4.7 Article

Membrane fouling and influencing factors of a submerged commercial ceramic flat membrane bioreactor in treatment of coal chemical wastewater

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ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2023.111510

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Coal pyrolysis wastewater; Commercial ceramic flat-membrane bioreactor; Membrane fouling; Influencing factors

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This study investigated the mechanisms of membrane fouling in a commercial ceramic flat membrane bioreactor. It was found that the duration of backwash, charged particles, and suspended solids content are important factors influencing membrane fouling. Adjusting operating parameters and using appropriate cleaning methods can effectively reduce membrane fouling.
An anoxic/oxic (A/O) treatment unit was upgraded using a submerged commercial ceramic flat-membrane bioreactor. The upgraded bioreactor effectively treated coal chemical wastewater. However, the factors influencing membrane fouling remain unclear. Thus, this study explored the mechanisms of membrane fouling of a commercial ceramic flat membrane bioreactor. With increasing duration of backwash, the rate of growth of transmembrane pressure (TMP) gradually increased. The proportions of concentration polarization resistance R-p and cake layer resistance R-f were 48.87% and 50.08%, respectively. Under the action of static electricity, negatively charged particles in the mixed liquid do not easily adhere to the membrane. Under conditions of high mixed liquid suspended solids (> 12 000 mg/L), an increase in the suspended solid content in the mixture caused membrane fouling and pore blockage. When the flux exceeded 58 Lm(-2)h(-1), the TMP increased sharply. When the aeration rate exceeded 200 mL/min, the impact of membrane erosion on fouling was no longer significant. The optimal suction/cessation ratio was 7:3. After cleaning with NaOH and NaClO, surface fouling of the membrane was significantly reduced.

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