期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 306, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2023.123530
关键词
ESIPT; Aggregation-induced emission; Fluorescent sensor; Colorimetric
类别
This study synthesized four compounds with different luminescent properties by controlling the electron-donor substitution of ESIPT molecules. Two of these compounds exhibited high solid-state quantum yields and large Stokes shifts due to the synergistic effect of aggregation-induced emission (AIE) and ESIPT. They showed excellent performance in detecting F-.
Excited-state intramolecular proton transfer (ESIPT) molecules has been using as a variety of functionalityled molecular systems. To investigate the relationship between the electron-donor substitution and luminescent properties of ESIPT luminogens, four 2-(2-hydroxyphenyl) benzothiazole derivatives with donor-lc-acceptor (Dlc-A)-structured were synthesized. The distinct fluorescence properties of them were found to be highly dependent on the electron-donor moiety (triphenylamine and anthracenyl), its substituent position (para and meta position) and solvent polarity. The M-TPA, P-En, and M-En showed ESIPT emission in organic solvents, while the P-TPA showed intramolecular charge transfer process (ICT) emission. It is due to the synergistic effect of the aggregation-induced emission (AIE) and ESIPT, that M-TPA and M-En exhibited high solid-state quantum yields and large Stokes shifts. They were used as a probe for detecting F-, which resulted in rapid colorimetric, high sensitivity and good selectivity. The M-TPA was a turn-on fluorescent probe, which had the best detection property, and the limit of detection was as low as 11 nM. Because M-TPA displayed phenol anion emission in DMSO and F- causes the deprotonation of the M-TPA, which led to significant red shift of the absorption band and enhancement of fluorescence emission. This work provides a reliable strategy for designing high performance fluorescent sensor via ESIPT manipulation.
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