Waste to treasure: Reutilization of fluid catalytic cracking coke block as photothermal conversion material for water evaporation

This study aims to analyze the coking process and propose an effective method for the reutilization of fluid catalytic cracking (FCC) coke block. Herein, we analyzed the basic characteristics and chemical composition of FCC coke blocks. The results showed that the main components were carbon, oxygen, and aluminum, accounting for 60.8%, 26.6%, and 11.5%, respectively. Under the conventional catalytic cracking reaction temperature from 500 degrees C to 600 degrees C, the formation of the first aromatic hydrocarbon was particularly important for the formation of coke. The condensation of oil-gas-entrained catalyst particles and their heavy components was the physical cause of coking, while the dehydrogenation condensation reaction of oil-gas heavy components was the chemical factor. In addition, the membrane prepared by powdered coke had excellent photothermal conversion ability, which could be heated to more than 110 degrees C within 360 s under two fixed light intensities. The evaporation rate of photothermal water was 5.89 kg m2 h-1, which has great industrial application potential. These works provide a novel and effective method of separation membrane for the reutilization of FCC coke blocks. (c) 2023 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Automated summary

This study aims to analyze the coking process and propose an effective method for the reutilization of fluid catalytic cracking (FCC) coke block. The main components of FCC coke blocks are carbon, oxygen, and aluminum. The physical cause of coking is the condensation of oil-gas-entrained catalyst particles and their heavy components, while the chemical factor is the dehydrogenation condensation reaction of oil-gas heavy components. The membrane prepared by powdered coke has excellent photothermal conversion ability and can have industrial application potential.