期刊
POLYMERS
卷 8, 期 7, 页码 -出版社
MDPI
DOI: 10.3390/polym8070257
关键词
itaconic acid; bio-based; amorphous polyamide; plasticization; elastomer
资金
- National Natural Science Foundation of China [50933001, 51221002, 51273005]
- New Star Plan of Science and Technology of Beijing [2008B06]
- Beijing Natural Science Foundation Program
- Scientific Research Key Program of the Beijing Municipal Commission of Education [KZ201110012016]
The purpose of this work was to study the effects of three green plasticizers H2O, glycerol, and soybean oil, on the properties of bio-based BDIS polyamides. The BDIS polyamides synthesized from the following biomass monomers: 1,4-butanediamine (BD), 1,10-decanediamine (DD), itaconic acid (IA), and sebacic acid (SA). It is interesting to note that the amorphous BDIS (IA-80%) polyamide was changed from the glassy state to the rubbery state after water soaking and induced crystallization at the same time. The H2O-plasticized non-crosslinked BDIS (IA-80%) polyamides can be very useful for the preparation of physical water gel. The glycerol-and soybean oil-plasticized BDIS (IA-80%) polyamides displayed excellent toughness. The plasticized BDIS (IA-80%) polyamides were characterized by Fouriertransform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), mechanical testing, and X-ray diffraction (XRD).
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