期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202300548
关键词
indan; tetralin; benzyl palladium; cyclization; difunctionalization
A Pd-catalyzed cyclization/1,4-difunctionalization of bromoarenes bearing a carbon nucleophile with diazo compounds was developed. This reaction proceeds through a pi-benzyl palladium intermediate, which is crucial for the remarkable 1,4-selectivity and provides functionalized indans and tetralins.
A Pd-catalyzed cyclization/1,4-difunctionalization of bromoarenes bearing a carbon nucleophile with diazo compounds has been developed. The present reaction proceeds through a pi-benzyl palladium intermediate, whose reactivity is a key for the remarkable 1,4-selectivity of this reaction, providing functionalized indans and tetralins. A Pd-catalyzed cyclization/1,4-difunctionalization of bromoarenes bearing a carbon nucleophile with diazo compounds was developed. The present reaction proceeds through a pi-benzyl palladium intermediate, whose reactivity is key for the remarkable 1,4-selectivity of this reaction, and provides functionalized indans and tetralins.+image
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