Bismuth and Chlorine Dual-Doped Perovskite Chloride as a Phase-Structure-Stable and Moisture-Resistant Solid Electrolyte for Chloride Ion Batteries

Article Chemistry, Physical

Near‐Room‐Temperature Quasi‐Solid‐State F‐Ion Batteries with High Conversion Reversibility Based on Layered Structured Electrolyte

Yifan Yu et al.

Advanced Energy Materials (2023)

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Article Multidisciplinary Sciences

Deforming lanthanum trihydride for superionic conduction

Weijin Zhang et al.

NATURE (2023)

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Article Multidisciplinary Sciences

A LaCl3-based lithium superionic conductor compatible with lithium metal

Yi-Chen Yin et al.

NATURE (2023)

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Article Multidisciplinary Sciences

Electrolyte design principles for developing quasi-solid-state rechargeable halide-ion batteries

Xu Yang et al.

Summary: State-of-the-art electrolytes limit the cycle life of halide-ion batteries. Here, the authors report a fluorinated low-polar gel polymer electrolyte capable of improving the stability of the electrolyte and electrode interphases to boost battery performance.

NATURE COMMUNICATIONS (2023)

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Article Chemistry, Physical

A Structurally Flexible Halide Solid Electrolyte with High Ionic Conductivity and Air Processability

Guruprakash Karkera et al.

Summary: In this work, a structurally revivable, chloride-ion conducting solid electrolyte (SE), CsSn0.9In0.067Cl3, with a high ionic conductivity of 3.45 x 10(-4) S cm(-1) at 25 degrees C is investigated. The suitable properties of CsSn0.9In0.067Cl3 as an electrolyte are demonstrated by designing all-solid-state batteries.

ADVANCED ENERGY MATERIALS (2023)

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Article Materials Science, Multidisciplinary

A Room-Temperature Chloride-Conducting Metal-Organic Crystal [Al(DMSO)6]Cl3 for Potential Solid-State Chloride-Shuttle Batteries

Bing Wu et al.

Summary: The demand for substitutes of lithium chemistries in battery has led to the emergence of chloride ion batteries (CIBs) as a novel anion-based electrochemical energy storage. However, the use of CIBs is limited by the dissolution and side reactions of chloride-based electrode materials in liquid electrolytes. This study introduces a solid-state metal-organic material, [Al(DMSO)(6)]Cl-3, which allows for chloride ion transfer. By replacing Cl- with PF6-, the ionic conductivity of the prepared electrolyte is significantly increased, making it a potential candidate for solid-state chloride ion batteries.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

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Article Electrochemistry

Room-temperature Operation of All-solid-state Chloride-ion Battery with Perovskite-type CsSn0.95Mn0.05Cl3 as a Solid Electrolyte

Ryo Sakamoto et al.

Summary: Researchers prepared CsSn0.95Mn0.05Cl3 solid electrolyte, which is a perovskite-type material, via mechanical milling method. The material exhibits high chloride ionic conductivity and is stable at -15℃. They successfully demonstrated the operation of an all-solid-state chloride-ion battery at room temperature using CsSn0.95Mn0.05Cl3 as the electrolyte, with a first discharge capacity of 169 mAh g-1. X-ray diffraction and X-ray photoelectron spectroscopy confirmed the reaction mechanism of the battery.

ELECTROCHEMISTRY (2023)

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Article Chemistry, Physical

Interaction between TEMPO Radicals and Gold Surfaces

Haitao Zhang et al.

Journal of Physical Chemistry C (2023)

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Article Multidisciplinary Sciences

A lithium superionic conductor for millimeter-thick battery electrode

Yuxiang Li et al.

Summary: No design rules have been established for high-conductivity solid electrolytes to replace liquid electrolytes in lithium-ion batteries. By utilizing high-entropy materials, we have developed a highly ion-conductive solid electrolyte through increasing the compositional complexity of a known lithium superionic conductor. The synthesized phase exhibits improved ion conductivity, enabling room temperature charge and discharge of thick lithium-ion battery cathodes and potentially revolutionizing battery configurations.

SCIENCE (2023)

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Article Chemistry, Physical

Fluoride-ion conversion alloy for fluoride-ion batteries

Kei Nakayama et al.

Summary: To achieve high energy density in fluoride-ion batteries, it is necessary to develop better cathode materials. Hydrogen storage alloys such as LaNi5 show promise as candidates for cathode materials, as they can be fluorinated and provide good conductivity. Through atomic-resolution scanning transmission electron microscopy, it was observed that LaNi5 particles decompose into LaF3 and Ni nanocrystals during the charge process, forming a nano-scale network that maintains ion conductivity. This suggests that intermetallic alloys containing two function-sharing elements could be useful in exploring higher capacity cathodes for fluoride-ion batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Multidisciplinary

Substantial Improvement of Operating Stability by Strengthening Metal-Halogen Bonds in Halide Perovskites

Xi Chen et al.

Summary: Solution-processed lead halide perovskites (LHPs) suffer from operating instability due to ionic migration and lattice decomposition. This study shows that the stability can be improved by partially substituting lead with 3d transition metals, such as Mn and Ni, which enhance lattice stability and suppress ionic migration.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Raising the Intrinsic Safety of Layered Oxide Cathodes by Surface Re-Lithiation with LLZTO Garnet-Type Solid Electrolytes

Junyang Wang et al.

Summary: Battery safety concerns have become more prominent as the demand for higher energy density lithium-ion batteries (LIBs) increases. This study demonstrates the use of solid electrolyte Li6.5La3Zr1.5Ta0.5O12 (LLZTO) to supply lithium ions to charged LiCoO2, effectively improving the safety performance of the battery.

ADVANCED MATERIALS (2022)

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Article Chemistry, Physical

Polyxylylviologen Chloride as an Organic Electrode Material for Efficient Reversible Chloride-Ion Storage

Tianchen Xia et al.

Summary: Organic molecules, such as viologens, have shown potential as efficient anion storage materials but are limited by their high solubility. In this study, an insoluble polymerized polyxylylviologen chloride (PXVCl2) was developed as a chloride ion storage electrode in chloride ion batteries. The incorporation of graphene significantly improved the electrode's reaction reversibility and rate capability.

ACS APPLIED ENERGY MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Rechargeable anion-shuttle batteries for low-cost energy storage

Qi Liu et al.

Summary: ASBs, as promising alternatives to lithium-ion batteries, have advantages such as low cost, long cyclic lifetime, and high energy density. This review comprehensively provides insights into the anion shuttling mechanisms of ASBs, including ARBs, DIBs, and RDIBs, while also discussing the latest progresses and challenges in electrode materials and electrolytes for ASBs. Additionally, it summarizes the existing dilemmas of ASBs and outlines the perspective of ASB technology for future grid storage.

CHEM (2021)

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Article Multidisciplinary Sciences

A dynamic stability design strategy for lithium metal solid state batteries

Luhan Ye et al.

Summary: A multi-layered electrolyte design can inhibit the growth of lithium dendrites in solid-state lithium metal batteries, improving their performance. However, practical challenges remain in realizing a lithium metal anode for batteries.

NATURE (2021)

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Article Chemistry, Physical

Water Stable Haloplumbate Modulation for Efficient and Stable Hybrid Perovskite Photovoltaics

Huanhuan Wang et al.

Summary: Commercialization of perovskite solar cells is hindered by operational stability issues, but the use of a water stable haloplumbate for interfacial modification shows promising results in enhancing efficiency and stability, as well as improving the controllability and repeatability of device fabrication.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Superior All-Solid-State Batteries Enabled by a Gas-Phase-Synthesized Sulfide Electrolyte with Ultrahigh Moisture Stability and Ionic Conductivity

Pushun Lu et al.

Summary: Sulfide solid electrolytes (SEs) are considered promising for all-solid-state batteries (ASSBs) due to their superior ionic conductivity and ductility. A one-step gas-phase synthesis method for sulfide SEs with oxide raw materials in ambient air has been developed, achieving high ionic conductivity. ASSBs with Li3.875Sn0.875As0.125S4 show superior performance, breaking records for reversible capacity and cycle life.

ADVANCED MATERIALS (2021)

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Article Multidisciplinary Sciences

Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes

Darren H. S. Tan et al.

Summary: The research successfully achieved stable operation of silicon anodes by using the interface passivating properties of sulfide solid electrolytes. Analysis showed that this approach eliminates continuous interfacial growth and irreversible lithium losses. The promising performance of microsilicon full cells can be attributed to the ideal interface properties between microsilicon and sulfide electrolytes and the unique chemomechanical behavior of the lithium-silicon alloy.

SCIENCE (2021)

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Article Multidisciplinary Sciences

A cost-effective and humidity-tolerant chloride solid electrolyte for lithium batteries

Kai Wang et al.

Summary: Li2ZrCl6 is a cost-effective chloride solid electrolyte with high ionic conductivity, deformability, and humidity tolerance, suitable for high-voltage Li metal batteries.

NATURE COMMUNICATIONS (2021)

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Article Electrochemistry

All-Solid-State Chloride-Ion Battery with Inorganic Solid Electrolyte

Ryo Sakamoto et al.

Summary: The all-solid-state chloride-ion battery demonstrated in this study with KCl-doped PbCl2 as a solid electrolyte shows improved cycle performance by suppressing the dissolution of chloride. The cell with BiCl3 as the cathode exhibits high initial discharge capacity and better cyclability compared to non-aqueous cells. XRD and XPS analysis confirm the unique behavior of conversion reaction during the charge-discharge process.

CHEMELECTROCHEM (2021)

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Review Chemistry, Multidisciplinary

Halide-Based Materials and Chemistry for Rechargeable Batteries

Xiangyu Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Physical

High-Voltage Superionic Halide Solid Electrolytes for All-Solid-State Li-Ion Batteries

Kern-Ho Park et al.

ACS ENERGY LETTERS (2020)

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Article Nanoscience & Nanotechnology

Room-Temperature Stable Inorganic Halide Perovskite as Potential Solid Electrolyte for Chloride Ion Batteries

Tianchen Xia et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Physical

A Na-rich fluorinated sulfate anti-perovskite with dual doping as solid electrolyte for Na metal solid state batteries

Shengsheng Fan et al.

ENERGY STORAGE MATERIALS (2020)

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Review Materials Science, Multidisciplinary

Importance of tailoring lattice strain in halide perovskite crystals

Hui-Seon Kim et al.

NPG ASIA MATERIALS (2020)

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Article Chemistry, Multidisciplinary

An All-Solid-State Rechargeable Chloride Ion Battery

Chao Chen et al.

ADVANCED SCIENCE (2019)

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Article Chemistry, Multidisciplinary

CoFe-Cl Layered Double Hydroxide: A New Cathode Material for High-Performance Chloride Ion Batteries

Qing Yin et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Chemistry, Physical

Stabilizing the CsSnCl3 Perovskite Lattice by B-Site Substitution for Enhanced Light Emission

Ziyan Wu et al.

CHEMISTRY OF MATERIALS (2019)

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Review Chemistry, Multidisciplinary

Chemical stability and instability of inorganic halide perovskites

Yuanyuan Zhou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

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Editorial Material Chemistry, Physical

Can B-Site Doping or Alloying Improve Thermal- and Phase-Stability of All-Inorganic CsPbX3 (X = CI, Br, I) Perovskites?

Abhishek Swarnkar et al.

ACS ENERGY LETTERS (2018)

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Article Chemistry, Physical

Nanoconfined Iron Oxychloride Material as a High-Performance Cathode for Rechargeable Chloride Ion Batteries

Tingting Yu et al.

ACS ENERGY LETTERS (2017)

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Article Chemistry, Physical

Bismuth Incorporation Stabilized α-CsPbI3 for Fully Inorganic Perovskite Solar Cells

Yanqiang Hu et al.

ACS ENERGY LETTERS (2017)

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Article Chemistry, Physical

Doping Mn2+ in Lead Halide Perovskite Nanocrystals: Successes and Challenges

Amit K. Guria et al.

ACS ENERGY LETTERS (2017)

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Article Chemistry, Multidisciplinary

Cubic Perovskite Fluoride as Open Framework Cathode for Na-Ion Batteries

Dunping Cao et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

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Article Nanoscience & Nanotechnology

Developing Polymer Cathode Material for the Chloride Ion Battery

Xiangyu Zhao et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Multidisciplinary Sciences

Pure H- conduction in oxyhydrides

Genki Kobayashi et al.

SCIENCE (2016)

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Article Chemistry, Multidisciplinary

Pressure-Induced Conductivity and Yellow-to-Black Piezochromism in a Layered Cu-Cl Hybrid Perovskite

Adam Jaffe et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Article Chemistry, Physical

Raman and ab Initio Investigation of Aqueous Cu(I) Chloride Complexes from 25 to 80 °C

Lucas M. S. G. A. Applegarth et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2014)

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Article Chemistry, Physical

Chloride ion battery: A new member in the rechargeable battery family

Xiangyu Zhao et al.

JOURNAL OF POWER SOURCES (2014)

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Article Chemistry, Physical

Fast fluoride ion conducting materials in solid state ionics: An overview

L. N. Patro et al.

SOLID STATE IONICS (2013)

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Article Chemistry, Multidisciplinary

TEMPO coated Au nanoparticles: synthesis and tethering to gold surfaces

Olga Swiech et al.

RSC ADVANCES (2013)

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Article Chemistry, Multidisciplinary

One-Dimensional Single-Crystalline Bismuth Oxide Micro/Nanoribbons: Morphology-Controlled Synthesis and Luminescent Properties

B. Ling et al.

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY (2010)

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Article Electrochemistry

Solid electrolytes with predominant chloride conductivity

I. V. Murin et al.

RUSSIAN JOURNAL OF ELECTROCHEMISTRY (2009)

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Article Materials Science, Multidisciplinary

Chloride ion conduction in PbCl2-PbO system

H Matsumoto et al.

MATERIALS RESEARCH BULLETIN (2001)

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Bismuth and Chlorine Dual-Doped Perovskite Chloride as a Phase-Structure-Stable and Moisture-Resistant Solid Electrolyte for Chloride Ion Batteries

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