期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 400, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2023.134887
关键词
Inverse opal photonic balls; Acetone sensing; Gas sensor; ZnO-SnO 2 heterojunction; Ultrafast
In this study, ZnO-SnO2 heterojunction three-dimensional inverse opal photonic crystal balls (IOPB) were fabricated via rapid and liquid waste-free spray drying. The IOPBs showed higher response and faster response/recovery times compared to pure SnO2 sensors, as well as good selectivity and long-term stability.
The development of metal oxide semiconductor-based chemiresistive gas sensors with ultra-fast response/recovery for toxic and flammable gases is of great importance, but still challenging. Here, ZnO-SnO2 heterojunction three-dimensional (3D) inverse opal photonic crystal balls (IOPBs) were fabricated based on rapid and liquid waste-free spray drying. The spherical three-dimensional (3D) ordered macroporous skeleton can provide more active sites and faster gas diffusion channels. Furthermore, the n-n heterojunction established by ZnO and SnO2 is favorable for electron transport. The response (Ra/Rg) of IOPBs to 50 ppm acetone reaches 40.3 at an optimal operating temperature of 260 degrees C when the Zn/Sn atomic ratio is 1:4, which is 5 times higher than that of the pure SnO2 sensor. Response/recovery time also reduces from 23/47 s for pure SnO2 to 6/10 s. In addition, the IOPBs gas sensors also exhibit good selectivity and excellent long-term stability. This work provides a straightforward and versatile synthetic route for the preparation of 3D IOPBs to explore novel gas sensors with ultra-fast response speed.
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