期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 14, 期 47, 页码 10685-10692出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.3c02850
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Perovskite solar cells, as a promising technology for low-cost and high-efficiency photovoltaics, face challenges in stability and nonradiative losses. This study demonstrates that replacing part of the iodide in formamidinium lead iodide (FAPbI(3)) with pseudohalide anions can suppress nonradiative charge recombination, leading to increased charge carrier lifetime.
Perovskite solar cells have witnessed a surge in interest as a promising technology for low-cost, high-efficiency photovoltaics with certified power conversion efficiencies beyond 25%. However, their commercial development is hindered by poor stability and nonradiative losses that restrict their approach to the theoretical efficiency limit. Using ab initio nonadiabatic molecular dynamics, we demonstrate that nonradiative charge recombination is suppressed when the iodide in formamidinium lead iodide (FAPbI(3)) is partially replaced with pseudohalide anions (SCN-, BF4 -, and PF6 (-)). The replacement breaks the symmetry of the system and creates local structural distortion and dynamic disorder, decreasing electron-hole overlap and nonadiabatic electron-vibrational coupling. The charge carrier lifetime is found to increase with increased structural distortion and is the longest for PF6 -. This work is fundamentally relevant to the design of high-performance perovskite materials for optoelectronic applications.
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