4.2 Review

Metal-organic frameworks for next-generation energy storage devices; a systematic review

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Article Chemistry, Physical

Investigation of cryo-adsorption hydrogen storage capacity of rapidly synthesized MOF-5 by mechanochemical method

Z. W. Zhu et al.

Summary: This study compared the samples prepared mechanochemically (MOF-5(M)) and solvothermally (MOF-5(S)) for efficient hydrogen storage. The synthesized samples were characterized structurally and their hydrogen adsorption equilibrium was measured at temperature-pressure range 77 K -87 K and 0.1-10 MPa. GCMC simulations were also conducted to study the adsorption behavior of hydrogen molecules on MOF-5. The results showed that the mechanochemical method had advantages of large scale synthesis and lower cost, and it increased the specific surface area and maximum excess adsorption capacity of hydrogen by 207% and 90.5% respectively at 77 K within pressure range 0-10 MPa. The crystal within MOF-5(M) was more regular and uniformly distributed with a smaller size compared to MOF-5(S). Toth equation could effectively predict the adsorption equilibrium data of hydrogen on both MOF-5 samples with a mean relative error less than 1.5% at 77 K within pressure range 0-10 MPa. These findings suggest that MOF-5(M) is more promising for practical applications of hydrogen storage by adsorption.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Article Chemistry, Multidisciplinary

Exploring MOF-199 composites as redox-active materials for hybrid battery-supercapacitor devices

Muhammad Zahir Iqbal et al.

Summary: In this study, a copper-based metal-organic framework (MOF-199) was synthesized and its application in energy storage was investigated. By preparing composites with graphene and polyaniline (PANI), the electrochemical characteristics of MOF-199 were significantly enhanced. A hybrid supercapacitor (MOF-199)/PANI//activated carbon was fabricated, which showed excellent energy and power density, and maintained appreciable capacity even after 1000 charge-discharge cycles. The capacitive and diffusive contributions of the device were calculated using Dunn's model, confirming its hybrid nature.

RSC ADVANCES (2023)

Review Energy & Fuels

Metal-Organic Frameworks-Based Cathode Materials for Energy Storage Applications: A Review

Saravanan Nagappan et al.

Summary: Recently, metal-organic frameworks (MOFs)-based cathode materials have gained significant attention for their high surface area, controlled architecture, porosity, and tunability. By altering the synthesis techniques, the performance of MOF-based cathodes can be improved for specific battery applications. The review article provides a comprehensive overview of the uniqueness and history of MOF-based cathodes, their advantages and disadvantages, various synthesis approaches, and their use in different battery applications.

ENERGY TECHNOLOGY (2023)

Article Chemistry, Multidisciplinary

Sr(II) and Ba(II) Alkaline Earth Metal-Organic Frameworks (AE-MOFs) for Selective Gas Adsorption, Energy Storage, and Environmental Application

Nikolas Kiraly et al.

Summary: Two new alkaline earth metal-organic frameworks, UPJS-15 and UPJS-16, were synthesized and characterized. UPJS-15 exhibited one-dimensional channels with a size of approximately 11 x 10 angstrom(2) and showed high adsorption capacity for CO2. UPJS-16, on the other hand, did not show significant adsorption for the tested gases.

NANOMATERIALS (2023)

Review Chemistry, Inorganic & Nuclear

Advances in metal-organic frameworks for efficient separation and purification of natural gas

Haiming Yang et al.

Summary: Natural gas, as an essential chemical raw material and a promising clean energy source, is in high demand. Metal-organic frameworks (MOFs), a type of porous materials, have shown great potential for gas separation and purification due to their unique properties. This article summarizes the recent research progress of using MOFs as adsorbents for the separation of different gases in natural gas and discusses future research directions.

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY (2023)

Review Chemistry, Inorganic & Nuclear

Structure-directed growth and morphology of multifunctional metal-organic frameworks

Qi Huang et al.

Summary: Metal-organic frameworks (MOFs) have attracted much attention in materials science due to their tunability in structure, allowing for precise control of size and morphology. Hierarchical MOFs and their derivatives possess unique physicochemical properties, such as special morphology, controllable nanostructure, ultra-high porosity, and large specific surface area, making them widely used in the fields of environment and energy.

COORDINATION CHEMISTRY REVIEWS (2023)

Article Chemistry, Multidisciplinary

Eco-Environmental Analysis of Different Routes for the Synthesis of MIL-53(Fe): An Integrated Life Cycle Assessment and Life Cycle Cost Approaches

Davood Mohammady Maklavany et al.

Summary: This study conducted a cradle-to-gate life cycle assessment and life cycle costing of five MIL-53(Fe) synthesis routes to assess the potential environmental impacts and economics of its production. The results showed that using environmentally friendly reagents/solvents like water can reduce adverse effects on the environment and costs, and the fifth route is the most suitable method for producing MIL-53(Fe) due to its simplicity and lowest environmental impact and cost.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

Review Chemistry, Applied

Toward high-sulfur-content, high-performance lithium-sulfur batteries: Review of materials and technologies

Fulai Zhao et al.

Summary: Lithium sulfur batteries (LSBs) are promising for future energy storage systems due to their higher theoretical energy density and lower cost compared to lithium-ion batteries. However, issues such as lithium polysulfide dissolution and large volume expansion during electrochemical reactions hinder their industrial use. This review focuses on the development of novel preparation methods and cathode materials for LSBs, considering sulfur content and cycle performance.

JOURNAL OF ENERGY CHEMISTRY (2023)

Review Chemistry, Physical

Recent Advances in Metal-Organic Framework-Based Nanomaterials for Electrocatalytic Nitrogen Reduction

Bo Han et al.

Summary: This paper provides a comprehensive review on the application and development of metal-organic framework (MOF) catalysts in the electrochemical nitrogen reduction reaction (E-NRR) field. It first introduces the basic principles of E-NRR, including the reaction mechanism, major apparatus components, performance criteria, and ammonia detection protocols. Then, the synthesis and characterization methods for MOFs and their derivatives are discussed. A reaction mechanism study via density functional theory calculations is also presented. Furthermore, the recent advancement of MOF-based catalysts in the E-NRR field, as well as the modification approaches on MOFs for E-NRR optimization, are elaborated. Finally, the current challenges and outlook of MOF catalyst-based E-NRR field are emphasized.

SMALL METHODS (2023)

Article Engineering, Environmental

The intercalation cathode of MOFs-driven vanadium-based composite embedded in N-doped carbon for aqueous zinc ion batteries

Xiuting Wu et al.

Summary: This study demonstrates a novel cathode material, ZnVO-800, derived from zeolitic imidazolate framework-8 (ZIF-8) by a self-sacrificed route. The ZnVO-800 cathode exhibits outstanding electrochemical performance, with high reversible capacity and excellent cycleability in aqueous zinc ion batteries. The electrochemical mechanism involves the transformation of ZnVO-800 into ZnxV2O5·nH(2)O with high electrochemical activity through in-situ electrochemical activation process, and the heterojunction with hierarchical structure enhances the dynamics and long-term cycleability.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Chemistry, Inorganic & Nuclear

The application of MOFs for hydrogen storage

Xiaocheng Zhang et al.

INORGANICA CHIMICA ACTA (2023)

Article Chemistry, Physical

MOF derived cobalt-nickel bimetallic phosphide (CoNiP) modified separator to enhance the polysulfide adsorption-catalysis for superior lithium-sulfur batteries

Hangyi Zhu et al.

Summary: To further develop lithium-sulfur batteries, it is crucial to enhance the adsorption and catalytic conversion of lithium polysulfides. This study presents a novel approach by encapsulating Ni/Co bimetallic phosphides into a nitrogen-doped dual carbon conductive network, which greatly improves the anchoring and catalytic conversion of LiPSs and provides fast channels for Li+ transport. The experimental results demonstrate outstanding performance and cycle stability, making it a promising strategy for high-power advanced lithium-sulfur batteries.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Chemistry, Physical

Efficient Generation of Large Collections of Metal-Organic Framework Structures Containing Well-Defined Point Defects

Zhenzi Yu et al.

Summary: High-throughput molecular simulations of MOFs are valuable in identifying candidates for chemical separation and storage, complementing experimental efforts. We introduce a tool to generate missing-linker defects in MOFs and study the impact of defects on molecular adsorption. Defects have varying effects on different adsorbates, with a slightly negative or negligible influence on some, such as ethene, ethane, and CO2, but a strong positive influence on methanol due to hydrogen bonding with defects. Defective structures tend to have higher loadings than defect-free structures under elevated pressures.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2023)

Article Chemistry, Multidisciplinary

Conductive Lanthanide Metal-Organic Frameworks with Exceptionally High Stability

Chao-Long Chen et al.

Summary: Electrically conductive metal-organic frameworks (MOFs) have been extensively studied for their potential uses in energy-related technologies and sensors. A new series of lanthanide-based MOFs have been designed and synthesized, showing remarkable stability and conductivity under varying solution environments and temperatures.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Nanoscience & Nanotechnology

Sorption Thermal Energy Storage Performance of Nanoporous Metal-Organic Frameworks and Covalent Organic Frameworks by Grand Canonical Monte Carlo Simulations

Wei Li et al.

Summary: Developing materials with high performance for sorption thermal energy storage (STES) is crucial for the utilization of renewable energy. Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have attracted significant interest due to their excellent adsorption properties. This study evaluated and compared the material-based energy density (Q (ed)) of MOFs and COFs for STES using Monte Carlo simulations. It was found that most MOFs exhibited larger Q (ed) than COFs due to their high loading during the charging process. However, one COF showed the highest Q (ed) due to its low density and complete desorption during the discharging process, suggesting that COFs can have excellent performance if they achieve sufficient capacity during charging. The structure-property relationship indicated that large pore volume, relatively small density, suitable carbon atom ratio, and isotropic 3D cage were favorable for high-Q (ed) structures. The successful implementation of data mining and machine learning algorithms facilitates the rational design and rapid assessment of Q (ed) for nanoporous materials.

ACS APPLIED NANO MATERIALS (2023)

Review Chemistry, Multidisciplinary

Reticular Chemistry for Highly Porous Metal-Organic Frameworks: The Chemistry and Applications

Zhijie Chen et al.

Summary: This article summarizes recent progress in the synthesis and application of highly porous metal-organic frameworks (MOFs) inspired by reticular chemistry. The authors first introduce the synthesis of NU-1500 and NU-1501 using reticular chemistry and discuss their potential applications in storing clean energy gases such as hydrogen and methane. They then present the rational synthesis of highly porous and stable Zr-MOFs based on edge-transitive nets, and provide an overview of the potential applications of these MOFs, including water capture, catalysis, gas storage, etc. Overall, this Account provides valuable insights and inspiration for the development of next-generation highly porous materials for energy and environment-related applications.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

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Molecular Design Strategies toward Improvement of Charge Injection and Ionic Conduction in Organic Mixed Ionic-Electronic Conductors for Organic Electrochemical Transistors

Nadzeya A. Kukhta et al.

Summary: This review focuses on recent material developments and current challenges in mixed conductors for bioelectronic applications. It also highlights the fundamental operation principles of the OECT and the current bioelectronic applications of OMIECs, as well as potential strategies for mitigating challenges in OECT channel materials.

CHEMICAL REVIEWS (2022)

Article Energy & Fuels

Review of Carnot Battery Technology Commercial Development

Vaclav Novotny et al.

Summary: Carnot batteries are a group of rapidly developing technologies for medium and long duration electricity storage, which convert power to heat for storage and back to electricity when needed. They are suitable for storing surplus renewable energy with their low cost and long lifespan. Research and development on Carnot batteries have attracted attention from both academia and industry.

ENERGIES (2022)

Article Chemistry, Physical

A new rapid synthesis of hexagonal prism Zn-MOF as a precursor at room temperature for energy storage through pre-ionization strategy

Nana Liu et al.

Summary: A new hexagonal prismatic Zn-MOF was rapidly synthesized at room temperature using a one-step precipitation method, and served as a precursor for the preparation of porous carbon with superior supercapacitor performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Review Chemistry, Analytical

2D MXenes: Synthesis, properties, and electrochemical energy storage for supercapacitors-A review

Mutawara Mahmood Baig et al.

Summary: Supercapacitors, compared to conventional dielectric capacitors, offer higher energy storage capacities but lower than secondary batteries. MXenes, as a family of materials with high surface area and conductivity, significantly enhance the energy storage characteristics of supercapacitors.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2022)

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Nanostructured Conductive Metal Organic Frameworks for Sustainable Low Charge Overpotentials in Li-Air Batteries

Leily Majidi et al.

Summary: This study discovered the outstanding characteristics of a conductive metal organic framework (c-MOF), which promotes the growth of nanocrystalline Li2O2 and enables fast discharge at high current rates. In addition, the structure of Li2O2 works synergistically with the redox mediator (RM) to achieve long cycle life and high capacity under high current densities.
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In Situ/Operando Insights into the Stability and Degradation Mechanisms of Heterogeneous Electrocatalysts

Lindong Liu et al.

Summary: The further commercialization of renewable energy conversion and storage technologies requires durable heterogeneous electrocatalysts, and studying the stability and degradation mechanisms of these electrocatalysts is crucial for breakthroughs in stability issues. In situ/operando techniques performed under realistic reaction conditions are urgently needed to understand the nature of active center structures and establish links between structural motifs in a catalyst and its stability properties.
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MOFs-Graphene Composites Synthesis and Application for Electrochemical Supercapacitor: A Review

Surendra K. Shinde et al.

Summary: This review discusses the application of MOFs/graphene nanocomposites in supercapacitors. The reported results indicate that MOFs/G, MOFs/GO, and MOFs/rGO nanocomposites can considerably improve the structural, morphological, and electrochemical performance of supercapacitors.

POLYMERS (2022)

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Metal-Supported Biochar Catalysts for Sustainable Biorefinery, Electrocatalysis, and Energy Storage Applications: A Review

Ruben Ramos et al.

Summary: Biochar is a carbon-based bio-material derived from the thermochemical conversion of biomass. By activating or functionalizing biochar, its physicochemical and functional properties can be improved. In the context of green and sustainable development, activated and functionalized biochar can serve as catalysts or catalyst supports for the chemical transformation of bioproducts. This review focuses on the production/activation/functionalization of metal-supported biochar and discusses their potential as promising catalysts for bioenergy and bioproducts production.

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Article Chemistry, Multidisciplinary

One-Step MOF-Templated Strategy to Fabrication of Ce-Doped ZnIn2S4 Tetrakaidecahedron Hollow Nanocages as an Efficient Photocatalyst for Hydrogen Evolution

Huitao Fan et al.

Summary: This study successfully synthesized Ce-doped ZnIn2S4 photocatalysts with hollow nanocages using a one-step hydrothermal method. Both experimental and theoretical results showed that the doping of Ce and the formation of hollow nanocages improved light capture and the separation of photogenerated charge carriers.

ADVANCED SCIENCE (2022)

Review Chemistry, Multidisciplinary

Metal-organic frameworks for advanced transducer based gas sensors: review and perspectives

Sanjit Manohar Majhi et al.

Summary: In the past few decades, there has been a surge of interest in the development of gas sensing devices to detect environmentally toxic, hazardous, and volatile organic compounds, largely driven by technological advancements in the field. Metal-organic frameworks (MOFs) have attracted significant attention in various fields, including gas sensing, due to their high adsorption sites, porosity, tunable morphologies, structural diversities, and room temperature sensing capabilities.

NANOSCALE ADVANCES (2022)

Review Chemistry, Physical

Hybridization of Emerging Crystalline Porous Materials: Synthesis Dimensionality and Electrochemical Energy Storage Application

Huanhuan Zhang et al.

Summary: Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are crucial components in crystalline porous materials, offering vast structural diversity and adjustability. By hybridizing MOFs or COFs with other materials, issues like poor conductivity and weak mechanical properties can be effectively addressed. Various hybridization techniques at different scales have been developed for the preparation of MOF and COF hybrids, with representative applications in electrochemical energy storage devices. The basic principles and mechanisms guiding hybridization have also been elucidated.

ADVANCED ENERGY MATERIALS (2022)

Review Chemistry, Physical

Micro/Nano-Scaled Metal-Organic Frameworks and Their Derivatives for Energy Applications

Yong-Sheng Wei et al.

Summary: Metal-organic frameworks (MOFs) are crystalline porous materials constructed by organic linkers and metal ions/clusters, with high surface area and functional adjustability, leading to versatile applications. This review focuses on the design and synthesis of 1D, 2D, and 3D MOF nanostructures and their derivatives, discussing promising catalytic applications and energy storage, outlining the challenges and future prospects for this emerging field.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Multidisciplinary

Metal-Organic Frameworks Derived Electrolytes Build Multiple Wetting Interfaces for Integrated Solid-State Lithium-Oxygen Battery

Xiao-Xue Wang et al.

Summary: This study presents a high-performance solid-state lithium-oxygen battery with Li-ion-conducted UiO-67 as solid-state electrolyte and UiO-67-Li@rGO aerogel as solid-state cathode. The battery achieves suppression of anode dendrite formation, resistance to corrosion, and multiple low-impedance wetting interfaces, resulting in low overpotential, superior rate capability, and stable cycling life.

ADVANCED FUNCTIONAL MATERIALS (2022)

Review Chemistry, Multidisciplinary

Conductive Metal-Organic Frameworks for Supercapacitors

Liang Niu et al.

Summary: Metal-organic frameworks (MOFs) are porous materials with crystal lattices, which have attracted significant attention in the past two decades due to their exceptional specific surface area, tunable functionality, and versatile structures. This article summarizes the progress made in the synthesis and design of conductive MOFs, with particular focus on their application in electrochemical energy storage, specifically supercapacitors. The electronic and molecular aspects of the energy storage mechanism in supercapacitors with MOF electrodes are discussed, highlighting the advantages and limitations of conductive MOFs and inspiring new ideas for their development in supercapacitors.

ADVANCED MATERIALS (2022)

Article Engineering, Environmental

MOF-5 as anodes for high-temperature potassium-ion batteries with ultrahigh stability

Xianlu Lu et al.

Summary: Potassium-ion batteries (PIBs) are a promising modern energy storage device with high energy density and commercial application potential. However, their cycle stability under high-temperature conditions is a major challenge. In this study, we successfully developed high-temperature PIBs with ultrahigh stability by using metal organic framework-5 (MOF-5) as the anode material.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Chemistry, Multidisciplinary

Freestanding Metal-Organic Frameworks and Their Derivatives: An Emerging Platform for Electrochemical Energy Storage and Conversion

Bing He et al.

Summary: Metal-organic frameworks (MOFs) have shown great potential in electrochemical energy storage and conversion (EESC) due to their unique properties. Freestanding electrodes provide a promising platform for MOF-based materials, enabling superior electrochemical performance. This review provides a comprehensive overview of the structural features, fabrication techniques, and recent advances of freestanding MOF electrodes, as well as discussing the challenges and future perspectives for their scale-up production and commercial applications.

CHEMICAL REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Trimetallic metal-organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion

Xinzhi Luo et al.

Summary: Nowadays, there is significant research focus on advanced technologies for energy storage and conversion, and metal-organic frameworks (MOFs) have attracted attention due to their structural diversity and tunable properties. Multimetallic MOFs, compared to mono-and bimetallic MOFs, have advantages in terms of enhanced electrochemical activity and electronic conductivity. The addition of other metals to MOF structures can improve their electrochemical behavior and electrical conductivity, and the ratios of metals can be adjusted to tune various physicochemical properties. This review discusses recent developments in heterotrimetallic MOFs and their derivatives as extraordinary materials for various energy applications, providing a roadmap for the introduction of heterotrimetallic MOFs as advanced materials for electrochemical energy storage and conversion.

COORDINATION CHEMISTRY REVIEWS (2022)

Article Chemistry, Multidisciplinary

Understanding Solvothermal Growth of Metal-Organic Framework Colloids for CO2 Capture Applications

Pei-Fang Hsieh et al.

Summary: This study demonstrated the synthesis of metal-organic framework (MOF) colloids via a solvothermal growth process using electrospray-differential mobility analysis (ES-DMA). The results showed the effects of synthetic parameters on the properties of Cu-MOF, and confirmed the correlation between mobility size increase and crystallinity. The experiment also showed the good CO2 adsorption ability of synthesized Cu-MOF.

LANGMUIR (2022)

Review Green & Sustainable Science & Technology

A comprehensive review of stationary energy storage devices for large scale renewable energy sources grid integration

Abraham Alem Kebede et al.

Summary: This study investigates the current status and applicability of energy storage devices and identifies the most suitable types for grid support applications. Various criteria such as technical, economic, and environmental impact evaluations are considered to determine the characteristics and potentials of different storage technologies. The findings show that a hybrid solution with a combination of various storage devices is a viable option in the sector.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2022)

Article Chemistry, Physical

Self-activation effect in bimetallic MgMn2O4 and boosting its electrochemical performance using metal-organic framework template for magnesium-ion battery cathodes

Cheng Dong et al.

Summary: Efficient cubic spinel MgMn2O4 cathode materials were prepared by annealing bimetallic metal-organic frameworks, exhibiting excellent cyclability and fast ion diffusion channels. A self-activation effect occurred during the cycling process, improving the kinetic behavior of Mg ions in the spinel structure.

MATERIALS TODAY ENERGY (2022)

Article Chemistry, Physical

Fabrication of Sustainable Hybrid MOF/Silica Electrodes for Current Lithium-ion Batteries and Beyond

Zohre Parviz et al.

Summary: This study introduces an effective strategy for synthesizing silica-based anodes for lithium-ion batteries. The silica-based electrode demonstrates excellent electrochemical performance and compatibility with ether-based electrolytes, suggesting its potential applications in high-energy and environmentally sustainable lithium-based batteries.

ACS APPLIED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Sulfurization-functionalized 2D metal-organic frameworks for high-performance urea fuel cell

Xiang Ao et al.

Summary: Urea electrolysis is an effective solution for energy and environment issues. The use of a hierarchical structure derived from metal-organic framework improves catalytic activity and durability, offering potential for cost-effective hydrogen production and urea fuel cells.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Review Social Sciences, Interdisciplinary

Metaverse through the prism of power and addiction: what will happen when the virtual world becomes more attractive than reality?

Ljubisa Bojic

Summary: New technologies, such as the metaverse, are emerging rapidly, but their social impact and regulation are not adequately analyzed. Research is focusing on expectations and impacts of the metaverse, as well as potential power shifts and media addiction levels in society.

EUROPEAN JOURNAL OF FUTURES RESEARCH (2022)

Review Energy & Fuels

Applications of Transition Metal (Fe, Co, Ni)-Based Metal-Organic Frameworks and their Derivatives in Batteries and Supercapacitors

Xinguo Jin et al.

Summary: This review summarizes the characteristics and applications of MOFs based on transition metals and their derivatives, and reveals the relationship between their structures and performance.

TRANSACTIONS OF TIANJIN UNIVERSITY (2022)

Article Electrochemistry

Ionic Liquid-Incorporated Metal-Organic Framework with High Magnesium Ion Conductivity for Quasi-Solid-State Magnesium Batteries

Zhixuan Wei et al.

Summary: This study reports on a new magnesium ion conducting ionogel electrolyte based on a Metal-Organic Framework structure, which shows potential for use in quasi-solid-state magnesium batteries. The findings suggest that MOF-based materials are promising for QSSMBs.

BATTERIES & SUPERCAPS (2022)

Article Chemistry, Multidisciplinary

Ni-MOF composite polypyrrole applied to supercapacitor energy storage

Zhao Qin et al.

Summary: The electrode composite material Ni-MOF@PPy was synthesized to improve the electron transfer property of supercapacitor electrodes. With the addition of an electrochemically active substance, the composite material exhibited high specific capacitance. The Ni-MOF@PPy//AC ASC energy storage device showed excellent energy density, power density, and capacitance retention.

RSC ADVANCES (2022)

Review Engineering, Environmental

Progress and potential of metal-organic frameworks (MOFs) for gas storage and separation: A review

Tao Jia et al.

Summary: Gas storage and separation are crucial in the utilization of energy resources and the petrochemical industry. Metal-organic frameworks (MOFs) are emerging porous crystalline materials that can store energy-related gases with high density and separate target gases from hydrocarbon mixtures through host-guest interactions or sieving effects. This review summarizes recent advances in MOFs for hydrogen, methane, and acetylene storage, as well as carbon dioxide capture and light hydrocarbon separation, and discusses strategies for constructing efficient MOF adsorbents and material design.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

Review Chemistry, Multidisciplinary

Organo-macrocycle-containing hierarchical metal-organic frameworks and cages: design, structures, and applications

Yu Liang et al.

Summary: Developing hierarchical ordered systems using organo-macrocycles as building blocks is an efficient method to obtain metal-organic frameworks (MOFs) and porous coordination cages (PCCs). These macrocycles, such as crown ethers, cyclodextrins, calixarenes, cucurbiturils, and pillararenes, not only enhance the properties and functionalities of the composites but also have a wide range of applications. This review summarizes the recent developments of organo-macrocycle-containing hierarchical MOFs/PCCs, focusing on the structure-property relationships and applications of these hierarchically porous materials. It provides insights for future research on hierarchical self-assembly and extends the applications of the composites.

CHEMICAL SOCIETY REVIEWS (2022)

Review Chemistry, Multidisciplinary

Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage

Jing Zhu et al.

Summary: Due to the excessive consumption of nonrenewable resources, the exploration of effective and durable materials for sustainable energy conversion and storage is highly sought after. Metal-organic frameworks (MOFs) are a new class of hybrid materials that have gained traction in energy-related fields. Vanadium-MOFs (V-MOFs) possess unique structural characteristics and satisfactory electrochemical properties. Furthermore, V-MOFs-derived materials also exhibit superior electrical conductivity and stability when used as electrocatalysts and electrode materials. This review summarizes the research progress and potential applications of V-MOFs and their derivatives in electrochemical energy conversion and storage. Future possibilities and challenges in terms of design and synthesis are also discussed.

SMARTMAT (2022)

Article Materials Science, Multidisciplinary

Will lithium-sulfur batteries be the next beyond-lithium ion batteries and even much better?

Jianguo Sun et al.

Summary: Lithium-ion batteries are widely used in portable electronic devices, electric vehicles, and stationary energy storage, but there is a need for beyond lithium-ion batteries with higher energy density and lower cost. Lithium-sulfur batteries have been extensively pursued due to their high energy density, but poor cyclability remains a major challenge. This perspective examines the challenges and opportunities faced by lithium-sulfur batteries and proposes approaches at different levels to transform them into leading champions in the pursuit of beyond lithium-ion batteries. Suggestions for near-future research directions for both liquid and solid state lithium-sulfur batteries are also provided.

INFOMAT (2022)

Article Chemistry, Multidisciplinary

Hierarchical large-pore MOFs templated from poly(ethylene oxide)-b-polystyrene diblock copolymer with tuneable pore sizes

Jingwen Chen et al.

Summary: Diblock copolymer poly(ethylene oxide)-b-poly(styrene) (PEO-b-PS) was utilized as a template for the synthesis of hierarchically porous Ce-based metal-organic frameworks (MOFs) for the first time. The mesopore size of UiO-66 type Ce-MOFs was achieved to be about 15 nm, which could be further tuned up to approximately 23 nm by introducing 1,3,5-trimethylbenzene to the micelle core of PEO-b-PS.

CHEMICAL COMMUNICATIONS (2022)

Proceedings Paper Materials Science, Multidisciplinary

Adsorption of CO2 on ZSM-5 and Cu-MOF at room temperature and low pressure conditions for Carbon Capture and Storage (CCS) application

N. K. Daud et al.

Summary: This study investigates and compares the performance of zeolite and copper metal-organic framework as adsorbents for CO2 capture. The results show that zeolite exhibits higher CO2 adsorption capacity compared to copper metal-organic framework in a low pressure system. The optimum adsorption conditions are determined to be 200 mg adsorbent dosage and 1 bar inlet pressure.

MATERIALS TODAY-PROCEEDINGS (2022)

Article Chemistry, Physical

Metal-organic-framework-derived vanadium(iii) phosphate nanoaggregates for zinc-ion battery cathodes with long-term cycle stability

Suk-Ho Hwang et al.

Summary: This study explores the use of VPO4 as a cathode material for aqueous zinc-ion batteries. By using simultaneous carbonization/phosphidation processes, highly crystalline VPO4 nanoparticles are formed in a vanadium-based metal-organic framework. These nanoparticles are interconnected by a conductive thin carbon network. The HVPO cathode exhibits superior rate capability and long cycle life, with pseudocapacitive charge-storage performance.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Review Chemistry, Physical

Recent progress on synthesis of ZIF-67-based materials and their application to heterogeneous catalysis

Chongxiong Duan et al.

Summary: This article reviews the latest strategies for synthesizing and applying ZIF-67-based materials, as well as their applications in heterogeneous catalysis. The materials have many advantages, such as high surface area, tunable porosity, and excellent thermal and chemical stabilities, leading to promising applications.

GREEN ENERGY & ENVIRONMENT (2022)

Review Chemistry, Multidisciplinary

Metal-Organic Framework Derived Bimetallic Materials for Electrochemical Energy Storage

Soheila Sanati et al.

Summary: This review focuses on the use of MOF-derived bimetallic materials in supercapacitors, highlighting their advantages including tunable electrochemical activity, high charge capacity, and improved electrical conductivity. The challenges and perspectives in this research area are also discussed.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Layered V-MOF nanorods for rechargeable aqueous zinc-ion batteries

Yue Ru et al.

Summary: Metal-organic frameworks (MOFs) are drawing attention due to their controllable morphologies, adjustable aperture, and large specific surface areas. A typical V-MOF (MIL-47) product is successfully synthesized via a one-step hydrothermal method, with a one-dimensional layered nanorod-like framework. The V-MOF product, with a rhomboid structure and empty channels, is used as the cathode material for the aqueous MOF-Zn battery, showing high specific capacity, rate capability, and cycling performance.

MATERIALS TODAY CHEMISTRY (2021)

Article Nanoscience & Nanotechnology

Enhanced Potassium-Ion Storage of the 3D Carbon Superstructure by Manipulating the Nitrogen-Doped Species and Morphology

Yanhua Li et al.

Summary: In this study, an eco-efficient synthetic route was developed to create carbon superstructures with enhanced nitrogen-rich active facets for improved potassium-ion storage capabilities. By regulating the nitrogen doping types and morphology, the performance of the carbon superstructures was significantly enhanced.

NANO-MICRO LETTERS (2021)

Article Chemistry, Multidisciplinary

Robust Solid Electrolyte Interphases in Localized High Concentration Electrolytes Boosting Black Phosphorus Anode for Potassium-Ion Batteries

Xiaoqiong Du et al.

Summary: This study synthesized a BP-G composite with high BP loading and stabilized it with a localized high concentration electrolyte, revealing the benefits of high concentration electrolytes and the importance of stabilizing SEI films.

ACS NANO (2021)

Review Chemistry, Multidisciplinary

Flexible Transparent Supercapacitors: Materials and Devices

Weiwei Zhao et al.

Summary: This review comprehensively summarizes the rational design of nanostructured electrode materials towards flexible transparent supercapacitors (FTSCs), as well as the principles and applications of diverse electrode materials to achieve flexible transparent conductive electrodes (FTCEs). The achievements in multifunctional FTSCs are highlighted, and the current challenges and future perspectives on viable materials for powering portable electronics are outlined.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Physical

Review on the electromagnetic interference shielding properties of carbon based materials and their novel composites: Recent progress, challenges and prospects

Nannan Wu et al.

Summary: The rapid development of electronic devices has raised concerns about electromagnetic radiation issues, and the most effective way to address electromagnetic pollution is to fabricate electromagnetic interference shielding materials and microwave absorption materials with lightweight and strong attenuation abilities. Carbon nanocomposites have attracted attention in the field of electromagnetic interference shielding due to their low density, natural abundance, easy preparation, excellent conductivity, and flexibility. Recent advancements in carbon materials as ESMs/MAMs have shown that 3D carbon materials and novel composites have the potential to enhance electromagnetic interference shielding efficiency.

CARBON (2021)

Review Environmental Sciences

UiO series of metal-organic frameworks composites as advanced sorbents for the removal of heavy metal ions: Synthesis, applications and adsorption mechanism

Jing Ru et al.

Summary: Heavy metal pollution poses a threat to the environment and human health, making effective removal of these toxic pollutants a priority. Metal-organic frameworks (MOFs) have gained attention in environmental analytical chemistry due to their porous structure and stability. This review focuses on the applications of UiO series MOFs for removing heavy metal ions from various environmental samples, discussing their synthesis, adsorption characteristics, and future trends in MOF-based composites for pollutant removal.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2021)

Article Engineering, Environmental

Electrospun MOF-based ZnSe nanocrystals confined in N-doped mesoporous carbon fibers as anode materials for potassium ion batteries with long-term cycling stability

Jeong Ho Na et al.

Summary: This study designed a novel N-doped porous carbon nanofibers as an advanced anode material for KIBs with excellent electrochemical performance, mainly prepared by electrospinning and thermal treatment methods. These electrode materials have a unique one-dimensional structure, providing sufficient active sites for potassium ion storage, and showing remarkable performance in cycling stability.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Microwave-assisted synthesis of Zr-based metal-organic framework (Zr-fum-fcu-MOF) for gas adsorption separation

Hao Liu et al.

Summary: A reliable strategy to synthesize Zr-based metal-organic framework was successfully achieved using microwave assistance, demonstrating high adsorption capacities for various gases, particularly CO2 capture.

CHEMICAL PHYSICS LETTERS (2021)

Review Chemistry, Inorganic & Nuclear

Multicomponent isoreticular metal-organic frameworks: Principles, current status and challenges

Archisman Dutta et al.

Summary: Multicomponent Isoreticular Metal-Organic Frameworks (MI-MOFs) are materials designed with multiple linkers or mixed-metals as secondary building units, showing potential in various fields, but face challenges in controlling the periodicity and long-range order of components.

COORDINATION CHEMISTRY REVIEWS (2021)

Review Chemistry, Inorganic & Nuclear

Metal organic frameworks as hybrid porous materials for energy storage and conversion devices: A review

Sakshi Chuhadiya et al.

Summary: Metal organic frameworks (MOFs) have gained attention as a porous crystalline hybrid material with unique properties such as tunable porosities and high surface area, making them a focus in the energy storage and conversion field.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Multidisciplinary Sciences

Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework

Omid T. Qazvini et al.

Summary: Researchers present a metal-organic framework adsorbent, MUF-16, that efficiently captures CO2 over other competing gases with high selectivity. This adsorbent enables high-purity gas separation under dynamic conditions, making it suitable for the purification of natural gas and industrial feedstocks.

NATURE COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

The Role of Defects in Metal-Organic Frameworks for Nitrogen Reduction Reaction: When Defects Switch to Features

Islam E. Khalil et al.

Summary: The focus of research is on designing efficient electrocatalysts through defect engineering, with metal-organic frameworks (MOFs) and their derivatives gaining interest for providing more active sites to enhance electrochemical reactions. The paper summarizes in situ characterization techniques for defects, common methods for creating defects in MOFs, recent advances in MOF-based electrocatalysts for NRR, and proposes challenges and outlook for defects in MOFs for NRR.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Materials Science, Multidisciplinary

Microwave-assisted solvothermal synthesis of bimetallic metal-organic framework for efficient photodegradation of organic dyes

Hong-Tham T. Nguyen et al.

Summary: The study investigated the synthesis of M/Fe-MOFs using a microwave-assisted solvothermal method, characterized their properties through various techniques, explored their photocatalytic degradation of organic dyes, proposed a mechanism for RhB dye degradation, and evaluated the stability and reusability of the materials. The results are expected to expand the understanding of bimetallic MOF synthesis and applications.

MATERIALS CHEMISTRY AND PHYSICS (2021)

Review Chemistry, Physical

An extensive review on three dimension architectural Metal-Organic Frameworks towards supercapacitor application

Ankita Mohanty et al.

Summary: MOFs are emerging as new materials for supercapacitor applications due to their inherent porous characteristics. However, the insulating nature of pristine MOFs has hindered their usage in supercapacitors, leading to successful strategies such as hybridization with other materials or using MOFs as templates to derive metal oxides, carbon, or hydroxides.

JOURNAL OF POWER SOURCES (2021)

Article Chemistry, Physical

Potassium-ion battery cathodes: Past, present, and prospects

Zhenrui Wu et al.

Summary: Potassium-ion batteries (KIBs) have demonstrated high energy densities and power densities since 2004, with Prussian blue analogs (PBAs) currently being the most suitable cathodes. Other cathodes, such as tunnel-type manganese oxide and bilayered vanadium pentoxide, also exhibit stable energy densities over 500 Wh kg(-1). However, developing competitive high energy density KIB cathodes with stable and long cycling life remains a challenge.

JOURNAL OF POWER SOURCES (2021)

Article Materials Science, Multidisciplinary

A new calcium metal organic frameworks (Ca-MOF) for sodium ion batteries

Fangyuan Xiao et al.

Summary: A novel calcium metal organic framework (CaBDC) has been successfully synthesized through ion exchange, showing suitable voltage plateau for sodium-ion storage. The material exhibits high capacity retention and excellent rate performance, making it a promising anode material for sodium-ion batteries.

MATERIALS LETTERS (2021)

Article Materials Science, Multidisciplinary

Industrializing metal-organic frameworks: Scalable synthetic means and their transformation into functional materials

Wei Liang Teo et al.

Summary: This review provides an up-to-date summary of the progress towards industrialization of metal-organic frameworks (MOFs), discussing the latest developments in scalable production and processing methods, as well as evaluating their industrial utilization potentials.

MATERIALS TODAY (2021)

Article Materials Science, Multidisciplinary

Mechanochemistry: Toward green synthesis of metal-organic frameworks

Sylwia Glowniak et al.

Summary: Metal-organic frameworks (MOFs) are receiving special attention for their adjustable pore sizes and high potential in various applications, with mechanochemistry seen as an efficient and environmentally friendly synthesis method.

MATERIALS TODAY (2021)

Article Chemistry, Applied

Advanced metal-organic frameworks for aqueous sodium-ion rechargeable batteries

Dongkyu Choi et al.

Summary: Inexpensive and abundant sodium resources make energy storage systems using sodium chemistry promising replacements for lithium-ion batteries. Aqueous sodium-ion rechargeable batteries are cheaper, safer, and more ionically conductive than batteries using conventional organic electrolytes, and are suitable for grid-scale energy storage applications. Metal-organic frameworks have shown great potential in storing Na+ ions in ASIBs with their porous 3D crystal structures, compatibility with aqueous solutions, long cycle lives, and ease of synthesis.

JOURNAL OF ENERGY CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Multifunctional MOF-Based Separator Materials for Advanced Lithium-Sulfur Batteries

Ning Yuan et al.

Summary: This review summarizes recent advances in the functionalization of lithium-sulfur battery (LSBs) separators based on metal-organic frameworks (MOFs), including original MOFs, MOF derivatives, and MOF composites. The mechanisms enhancing the electrochemical performance of each modified separator are explained, and the potential outlook of this field is provided.

ADVANCED MATERIALS INTERFACES (2021)

Article Multidisciplinary Sciences

Ionic liquid facilitated melting of the metal-organic framework ZIF-8

Vahid Nozari et al.

Summary: The method of incorporating ionic liquids to melt MOFs has been introduced to extend the range of hybrid glasses.

NATURE COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Aqueous Rechargeable Zn-ion Batteries: Strategies for Improving the Energy Storage Performance

Sourav Mallick et al.

Summary: The growing demand for efficient energy storage devices has led to the emergence of rechargeable aqueous zinc-based battery technologies as a compelling alternative to lithium-based batteries. However, challenges such as cathode dissolution and dendrite formation still need to be addressed in zinc-ion batteries.

CHEMSUSCHEM (2021)

Article Chemistry, Multidisciplinary

Insights into the Mechanochemical Synthesis of MOF-74

Jethro Beamish-Cook et al.

Summary: Mechanochemical synthesis of MOF-74 from ZnO and H(4)HDTA involves the formation of four short-lived intermediate phases before the final crystallization of highly crystalline MOF-74.

CRYSTAL GROWTH & DESIGN (2021)

Article Chemistry, Inorganic & Nuclear

Status report on copper (I) complexes in photoredox catalysis; photophysical and electrochemical properties and future prospects

Christian Sandoval-Pauker et al.

Summary: Visible-light photoredox catalysis has become a practical tool in recent years for driving energy-demanding chemical reactions. Despite the drawbacks of classical octahedral ruthenium and iridium complexes, such as sustainability and costs, they still dominate the field of photoredox catalysis due to their exceptional photoelectrochemical properties. Luminescent Cu (I) complexes are considered promising candidates to replace traditional Ru- and Ir photoredox catalysts in the near future. This review covers the development of Cu(I) complexes for photoredox catalysis, focusing on their characteristics, advantages, drawbacks, applications, and strategies for controlling their properties. Incorporating carbon-donor ligands has shown to be a promising approach for enhancing the stability and properties of photoredox catalysts.

POLYHEDRON (2021)

Article Chemistry, Multidisciplinary

Engineering Mesopores and Unsaturated Coordination in Metal-Organic Frameworks for Enhanced Oxygen Reduction and Oxygen Evolution Activity and Li-Air Battery Capacity

Hao Wang et al.

Summary: Metal-organic frameworks (MOFs) have rapidly expanded research in unpyrolyzed oxygen electrocatalysts due to their flexible compositions and structures. Introducing mesopores through partial ligand removal enhances mass- and charge-transfer properties for more efficient oxygen reduction and oxygen evolution reactions.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Review Chemistry, Multidisciplinary

An Overview on Anodes for Magnesium Batteries: Challenges towards a Promising Storage Solution for Renewables

Federico Bella et al.

Summary: Magnesium-based batteries have gained attention due to their high theoretical volumetric capacity, abundance, and dendrite-free behavior. However, the formation of insulating passivation layers with Mg deposition and dissolution in polar organic electrolytes presents a challenge that requires specific strategies to overcome.

NANOMATERIALS (2021)

Review Chemistry, Multidisciplinary

Metal-Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal-Sulfur Batteries

Rui Yan et al.

Summary: Metal-sulfur batteries are considered promising future energy storage systems due to their high theoretical energy density, but their practical applications are hindered by challenges such as shuttle effects and low conductivity of sulfur species. Recently, metal-organic frameworks-derived nanostructures have emerged as efficient multifaceted electrodes in MSBs, showing high surface area and molecular/atomic-level reactive sites. This review discusses the advancements in designing MOF-derived electrodes and their impact on electrochemical properties, providing guidance for the future development of fast-kinetic and robust MSBs in broad energy fields.

ADVANCED MATERIALS (2021)

Review Chemistry, Multidisciplinary

Metal-Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications

Guorui Cai et al.

Summary: Metal-organic frameworks (MOFs) are fascinating materials with high porosity and tailored structures, but their narrow pores limit applications. The development of hierarchically porous MOFs and derivatives has attracted attention to broaden the scope of traditional MOF-based materials.

CHEMICAL REVIEWS (2021)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks-Derived Self-Supported Carbon-Based Composites for Electrocatalytic Water Splitting

Yikang Cong et al.

Summary: Electrocatalytic water splitting is a promising strategy for sustainable hydrogen energy development, and self-supported metal-organic frameworks (MOFs) can be suitable templates/precursors to construct free-standing carbon-based composites with well-aligned array architecture and evenly distributed active sites, serving as alternative options to non-noble metal-included electrocatalysts.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Review Chemistry, Inorganic & Nuclear

Design principles and direct applications of cobalt-based metal-organic frameworks for electrochemical energy storage

Sha Li et al.

Summary: This review comprehensively summarizes the recent research progress and applications of cobalt-based metal-organic frameworks in electrochemical energy storage, including synthetic engineering strategies, improvement of electrochemical performance, charge storage mechanisms, applications in various energy storage devices, and future challenges and prospects.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Green & Sustainable Science & Technology

Advanced/hybrid thermal energy storage technology: material, cycle, system and perspective

Zhixiong Ding et al.

Summary: Thermal energy storage (TES) technology is crucial in addressing energy crisis and environmental issues. Various TES technologies have been intensively studied, with a focus on advanced/hybrid TES technologies that show great potential. These technologies aim to overcome the limitations of basic TES and improve energy storage efficiency.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2021)

Article Green & Sustainable Science & Technology

Metal-Organic Frameworks and Their Derived Functional Materials for Supercapacitor Electrode Application

Di Tian et al.

Summary: This review focuses on recent advances in the use of MOFs and their derived functional materials as electrode materials in supercapacitors, including pristine MOFs, MOF composites, and MOF-derived functional materials. The synthetic routes and modification strategies are summarized, and the relationship between the diversity of the architectures and compositions of MOF-based materials and their electrochemical performance is discussed. The challenges and opportunities for future research and extensive applications of MOFs and their derived functional materials are also addressed.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

Review Chemistry, Multidisciplinary

Conducting polymers: a comprehensive review on recent advances in synthesis, properties and applications

K. Namsheer et al.

Summary: Conducting polymers are extensively studied for their outstanding properties and limitations in their pristine form can be overcome through hybridization with other materials. The synergetic effects of conducting polymer composites find wide applications in electrical, electronics, and optoelectronic fields. Understanding the transport models and physical properties of these composites is crucial for their various applications in fields like energy storage, photocatalysis, and biomedical applications.

RSC ADVANCES (2021)

Review Chemistry, Multidisciplinary

Synthesis and application of core-shell liquid metal particles: a perspective of surface engineering

Yong Liu et al.

Summary: Liquid metal micro/nano particles (LMPs) from gallium and its alloys have attracted attention due to their unique metallic and fluidic properties, but achieving highly controllable fabrication and functionalization remains a challenge. This review explores solutions for on-demand design and manipulation of LMPs through physicochemical engineering of their surface microenvironment, showcasing improved performances of core-shell liquid metal composites in various scenarios.

MATERIALS HORIZONS (2021)

Review Food Science & Technology

Multifunctional nanocellulose/metal and metal oxide nanoparticle hybrid nanomaterials

Ahmed A. Oun et al.

CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION (2020)

Review Energy & Fuels

A review of energy storage types, applications and recent developments

S. Koohi-Fayegh et al.

JOURNAL OF ENERGY STORAGE (2020)

Article Chemistry, Multidisciplinary

Uniform Bi-Sb Alloy Nanoparticles Synthesized from MOFs by Laser Metallurgy for Sodium-Ion Batteries

Wei Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Review Chemistry, Inorganic & Nuclear

Applications of metal-organic framework-derived materials in fuel cells and metal-air batteries

Xudong Wen et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Article Chemistry, Physical

Metal-Organic Framework Integrated Anodes for Aqueous Zinc-Ion Batteries

Recep Yuksel et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Multidisciplinary

Strategies to Enhance Carbon Dioxide Capture in Metal-Organic Frameworks

Calogero Giancarlo Piscopo et al.

CHEMPLUSCHEM (2020)

Review Chemistry, Inorganic & Nuclear

Green synthesis of metal-organic frameworks: A state-of-the-art review of potential environmental and medical applications

Sandeep Kumar et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Review Chemistry, Inorganic & Nuclear

Progress of nanostructured metal oxides derived from metal-organic frameworks as anode materials for lithium-ion batteries

R. Chenna Krishna Reddy et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Review Chemistry, Inorganic & Nuclear

Recent progress in metal-organic framework-based supercapacitor electrode materials

Ben Xu et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Article Chemistry, Physical

Optimization of Washing Processes in Solvothermal Synthesis of Nickel-Based MOF-74

Khaliesah Kamal et al.

MATERIALS (2020)

Review Chemistry, Multidisciplinary

Electrochemical Biosensors Based on Conducting Polymers: A Review

Boris Lakard

APPLIED SCIENCES-BASEL (2020)

Review Electrochemistry

MOFs and COFs for Batteries and Supercapacitors

Xing Gao et al.

ELECTROCHEMICAL ENERGY REVIEWS (2020)

Review Chemistry, Inorganic & Nuclear

A review on the field patents and recent developments over the application of metal organic frameworks (MOFs) in supercapacitors

Farshad Boorboor Ajdari et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Review Chemistry, Physical

Recent progress on MOF-derived carbon materials for energy storage

Jincan Ren et al.

CARBON ENERGY (2020)

Article Chemistry, Multidisciplinary

Conversion of a microwave synthesized alkali-metal MOF to a carbonaceous anode for Li-ion batteries

Aamod V. Desai et al.

RSC ADVANCES (2020)

Review Chemistry, Multidisciplinary

Metal-organic frameworks as a platform for clean energy applications

Xinran Li et al.

ENERGYCHEM (2020)

Review Materials Science, Multidisciplinary

Machine learning: Accelerating materials development for energy storage and conversion

An Chen et al.

INFOMAT (2020)

Review Chemistry, Inorganic & Nuclear

Recent progress on metal-organic framework-derived materials for sodium-ion battery anodes

Taiqiang Chen et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

Article Chemistry, Inorganic & Nuclear

Microwave-Assisted Rapid Synthesis of Well-Shaped MOF-74 (Ni) for CO2 Efficient Capture

Changwei Chen et al.

INORGANIC CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Synergistic Effect of Co-Ni Hybrid Phosphide Nanocages for Ultrahigh Capacity Fast Energy Storage

Zibin Liang et al.

ADVANCED SCIENCE (2019)

Article Nanoscience & Nanotechnology

Control of SEI Formation for Stable Potassium-Ion Battery Anodes by Bi-MOF-Derived Nanocomposites

Sailan Su et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Chemistry, Multidisciplinary

Synthesis of CuS@CoS2 Double-Shelled Nanoboxes with Enhanced Sodium Storage Properties

Yongjin Fang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Redox Additive Electrolyte Study of Mn-MOF Electrode for Supercapacitor Applications

Shashank Sundriyal et al.

CHEMISTRYSELECT (2019)

Article Multidisciplinary Sciences

Metal-organic frameworks with photocatalytic bactericidal activity for integrated air cleaning

Ping Li et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Ordered Macro-Microporous Metal-Organic Framework Single Crystals and Their Derivatives for Rechargeable Aluminum-Ion Batteries

Hu Hong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Metal-Organic Framework-Derived Co3O4@MWCNTs Polyhedron as Cathode Material for a High-Performance Aluminum-Ion Battery

Xiang Xiao et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Review Nanoscience & Nanotechnology

Kinetic stability of metal-organic frameworks for corrosive and coordinating gas capture

Adam J. Rieth et al.

NATURE REVIEWS MATERIALS (2019)

Article Chemistry, Physical

MOF assistance synthesis of nanoporous double-shelled CuCo2O4 hollow spheres for hybrid supercapacitors

Fereshteh Saleki et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

Article Chemistry, Multidisciplinary

Three-Dimensional Phthalocyanine Metal-Catecholates for High Electrochemical Carbon Dioxide Reduction

Roc Matheu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries

Kwan Woo Nam et al.

NATURE COMMUNICATIONS (2019)

Review Energy & Fuels

A review of performance optimization of MOF-derived metal oxide as electrode materials for supercapacitors

Shaorui Wu et al.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2019)

Article Chemistry, Inorganic & Nuclear

Mechanochemical synthesis of metal-organic frameworks

Dong Chen et al.

POLYHEDRON (2019)

Article Energy & Fuels

Metal-organic frameworks for energy storage devices: Batteries and supercapacitors

Tahira Mehtab et al.

JOURNAL OF ENERGY STORAGE (2019)

Review Electrochemistry

Metal-Organic Frameworks (MOFs) and MOF-Derived Materials for Energy Storage and Conversion

Xu Zhang et al.

ELECTROCHEMICAL ENERGY REVIEWS (2019)

Article Chemistry, Multidisciplinary

Mechanical properties of metal-organic frameworks

Louis R. Redfern et al.

CHEMICAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Optimized synthesis of Zr(iv) metal organic frameworks (MOFs-808) for efficient hydrogen storage

Jiong Xu et al.

NEW JOURNAL OF CHEMISTRY (2019)

Review Chemistry, Multidisciplinary

Metal-Organic Framework-Derived Materials for Sodium Energy Storage

Guoqiang Zou et al.

Article Engineering, Environmental

Metal-organic framework-derived hollow CoS nanobox for high performance electrochemical energy storage

Xijun Wei et al.

CHEMICAL ENGINEERING JOURNAL (2018)

Review Chemistry, Physical

Metal-organic framework derived hollow materials for electrochemical energy storage

Xing-Chen Xie et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Physical

MOF-74 derived porous hybrid metal oxide hollow nanowires for high-performance electrochemical energy storage

Cuiping Yu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Physical

Record High Hydrogen Storage Capacity in the Metal-Organic Framework Ni-2(m-dobdc) at Near-Ambient Temperatures

Matthew T. Kapelewski et al.

CHEMISTRY OF MATERIALS (2018)

Review Chemistry, Multidisciplinary

From Lithium-Ion to Sodium-Ion Batteries: Advantages, Challenges, and Surprises

Prasant Kumar Nayak et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Physical

Carbon Anode Materials for Advanced Sodium-Ion Batteries

Hongshuai Hou et al.

ADVANCED ENERGY MATERIALS (2017)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks for Energy Applications

Hailong Wang et al.

Article Nanoscience & Nanotechnology

Palladium Nanoparticles Supported on Ce-Metal-Organic Framework for Efficient CO Oxidation and Low-Temperature CO2 Capture

Andrew Lin et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Chemistry, Multidisciplinary

Diamondoid-structured polymolybdate-based metal-organic frameworks as high-capacity anodes for lithium-ion batteries

Yuan-Yuan Wang et al.

CHEMICAL COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

High Methane Storage Working Capacity in Metal-Organic Frameworks with Acrylate Links

Juncong Jiang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Review Chemistry, Multidisciplinary

Metal-organic frameworks: structure, properties, methods of synthesis and characterization

V. V. Butova et al.

RUSSIAN CHEMICAL REVIEWS (2016)

Review Chemistry, Physical

Metal organic frameworks for energy storage and conversion

Yang Zhao et al.

ENERGY STORAGE MATERIALS (2016)

Article Chemistry, Multidisciplinary

Preparation of multi-walled carbon nanotube incorporated MIL-53-Cu composite metal-organic framework with enhanced methane sorption

Mansoor Anbia et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Highly porous and robust scandium-based metal-organic frameworks for hydrogen storage

Ilich A. Ibarra et al.

CHEMICAL COMMUNICATIONS (2011)

Article Chemistry, Multidisciplinary

Hydrogen storage in water-stable metal-organic frameworks incorporating 1,3-and 1,4-benzenedipyrazolate

Hye Jin Choi et al.

ENERGY & ENVIRONMENTAL SCIENCE (2010)