期刊
ORGANIC LETTERS
卷 25, 期 47, 页码 8535-8539出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c03589
关键词
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A novel method for the nickel-catalyzed multicomponent aminofluoroalkylation/cyclization of styrenes with ethyl fluoroacetate and anilines has been developed, providing a general and efficient access to a diverse range of fluoro-gamma-lactams from simple and readily available starting materials. Control experiments confirmed the involvement of radical intermediates and ruled out the presence of 2-fluoro-N-phenylacetamide.
A novel method for the nickel-catalyzed multicomponent aminofluoroalkylation/cyclization of styrenes with ethyl fluoroacetate and anilines has been developed. This protocol provides general and efficient access to a diverse range of fluoro-gamma-lactams from simple and readily available starting materials. Control experiments prove the involvement of radical intermediates and excluded the presence of 2-fluoro-N-phenylacetamide.
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