Persulfate activation over CoFe2O4/CuS for degradation of Orange II under visible light

A magnetic porous composite catalyst has been synthesized from CoFe2O4 and CuS. Its degradation performance towards organic pollutants in a heterogeneous photocatalytic system has been compared with those of the in-dividual photocatalysts and those of individual chemocatalysis systems. Orange II served as a target contaminant. Persulfate and catalyst were combined under visible light conditions to achieve degradation of the organic pollutant, whereupon the degradation efficiency reached up to 97 %. The catalyst has been characterized by X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) analysis, Mott-Schottky analysis, scanning electron microscopy (SEM), and solid-state UV/Vis spectrophotometry. The influences of pH and different catalyst and persulfate loadings in the system have been studied. The results of quenching experiments showed non-radical degradation to be a major pathway, with singlet molecular oxygen (1O2) and photogenerated holes (h+) as the critical reactive species. Besides, the magnetic properties of the catalyst are conducive to its recycling, and it still showed high degradation efficiency after three cycles.

Automated summary

A magnetic porous composite catalyst synthesized from CoFe2O4 and CuS showed high degradation efficiency for organic pollutants under visible light conditions, using non-radical degradation as the main pathway.