4.6 Article

Reactivity of NHI-Stabilized Heavier Tetrylenes towards CO2 and N2O

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Isolation and Reactivity of Stannylenoids Stabilized by Amido/Imino Ligands

Xuan-Xuan Zhao et al.

Summary: A novel stannylenoid compound was synthesized by reacting lithium aryl(silyl)amide with SnCl2, and further transformations of the stannylenoid compound were achieved. All compounds were characterized by NMR, elemental analysis, and X-ray structural determination.

CHEMISTRY-A EUROPEAN JOURNAL (2023)

Article Chemistry, Multidisciplinary

Anions featuring an aluminium-silicon core with alumanyl silanide and aluminata-silene characteristics

Moritz Ludwig et al.

Summary: We report the isolation of three alumanyl silanide anions featuring an Al-Si core stabilized by bulky substituents and a Si-Na interaction. The Al-Si interaction possesses partial double bond character. Reactivity studies suggest a predominant nucleophilic character of the sodium-coordinated silicon center in the Al-Si core, as shown by silanide-like reactivity towards halosilane electrophiles and CH-insertion of phenylacetylene. We also report an alumanyl silanide with a sequestered sodium cation, where cleavage of the Si-Na bond increases the double bond character of the Al-Si core.

NATURE CHEMISTRY (2023)

Article Multidisciplinary Sciences

Catalytic synthesis of phenols with nitrous oxide

Franck Le Vaillant et al.

Summary: This study presents a method for inserting N2O into a Ni-C bond to synthesize valuable phenols under mild conditions. This method provides an alternative catalytic approach for the conversion of aryl halides to phenols, different from traditional strategies.

NATURE (2022)

Article Chemistry, Multidisciplinary

Isolation and Reactivity of Tetrylene-Tetrylone-Iron Complexes Supported by Bis(N-Heterocyclic Imine) Ligands

Xuan-Xuan Zhao et al.

Summary: The germanium iron carbonyl complex and the tin iron carbonyl complex were prepared and showed reversible formation of bis(tetrylene) and tetrylene-tetrylone character. Computational analysis further explained the reduction pathway from the chlorotetrylenes to the corresponding complexes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Review Environmental Sciences

Conversion of carbon dioxide to methanol: A comprehensive review

Trinath Biswal et al.

Summary: This review provides an explanation of the various methods for converting carbon dioxide (CO2) to methanol, including the use of homogeneous and heterogeneous catalysts, as well as hydrogenation, photochemical, electrochemical, and photoelectrochemical techniques. The article emphasizes the importance of proper catalyst selection and method development to break the stable CO2 bond and produce valuable chemicals like methanol.

CHEMOSPHERE (2022)

Article Chemistry, Physical

Ligand Assisted CO2 Activation and Catalytic Valorization by an NHI-Stabilized Stannylene

Debotra Sarkar et al.

Summary: The aryl(imino)stannylene (Mes)Ter[N(IDipp)]Sn, stabilized by the NHI ligand, enables the sequestration and valorization of CO2 to C1 feedstock stoichiometrically, as well as catalytically. The NHI ligand plays a key role in the CO2 reduction process, rationalized by experimental and computational analysis.

CHEMCATCHEM (2022)

Article Chemistry, Physical

A mild and effective photo-catalytic protocol for triggering inert nitrous oxide to participate in oxidative dehydrogenation of alcohols under visible light illumination

Jiekun Zhu et al.

Summary: The development of a mild and efficient activation protocol for N2O-based selective oxidation has significant academic and applied values. This study reveals that decatungstate (DT) anion and its hybrids with metal ions are active for the N2O-involved oxidative dehydrogenation reactions. The best catalyst achieves high cyclohexanone yield and is efficient for the N2O-involved ODH reactions of various alcohols.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Multidisciplinary

A Stable N-Heterocyclic Silylene with a 1,1′-Ferrocenediyl Backbone

Nadine Weyer et al.

Summary: The N-heterocyclic silylene shows a remarkable combination of thermal stability and reactivity towards small molecules, producing different follow-up products in reactions with CO2, N2O, H2O, NH3, and FcPH(2). Unexpectedly, the reaction with H3BNH3 results in B-H activation instead of N-H activation. DFT results suggest dramatically different mechanisms for these H-X insertions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Recent Advances in Metal Catalyst Design for CO2 Hydroboration to C1 Derivatives

Sylwia Kostera et al.

Summary: This mini-review article summarizes the main results obtained since 2016 in the synthetic design of main group, first and second row transition metals for use as catalysts for CO2 hydroboration.

CATALYSTS (2021)

Article Chemistry, Inorganic & Nuclear

Synthesis and Reactivity of Acyclic Germanimines: Silyl Rearrangement and Cycloadditions

Matthew J. Evans et al.

Summary: This study reports the synthesis and reactivity of aromatic germanimines, demonstrating their decomposition and intramolecular reactions at different temperatures. Furthermore, it shows that these germanimines can react with various unsaturated polar substrates via a [2 + 2] cycloaddition pathway.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

An Isolable Three-Coordinate Germanone and Its Reactivity

Xuan-Xuan Zhao et al.

Summary: The isolated three-coordinate germanone [IPrN](2)Ge=O has high thermal stability in arene solvents, but still reactive towards small molecules, mimicking nucleophilic transition-metal oxides. The O-atom transfer reaction proceeds via a [2+2] cycloaddition intermediate, as revealed by DFT calculations.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Multidisciplinary

Low-Valent Germanylidene Anions: Efficient Single-Site Nucleophiles for Activation of Small Molecules

Chris Gendy et al.

Summary: Rare mononuclear and helical chain low-valent germanylidene anions, synthesized by stepwise reduction from corresponding germylene precursors, exhibit electronic structures describable with ylidene and ylidone resonance forms, and act as efficient single-site nucleophiles for activating small molecules.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Inorganic & Nuclear

Imino(silyl)disilenes: application in versatile bond activation, reversible oxidation and thermal isomerization

Richard Holzner et al.

Summary: Two novel disilenes with N-heterocyclic imino and trialkylsilyl groups are reported. Compound 2 exhibits high stability and reactivity, undergoing (E/Z) isomerization and showing reversible redox behavior. Furthermore, selective thermal rearrangement of 2 at higher temperatures results in the formation of unique cage compound 8 and A(2)Si= SiB2-type disilene 9.

DALTON TRANSACTIONS (2021)

Article Chemistry, Inorganic & Nuclear

Reactions of a diborylstannylene with CO2 and N2O: diboration of carbon dioxide by a main group bis(boryl) complex

Andrey V. Protchenko et al.

Summary: The reaction of boryl-substituted stannylene with carbon dioxide proceeds via pathways involving insertion into the Sn-B bonds. Several different products can be derived from this reaction, including boryl(borylcarboxylate)ester and bis(borylcarboxylate) stannylene complexes. The possibility of extrusion of CO from the reaction products to generate boryloxy systems has also been observed.

DALTON TRANSACTIONS (2021)

Review Chemistry, Multidisciplinary

Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis

Franziska Hanusch et al.

Summary: This review article provides an overview of recent developments in the chemistry of stable group 14 dimetallenes and dimetallynes, focusing on their potential catalytic applications and emphasizing the strong relationship between structure and reactivity.

CHEMICAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

The Metallo-Diels-Alder Reactions: Examining the Metalloid Behavior of Germanimines

Matthew J. Evans et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Chemistry, Multidisciplinary

Hydroxide Based Integrated CO2 Capture from Air and Conversion to Methanol

Raktim Sen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

Strategies for mitigation of climate change: a review

Samer Fawzy et al.

ENVIRONMENTAL CHEMISTRY LETTERS (2020)

Review Chemistry, Inorganic & Nuclear

Small Molecule Activation by Two-Coordinate Acyclic Silylenes

Shiori Fujimori et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

Article Multidisciplinary Sciences

A comprehensive quantification of global nitrous oxide sources and sinks

Hanqin Tian et al.

NATURE (2020)

Article Chemistry, Multidisciplinary

From CO2activation to catalytic reduction: a metal-free approach

P. Sreejyothi et al.

CHEMICAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry

Adinarayana Doddi et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Multidisciplinary

Reduction of Carbon Oxides by an Acyclic Silylene: Reductive Coupling of CO

Andrey V. Protchenko et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

Thermochemistry of germanium and organogermanium compounds

Rosa Becerra et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2019)

Article Chemistry, Physical

The Road Travelled: After Main-Group Elements as Transition Metals

Catherine Weetman et al.

CHEMCATCHEM (2018)

Article Multidisciplinary Sciences

Trajectories of the Earth System in the Anthropocene

Will Steffen et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

Article Chemistry, Multidisciplinary

Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst

Jacob Schneidewind et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

A Tin Analogue of Carbenoid: Isolation and Reactivity of a Lithium Bis(imidazolin-2-imino)stannylenoid

Tatsumi Ochiai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

Applications of N-heterocyclic imines in main group chemistry

Tatsumi Ochiai et al.

CHEMICAL SOCIETY REVIEWS (2016)

Review Chemistry, Multidisciplinary

Synthetic chemistry with nitrous oxide

Kay Severin

CHEMICAL SOCIETY REVIEWS (2015)

Article Chemistry, Multidisciplinary

Formation of an Imino-Stabilized Cyclic Tin(II) Cation from an Amino(imino)stannylene

Tatsumi Ochiai et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Article Chemistry, Inorganic & Nuclear

Contrasting Reactivities of Silicon and Germanium Complexes Supported by an N-Heterocyclic Guanidine Ligand

Melanie W. Lui et al.

INORGANIC CHEMISTRY (2015)

Review Multidisciplinary Sciences

Using carbon dioxide as a building block in organic synthesis

Qiang Liu et al.

NATURE COMMUNICATIONS (2015)

Article Chemistry, Multidisciplinary

Synthesis of Azoimidazolium Dyes with Nitrous Oxide

Alexander G. Tskhovrebov et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Synthesis of Triazenes with Nitrous Oxide

Gregor Kiefer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Inorganic & Nuclear

Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride

Gengwen Tan et al.

DALTON TRANSACTIONS (2014)

Article Chemistry, Inorganic & Nuclear

Combined NMR and DFT Study on the Complexation Behavior of Lappert's Tin(II) Amide

Lies Broeckaert et al.

ORGANOMETALLICS (2013)

Article Chemistry, Multidisciplinary

The Facile Reduction of Carbon Dioxide to Carbon Monoxide with an Amido-Digermyne

Jiaye Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Inorganic & Nuclear

Reactions of CO2 and related heteroallenes with CF3-substituted aromatic silylamines of tin

Constantine A. Stewart et al.

POLYHEDRON (2012)

Review Chemistry, Multidisciplinary

Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

Mirza Cokoja et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Article Chemistry, Inorganic & Nuclear

Synthesis and reactivity of tin amide complexes

Lisa A. -M. Harris et al.

INORGANICA CHIMICA ACTA (2011)

Article Chemistry, Multidisciplinary

Reactions of Tin(II) Hydride Species with Unsaturated Molecules

Anukul Jana et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Article Chemistry, Multidisciplinary

Homolytic bond-dissociation enthalpies of tin bonds and tin-ligand bond strengths - A computational study

Sarah R. Whittleton et al.

CANADIAN JOURNAL OF CHEMISTRY (2009)

Article Chemistry, Multidisciplinary

A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions

Anukul Jana et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Environmental Sciences

N2O release from agro-biofuel production negates global warming reduction by replacing fossil fuels

P. J. Crutzen et al.

ATMOSPHERIC CHEMISTRY AND PHYSICS (2008)

Review Chemistry, Organic

Structural and theoretical investigation of 2-iminoimidazolines - carbene analogues of iminophosphoranes

Matthias Tamm et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2007)

Article Chemistry, Multidisciplinary

Titanium complexes with imidazolin-2-iminato ligands

M Tamm et al.

CHEMICAL COMMUNICATIONS (2004)