期刊
THIN-WALLED STRUCTURES
卷 195, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.tws.2023.111369
关键词
Polymeric interlayer; Laminated glass; Thermal rheological behavior; Relaxation characteristic; Glass transition
Polymeric interlayers are crucial for the structural capability of laminated glass members. The mechanical properties of polymers are influenced by temperature and time. Novel interlayers exhibit complex thermal rheological behavior, while conventional materials are relatively simple. Mathematical models can be used to describe the relaxation modulus of polymers.
Polymeric interlayers are of significance for the structural capability of thin-walled laminated glass members both before and after glass fracture. Polymers present evident temperature and time dependence, which should be carefully assessed in the design process. To improve mechanical properties dependent on the temperature and time, novel interlayers including modified ethylene-vinyl acetate (PVE (R)) and composite PVE/PC (SGE (R)), have been developed along with the sound resistance of the interfacial adhesion to aging. In this work, dynamic mechanical thermal analysis tests were carried out to investigate the thermal rheological behavior and relaxation characteristic of polyvinyl butyral (PVB), ionomer (SentryGlas (R), SG), PVE, PC and SGE. The results show that PVE and SGE follow the complex thermal rheological behavior as a result of the existence of two different types of relaxation transitions, whilst PVB, SG, and PC are thermorheologically simple materials. The arctangent function was introduced to describe the temperature dependence of PVB and SG. The relaxation modulus of polymers was subsequently derived based on the approximation equation and inverse Fourier transform. The results of the inverse Fourier transform indicate that vertical shift might need to be considered for PVE and SGE. The application of the approximation equation was assessed and its limitation was discussed. Finally, the relaxation characteristics of five polymers were described using the generalized Maxwell model based on the weighted least squares method.
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