期刊
CHEMCATCHEM
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202301344
关键词
allenes; Co-porphines; dienes; MHAT; photochemical
The metal-hydride hydrogen atom transfer (MHAT) method is a powerful technique for functionalizing alkenes. However, its application in industrial feedstock dienes and allenes is limited due to chemo-selectivity challenges. Recent studies have found that Co-porphines are highly efficient catalysts under photoirradiation, showing exceptional chemoselectivity for the functionalization of dienes and allenes.
The metal-hydride hydrogen atom transfer (MHAT) method is widely recognized as a powerful technique for functionalizing alkenes. However, its application in the functionalization of industrial feedstock dienes and allenes is relatively rare due to challenges related to chemo-selectivity. In recent studies, Co-porphines have been identified as highly efficient catalysts under photoirradiation for MHAT, demonstrating an exceptional level of chemoselectivity for the functionalization of dienes and allenes, while disregarding other simple olefins present. This novel method enables the selective reductive coupling of pyridines with dienes and the allylation of aldehydes by the combination with Ti catalysis. Mechanistic studies and density functional theory (DFT) calculations support the idea that the non-reversible transfer of hydrogen atoms from cobalt hydride to dienes and allenes, leading to the generation of allyl radicals, is the key step in the catalytic cycle. Co-porphines have been recognized as exceptionally efficient catalysts for the photoirradiation-induced chemoselective functionalization of dienes and allenes while disregarding other simple olefins present.+image
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