4.7 Article

The influence of alkyl ammonium modifiers on the microstructure and high-pressure rheology of sepiolite-vegetable oil dispersions

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APPLIED CLAY SCIENCE
卷 247, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.clay.2023.107210

关键词

Sepiolite; Alkyl -ammonium; Vegetable oil; Drilling fluid; High-pressure rheology

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The drilling industry is facing new challenges to develop eco-friendlier drilling fluids. Organic modified sepiolite dispersed in oil can be an excellent additive with suitable rheological properties. This study investigated the effect of alkyl ammonium modifiers on the microstructure and rheological properties of sepiolite-vegetable oil dispersions under high-temperature and high-pressure conditions.
In the context of environmental sustainability, the drilling industry faces new challenges resulting in the study and development of new drilling fluids based on eco-friendlier components to replace harmful mineral oils. Organic modified sepiolite dispersed in oil is an excellent additive to provide suitable rheological properties at low concentrations. The present study investigates the effect of alkyl ammonium modifiers on the microstructure and rheological properties of sepiolite-vegetable oil dispersions under high-temperature (up to 140 degrees C) and highpressure (up to 2000 bar) conditions. Organo-sepiolite, prepared using a high-shear processing method and containing surfactant with alkyl chains longer than 12 carbon atoms, exhibited a high degree of surface adsorption and thermal resistance. All modifiers developed a stable fibrous structure in the dispersion. This structure maintained the pseudoplastic behavior in a wide range of shear rate, temperature and pressure without reaching an apparent yield stress. These dispersions showed suitable rheological and thermal properties to develop sustainable drilling fluids.

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