3.8 Article

Expanding the boundary of biorefinery: long-chain heteroatom-containing chemicals from biomass

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DOI: 10.1016/j.ccst.2023.100158

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Biorefinery; Heteroatom-containing chemicals; C-c coupling; Hydrodeoxygenation

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This article discusses the strategies for producing long-chain heteroatom-containing chemicals from biomass, with a focus on the transformation of long-chain intermediates into long-chain heteroatom-containing chemicals.
Biomass is regarded as the largest renewable carbon resource on earth. Various biomass-based value-added chem-icals, transportation fuels and carbon-based functional materials can be obtained through selective catalytic sys-tems and reaction processes. The production of long-chain heteroatom-containing chemicals from biomass as a relatively new direction in the field of biorefinery has received significant attention in recent years. The process of producing long-chain heteroatom-containing chemicals involves two steps, namely C -C coupling to long-chain intermediates and further transformation into long-chain heteroatom-containing chemicals. In this perspective, we discuss the strategies for the production of long-chain heteroatom-containing chemicals, with a focus on the transformation strategies of long-chain intermediates into long-chain heteroatom-containing chemicals. Finally, our insights into future recommendations in this promising field are provided.

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