☆ 4.8 Article

Solvation Sheath Engineering by Multivalent Cations Enabling Multifunctional SEI for Fast-Charging Lithium-Metal Batteries

ACS APPLIED MATERIALS & INTERFACES (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Physical

Memory Effect of MgAl Layered Double Hydroxides Promotes LiNO3 Dissolution for Stable Lithium Metal Anode

Fenglin Wang et al.

Summary: A novel electrolyte additive of MgAl layered double hydroxides (LDHs) is proposed to improve the solubility of LiNO3 and enhance the performance of Li metal anodes. MgAl LDHs promote the coordination of NO3- ions and absorb anions, leading to more dissociated Li+ ions and improved Li+ migration in carbonate electrolytes. The cells assembled with MgAl LDHs and LiNO3 additives demonstrate high Coulombic efficiency, excellent rate capability, and high capacity retention. This study provides new insights into LiNO3 promoter design and explores the potential of LDHs materials for Li metal batteries.

ADVANCED ENERGY MATERIALS (2023)

添加到收藏夹

Review Chemistry, Applied

Lithium nitrate regulated carbonate electrolytes for practical Li-metal batteries: Mechanisms, principles and strategies

Kun Wang et al.

Summary: Li-metal batteries (LMBs) are attracting research attention again due to their high-energy requirements. Commercial carbonate electrolytes have unfavorable reactions with the Li-metal anode, leading to the formation of unstable solid electrolyte interphase (SEI) and Li dendrites. However, the incorporation of lithium nitrate (LiNO3) into commercial carbonate electrolytes can successfully stabilize the SEI and enable dendrite-free Li-metal anode, making LMBs practical.

JOURNAL OF ENERGY CHEMISTRY (2023)

添加到收藏夹

Article Engineering, Environmental

Crystallographic oriented plating by using lithiophilic ionic additives in carbonate electrolyte for enabling high voltage lithium metal batteries

Qiwen Ran et al.

Summary: In this work, lithiophilic active ionic additives are used to generate a multi-layer solid electrolyte interphase (SEI) and promote preferential Li plating. The modified carbonate electrolyte ensures an ultra-high average CE (99.3%) and a high-capacity retention (94.2%) in Li metal batteries.

CHEMICAL ENGINEERING JOURNAL (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reversible, Dendrite-Free, High-Capacity Aluminum Metal Anode Enabled by Aluminophilic Interface Layer

Yahan Meng et al.

Summary: We propose a strategy for constructing an ultrathin aluminophilic interface layer (AIL) to enable highly reversible and dendrite-free Al plating/stripping in rechargeable batteries. The Pt-AIL@Ti electrode demonstrates stable plating/stripping of Al at a high areal capacity and exhibits an average Coulombic efficiency of 99.9%. This work provides valuable insights for the development of high-performance rechargeable Al metal batteries.

NANO LETTERS (2023)

添加到收藏夹

Article Multidisciplinary Sciences

A monofluoride ether-based electrolyte solution for fast-charging and low-temperature non-aqueous lithium metal batteries

Guangzhao Zhang et al.

Summary: The authors report a monofluoride ether-based electrolyte solution that stabilizes high-voltage lithium metal batteries at high current rates and low temperatures. The electrolyte solution exhibits good compatibility with positive and negative electrodes, high ionic conductivity, and oxidation stability, enabling high capacity retention.

NATURE COMMUNICATIONS (2023)

添加到收藏夹

Article Chemistry, Applied

In-situ construction of high-mechanical-strength and fast-ion-conductivity interphase for anode-free Li battery

Yangfan Lin et al.

Summary: The in-situ construction of high-quality solid electrolyte interphase (SEI) using synergistic additives of LiNO3 and ethylene sulfite (ES) results in improved mechanical strength and ion conductivity, effectively suppressing Li-dendrite growth and side reactions and achieving high Coulombic efficiency (CE) and capacity retention.

JOURNAL OF ENERGY CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Physical

Highly Soluble Lithium Nitrate-Containing Additive for Carbonate-Based Electrolyte in Lithium Metal Batteries

Venkata A. K. Adiraju et al.

Summary: While the poor solubility of lithium nitrate (LiNO3) limits its use in conventional carbonate-based electrolytes, a new LiNO3-containing electrolyte additive called 1-trimethylsilyl imidazole lithium nitrate adduct (TMSILN) has been synthesized to improve its solubility. The presence of TMSILN in the electrolyte significantly enhances the electrochemical performance of Li/Li and NCM622/Li cells, resulting in a circular morphology of deposited lithium metal with a thin surface film containing lithium nitrate decomposition products. This improvement is attributed to the favorable features of the SEI and morphology of the deposited lithium with TMSILN additive.

ACS ENERGY LETTERS (2023)

添加到收藏夹

Article Energy & Fuels

Growing single-crystalline seeds on lithiophobic substrates to enable fast-charging lithium-metal batteries

Zhaohui Wu et al.

Summary: Controlling the nucleation and growth is essential for enabling long-life Li-metal batteries. Here, the authors report the growth of faceted single-crystalline Li seeds on a lithiophobic Fe/LiF composite substrate that enables dense Li deposition under fast-charging conditions. A cell using a 3 mAh cm(-2) LiNi0.8Co0.1Mn0.1O2 (LiNMC811) cathode, onefold excess of lithium and 3 g Ah(-1) electrolyte cycles at a 1 C rate for more than 130 cycles with 80% capacity retention, a 550% improvement over the baseline cells. These findings advance the understanding of lithium nucleation and pave the way for realizing high-energy, fast-charging Li-metal batteries.

NATURE ENERGY (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Non-Flammable Electrolyte with Lithium Nitrate as the Only Lithium Salt for Boosting Ultra-Stable Cycling and Fire-Safety Lithium Metal Batteries

Can Liao et al.

Summary: In this study, a low-cost, thermally stable, and low environmentally-sensitive lithium nitrate (LiNO3) is proposed as the only lithium salt to incorporate with nonflammable triethyl phosphate and fluoroethylene carbonate (FEC) co-solvent as the electrolyte to enhance the performance and safety of lithium metal batteries.

ADVANCED FUNCTIONAL MATERIALS (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Entropy-Driven Liquid Electrolytes for Lithium Batteries

Qidi Wang et al.

Summary: Developing liquid electrolytes with higher kinetics and enhanced interphase stability is crucial for improving lithium battery performance. This study demonstrates that introducing multiple salts to form a high-entropy solution can improve solubility and stabilize electrode-electrolyte interphases. The high-entropy electrolytes significantly enhance cycling and rate performance, extending the cycle life of lithium batteries and achieving more than 1000 charge-discharge cycles for commercial batteries. These improvements are attributed to the unique features of the solvation structure in high-entropy electrolytes, which result in improved lithium-ion kinetics and stabilized interphases.

ADVANCED MATERIALS (2023)

添加到收藏夹

Article Chemistry, Applied

Enhancing Li cycling coulombic efficiency while mitigating shuttle effect of Li-S battery through sustained release of LiNO3

Qi Jin et al.

Summary: Researchers have developed a novel strategy to construct high-quality and durable solid electrolyte interphase (SEI) in lithium-sulfur batteries (LSBs), which effectively mitigates the shuttle effect and improves the cycling efficiency of lithium. The F-and N-rich SEI modulates lithium deposition behavior and allows for persistent repair during prolonged cycling, enhancing the overall performance of LSBs.

JOURNAL OF ENERGY CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Applied

Synthesizing an inorganic-rich solid electrolyte interphase by tailoring solvent chemistry in carbonate electrolyte for enabling high-voltage lithium metal batteries

Qiwen Ran et al.

Summary: High-voltage (>4.0 V) lithium metal battery (LBM) is considered as one of the most promising candidates for next-generation high-energy batteries. However, the commercial carbonate electrolyte shows poor compatibility with Li metal anode and its organic dominated solid electrolyte interphase (SEI) has low interfacial energy and slow Li+ diffusion ability. In this study, an inorganic-organic hybrid SEI electrolyte is designed to enable high-voltage LBM.

JOURNAL OF ENERGY CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Physical

Achieving stable interphases toward lithium metal batteries by a dilute and anion-rich electrolyte

Dandan Chai et al.

Summary: A novel cluster-like and anion-rich dilute electrolyte system was constructed using LiNO3 and trace LiOTf, which enables high ion conductivity and ensures the stability and cycling performance of LMBs.

ENERGY STORAGE MATERIALS (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Constructing a Stable Interface Layer by Tailoring Solvation Chemistry in Carbonate Electrolytes for High-Performance Lithium-Metal Batteries

Zhihong Piao et al.

Summary: By adding lithium nitrate additive and a small amount of tetramethylurea as a multifunctional cosolvent to a commercial carbonate electrolyte, it is possible to improve the performance and cycle life of lithium-metal batteries, providing a simple and effective way to extend the use of commercial carbonate electrolytes for next-generation battery systems.

ADVANCED MATERIALS (2022)

添加到收藏夹

Article Engineering, Environmental

Solvation chemistry of rare earth nitrates in carbonate electrolyte for advanced lithium metal batteries

Pengcheng Li et al.

Summary: In this study, rare earth metal salts were used as electrolyte additives to optimize the solvation structure of lithium ions and improve the performance of lithium metal anode. The resulting interphase from electrochemical reactions facilitated stable and efficient Li deposition, leading to enhanced safety and cycling stability of lithium metal batteries. This strategy provides a promising approach for the design and optimization of electrolytes for next-generation high-capacity lithium batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

添加到收藏夹

Article Multidisciplinary Sciences

A dual-function liquid electrolyte additive for high-energy non-aqueous lithium metal batteries

Yuji Zhang et al.

Summary: Engineering the formulation of non-aqueous liquid electrolytes is a viable strategy to produce high-energy lithium metal batteries. By adding specific additives, a stable interphase can be formed on both the lithium metal anode and the layered cathode, improving the performance and cycle life of the battery.

NATURE COMMUNICATIONS (2022)

添加到收藏夹

Article Chemistry, Physical

Stabilizing the interphase between Li and Argyrodite electrolyte through synergistic phosphating process for all-solid-state lithium batteries

Han Su et al.

Summary: Among solid electrolytes, sulfides are considered promising candidates due to their softness and high ionic conductivity. However, the interface problem between Li metal and sulfide electrolytes has been a concern. This work presents a two-step phosphating process to create a hybrid interphase with high ionic conductivity and low electronic conductivity, providing excellent stability for lithium metal in all-solid-state lithium batteries.

NANO ENERGY (2022)

添加到收藏夹

Article Chemistry, Physical

In-situ formation of a nanoscale lithium aluminum alloy in lithium metal for high-load battery anode

Shuanghui Han et al.

Summary: A unique lithium thermal reduction method is used to produce lithium-rich alloys, which can effectively solve the problems of inhomogeneous lithium deposition and side reactions, improving the battery efficiency and cycle life.

ENERGY STORAGE MATERIALS (2022)

添加到收藏夹

Article Chemistry, Physical

Constructing a lithiophilic and mixed conductive interphase layer in electrolyte with dual-anion solvation sheath for stable lithium metal anode

Bing Zhong et al.

Summary: This study introduces a stable mixed conductive interphase (MCI) layer on the surface of lithium metal through in-situ surface reaction, effectively inhibiting the growth of lithium metal dendrites and improving the interfacial kinetics. The electrochemical performance of lithium metal batteries is greatly enhanced, with a long lifespan and high capacity retention. This strategy provides a new approach to address dendrite issues and promotes the application of lithium metal batteries.

ENERGY STORAGE MATERIALS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

An Inorganic-Rich Solid Electrolyte Interphase for Advanced Lithium-Metal Batteries in Carbonate Electrolytes

Sufu Liu et al.

Summary: In this study, an inorganic-rich solid electrolyte interphase (SEI) was designed on the Li-metal surface in carbonate electrolytes to reduce the bonding energy with Li metal, enabling high Li plating/stripping efficiency and cycling performance. The weak bonding of the SEI to Li promotes Li diffusion and prevents Li dendrite penetration, resulting in a high Coulombic efficiency during cycling.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Energy & Fuels

Pressure-tailored lithium deposition and dissolution in lithium metal batteries

Chengcheng Fang et al.

Summary: This study presents a high-density Li deposition technique achieved by controlling uniaxial stack pressure to improve the performance of lithium metal batteries, along with proposing a Li morphology testing protocol to maintain the ideal Li deposition morphology. The critical role of stack pressure on Li nucleation, growth, and dissolution processes is elucidated, highlighting the importance of precise control of Li deposition and dissolution.

NATURE ENERGY (2021)

添加到收藏夹

Article Chemistry, Physical

Dissolution-Precipitation Dynamics in Ester Electrolyte for High-Stability Lithium Metal Batteries

Huicong Yang et al.

Summary: The research shows that using ethylene glycol diacetate in ester electrolyte can prevent the recombination of anions and cations, increasing the solubility of LiNO3 and achieving lithium metal batteries with high Coulombic efficiency and long cycling life. Low permittivity solvents can change the solvation structures of cations and increase the solubility of salts by preventing the recombination of anions and cations.

ACS ENERGY LETTERS (2021)

添加到收藏夹

Article Chemistry, Physical

In Situ Conversion of Cu3P Nanowires to Mixed Ion/Electron-Conducting Skeleton for Homogeneous Lithium Deposition

Changzhi Sun et al.

ADVANCED ENERGY MATERIALS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enabling High-Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte

Yulin Jie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

High Interfacial-Energy Interphase Promoting Safe Lithium Metal Batteries

Sufu Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Colossal Granular Lithium Deposits Enabled by the Grain-Coarsening Effect for High-Efficiency Lithium Metal Full Batteries

Weidong Zhang et al.

ADVANCED MATERIALS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Diffusion-Reaction Competition Mechanism to Tailor Lithium Deposition for Lithium-Metal Batteries

Xiao-Ru Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

In Situ Construction of a LiF-Enriched Interface for Stable All-Solid-State Batteries and its Origin Revealed by Cryo-TEM

Ouwei Sheng et al.

ADVANCED MATERIALS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regulating the Li+-Solvation Structure of Ester Electrolyte for High-Energy-Density Lithium Metal Batteries

Dengji Xiao et al.

SMALL (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

A review on energy chemistry of fast-charging anodes

Wenlong Cai et al.

CHEMICAL SOCIETY REVIEWS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Towards practical lithium-metal anodes

Xin Zhang et al.

CHEMICAL SOCIETY REVIEWS (2020)

添加到收藏夹

Article Nanoscience & Nanotechnology

Bridging the academic and industrial metrics for next-generation practical batteries

Yuliang Cao et al.

NATURE NANOTECHNOLOGY (2019)

添加到收藏夹

Review Chemistry, Physical

Commercialization of Lithium Battery Technologies for Electric Vehicles

Xiaoqiao Zeng et al.

ADVANCED ENERGY MATERIALS (2019)

添加到收藏夹

Article Chemistry, Physical

Enhanced Stability of Li Metal Anodes by Synergetic Control of Nucleation and the Solid Electrolyte Interphase

Zhe Peng et al.

ADVANCED ENERGY MATERIALS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Guiding Uniform Li Plating/Stripping through Lithium-Aluminum Alloying Medium for Long-Life Li Metal Batteries

Huan Ye et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Physical

Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries

Xue-Qiang Zhang et al.

ACS ENERGY LETTERS (2019)

添加到收藏夹

Article Chemistry, Physical

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries

Brian D. Adams et al.

ADVANCED ENERGY MATERIALS (2018)

添加到收藏夹

Article Nanoscience & Nanotechnology

Lithium Difluorophosphate as a Dendrite-Suppressing Additive for Lithium Metal Batteries

Pengcheng Shi et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

添加到收藏夹

Article Multidisciplinary Sciences

Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode

Yayuan Liu et al.

NATURE COMMUNICATIONS (2018)

添加到收藏夹

Article Nanoscience & Nanotechnology

Suppression of Dendritic Lithium Growth by in Situ Formation of a Chemically Stable and Mechanically Strong Solid Electrolyte lnterphase

Guojia Wan et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

添加到收藏夹

Review Nanoscience & Nanotechnology

Reviving the lithium metal anode for high-energy batteries

Dingchang Lin et al.

NATURE NANOTECHNOLOGY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport

Snehashis Choudhury et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Lithium metal anodes for rechargeable batteries

Wu Xu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Li+ ion conductivity and diffusion mechanism in alpha-Li3N and beta-Li3N

Wen Li et al.

ENERGY & ENVIRONMENTAL SCIENCE (2010)

添加到收藏夹

Article Crystallography

First principles methods using CASTEP

SJ Clark et al.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE (2005)

添加到收藏夹

Article Chemistry, Physical

Oxidation of iron deposited on polycrystalline aluminum surfaces

C Palacio et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2001)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.