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Mechanochemical Pd-Catalyzed Amino- and Oxycarbonylations using FeBr2(CO)4 as a CO Source

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卷 25, 期 48, 页码 8617-8621

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AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c03440

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Here, we present the development of mechanochemical amino- and oxycarbonylation reactions using FeBr2(CO)(4) as a solid CO source. This Pd/XantPhos-catalyzed reaction enables the synthesis of a wide range of carboxamides and esters from aryl iodides and various amines or phenols. Notably, both primary and secondary amines, including amino acids, can be used as N-nucleophiles.
Herein, we describe the development of mechanochemical amino- and oxycarbonylation employing FeBr2(CO)(4) as a solid CO source. This Pd/XantPhos-catalyzed reaction affords a range of carboxamides and esters from aryl iodides and various amines or phenols. Both primary and secondary amines, including amino acids, can be employed as N-nucleophiles.

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