期刊
MATERIALS TODAY COMMUNICATIONS
卷 38, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.mtcomm.2023.107623
关键词
Ethylammonium; Rubidium; Perovskite; Solar cell; Guanidinium; Indoor light
The effects of adding rubidium (Rb) and ethylammonium (CH3CH2NH3, EA) to guanidinium [C(NH2)3, GA] based CH3NH3PbI3 perovskite solar cells were investigated. The lattice constants and (100)-orientation of EA and Rb-modified perovskite crystals increased compared to the as-prepared perovskite. The addition of GA and EA effectively improved the photovoltaic properties of the device under indoor light conditions.
Effects of the addition of rubidium (Rb) and ethylammonium (CH3CH2NH3, EA) to guanidinium [C(NH2)3, GA]based CH3NH3PbI3 perovskite solar cells were investigated. Lattice constants and the (100)-orientation of EAand Rb-modified perovskite crystals increased compared with those of as-prepared perovskite. Abnormal increases of lattice constants of the GA- and EA-modified perovskite crystals prepared at 190 degrees C for 10 min in ambient air were also observed during the room temperature aging, which was due to crystal growth of the perovskites, and these features contributed to increased conversion efficiencies of devices based on the modified perovskites. Addition of GA and EA also effectively improved the photovoltaic properties of the device under indoor light conditions using white light-emitting diodes. First-principles calculations of the density of states and band structures indicated a reduction of the total energy through the addition of Rb or EA, suggesting that the current density was improved by the reduced band gap.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据