Water absorption of biomass fillers to impact the degradation of poly(butyleneadipate-co-terephthalate) composites

In this work, two kinds of biomass fillers including reed and wheat straw with similar sizes at micrometer scale were used as filler and poly(butyleneadipate-co-terephthalate) (PBAT) as matrix to prepare high-performance composite materials and to use for the research of enzymatic degradation. Accordingly, hard PBAT composites with average bending strength and modulus at 12 and 1100 MPa were prepared. With the progress of enzymatic degradation, water absorption of the biomass fillers to promote the degradation of PBAT matrix was clearly revealed. The strong water absorption of biomass filler led to the large degradation rate. During the degradation within 90 days, the mechanical properties of PBAT/biomass fillers composites decreased to 23.7%. This study revealed the important factors of biomass fillers affecting the degradation behavior of PBAT in composite.Highlights center dot Two different biomass fillers are blended into PBAT to fabricate the composites.center dot All of the biomass fillers are similarly controlled at the micrometer level.center dot Water absorption of biomass filler promotes the degradation of the PBAT matrix.center dot Stronger water absorption induces quicker degradation rate.center dot After degradation, bending properties of PBAT composites obviously decrease.Highlights center dot Two different biomass fillers are blended into PBAT to fabricate the composites.center dot All of the biomass fillers are similarly controlled at the micrometer level.center dot Water absorption of biomass filler promotes the degradation of the PBAT matrix.center dot Stronger water absorption induces quicker degradation rate.center dot After degradation, bending properties of PBAT composites obviously decrease.Highlights center dot Two different biomass fillers are blended into PBAT to fabricate the composites.center dot All of the biomass fillers are similarly controlled at the micrometer level.center dot Water absorption of biomass filler promotes the degradation of the PBAT matrix.center dot Stronger water absorption induces quicker degradation rate.center dot After degradation, bending properties of PBAT composites obviously decrease.Highlights center dot Two different biomass fillers are blended into PBAT to fabricate the composites.center dot All of the biomass fillers are similarly controlled at the micrometer level.center dot Water absorption of biomass filler promotes the degradation of the PBAT matrix.center dot Stronger water absorption induces quicker degradation rate.center dot After degradation, bending properties of PBAT composites obviously decrease.Highlights center dot Two different biomass fillers are blended into PBAT to fabricate the composites.center dot All of the biomass fillers are similarly controlled at the micrometer level.center dot Water absorption of biomass filler promotes the degradation of the PBAT matrix.center dot Stronger water absorption induces quicker degradation rate.center dot After degradation, bending properties of PBAT composites obviously decrease. High water absorption of the biomass fillers extremely enhances the degradation of PBAT matrix in composite.image

Automated summary

In this study, high-performance composite materials were prepared using reed and wheat straw as biomass fillers and poly(butyleneadipate-co-terephthalate) as matrix, and their enzymatic degradation was researched. The water absorption of biomass fillers promoted the degradation of the PBAT matrix, leading to a decrease in the mechanical properties of the composites.