A CTAB-assisted PANI-MoS2 nanosheet flower morphology for the highly sensitive electrochemical detection of hydrazine

In this work, cetyl trimethylammonium bromide (CTAB)-assisted polyaniline-molybdenum disulfide (CPANI-MoS2) nanosheets with a flower morphology have been synthesized through in situ polymerization and a hydrothermal method. The composite was analyzed for structural modification through X-ray diffraction (XRD) to examine chemical changes and the presence of functional groups via Fourier transform infrared (FTIR) and Raman spectroscopy techniques. The surface morphology was identified by field-emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HR-TEM) techniques. The CPANI-MoS2 nanosheet glassy carbon electrode (GCE) offers a novel strategy for the electrochemical detection of carcinogenic hydrazine. The cyclic voltammetry (CV) curve demonstrated a quasi-reversible behaviour with a high-surface area. Furthermore, differential pulse voltammetry (DPV) analysis of hydrazine detection showed a wide linear range from 10 mu M to 100 mu M, a low limit of detection of 0.40 mu M, and a high sensitivity of 7.23 mu A mu M cm(-2). The determination of hydrazine in a water sample and the recovery percentage were found to be 100.31% and 103.73%, respectively. The CPANI-MoS2 nanosheet GCE significantly contributed to the high electroanalytical oxidation activity due to the CTAB surfactant modifying the flower-like nanosheet morphology, which enables the easy adsorption of hydrazine analyte species and exhibits a high current rate with a rapid detection response.

Automated summary

In this work, flower-like CPANI-MoS2 nanosheets were synthesized through in situ polymerization and a hydrothermal method. The composite was analyzed for structural modification and chemical changes, and showed great potential for electrochemical detection, especially for the detection of hydrazine with wide linear range, low detection limit, and high sensitivity.