期刊
CHEMICAL RECORD
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.202300326
关键词
two-molecule photoredox system; two-molecule photoredox catalyst; photoinduced decarboxylation; photoinduced deboronation; aryl radical
Based on our recent results, this article explores the distinct reactivities of two-molecule photoredox systems compared to one-molecule photoredox systems. The inefficient electron transfer processes in the two-molecule system result in unique products through different pathways. The substitution of photoredox catalysts with appropriate oxidation/reduction potentials in this system provides valuable insights into photoredox reactions.
Using our recent relevant results, this account shows the featured reactivities of two-molecule photoredox systems compared to one-molecule photoredox systems. The low efficiency of electron transfer processes, such as photoinduced and back-electron transfer, in the two-molecule photoredox system, furnishes unique products through different pathways. The facile replacement of photoredox catalysts with appropriate oxidation/reduction potentials in this system provides valuable insights into photoredox reactions. This account shows featured reactivities of two-molecule photoredox system using recent our results. The low efficiency of electron transfer processes in the two-molecule photoredox system furnished the unique products through the different pathway. A facile replacing photoredox catalysts in this system can provide the valuable insights for a photoredox reaction.image
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