry, Multidisciplinary

The Features and Progress of Electrolyte for Potassium Ion Batteries

Yiwei Liu et al.

Review Energy & Fuels

Advances and issues in developing salt-concentrated battery electrolytes

Yuki Yamada et al.

NATURE ENERGY (2019)

Article Chemistry, Physical

Unraveling the Potassium Storage Mechanism in Graphite Foam

Jilei Liu et al.

ADVANCED ENERGY MATERIALS (2019)

Article Chemistry, Multidisciplinary

Graphite Anode for a Potassium-Ion Battery with Unprecedented Performance

Ling Fan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

Localized High-Concentration Electrolytes Boost Potassium Storage in High-Loading Graphite

Lei Qin et al.

ADVANCED ENERGY MATERIALS (2019)

Article Chemistry, Physical

Graphite as a potassium ion battery anode in carbonate-based electrolyte and ether-based electrolyte

Liping Wang et al.

JOURNAL OF POWER SOURCES (2019)

Review Chemistry, Multidisciplinary

Deciphering the Ethylene Carbonate-Propylene Carbonate Mystery in Li-Ion Batteries

Lidan Xing et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Chemistry, Multidisciplinary

An Ultrafast and Highly Stable Potassium-Organic Battery

Ling Fan et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Physical

Organic Batteries Operated at -70 degrees C

Xiaoli Dong et al.

Article Chemistry, Multidisciplinary

Potassium Prussian Blue Nanoparticles: A Low-Cost Cathode Material for Potassium-Ion Batteries

Chenglin Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Article Chemistry, Physical

A novel K-ion battery: hexacyanoferrate(II)/graphite cell

Xiaofei Bie et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Nanoscience & Nanotechnology

Li+-Desolvation Dictating Lithium-Ion Battery's Low-Temperature Performances

Qiuyan Li et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Chemistry, Multidisciplinary

Electrochemical Intercalation of Potassium into Graphite

Jin Zhao et al.

ADVANCED FUNCTIONAL MATERIALS (2016)

Article Multidisciplinary Sciences

Superconcentrated electrolytes for a high-voltage lithium-ion battery

Jianhui Wang et al.

NATURE COMMUNICATIONS (2016)

Article Chemistry, Multidisciplinary

Carbon Electrodes for K-Ion Batteries

Zelang Jian et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Review Chemistry, Multidisciplinary

Nonaqueous liquid electrolytes for lithium-based rechargeable batteries

K Xu

CHEMICAL REVIEWS (2004)

Article Chemistry, Physical

Effect of propylene carbonate on the low temperature performance of Li-ion cells

SS Zhang et al.

JOURNAL OF POWER SOURCES (2002)