Investigating temperature change rate and pore confinement effect on thermal properties of phase change materials for de-icing and low-temperature applications in cementitious composites

Incorporation techniques of phase change materials (PCM) in cementitious composites have a significant influence on thermal properties. This study investigated the thermal behavior of low-temperature PCM when subjected to varying temperature change rates and pore confinement inside the porous network of lightweight aggregates (LWA) and encapsulation using melamine-formaldehyde-based polymer. Three categories of thermal energy storage (TES) specimens were prepared: (i) Bulk PCM (i.e., liquid PCM), (ii) micro-encapsulated PCM (MPCM), and (iii) four different LWAs infused with PCM (PCM-LWA). The thermal properties of small-scale individual TES specimens were analyzed using a low-temperature differential scanning calorimeter (LT-DSC) to evaluate the effect of ramp rates. Dynamic vapor sorption (DVS) analysis was utilized to characterize the pore structure of LWAs. LT-DSC results show that undercooling of the PCM significantly increases with the rise in ramp rate for all the specimens; temperature change rate affects the nucleation and crystallization growth process during the phase transition. Pore structure characterization of LWAs indicates that the majority of the pores (> 92 %) were larger than 17.3 nm (i.e., macropores). Confined liquid properties are subjected to modification due to interaction with the confining surfaces, as explained by Gibbs-Thomson theory. PCM incorporated in the LWA porous network experienced variable degree of supercooling during phase transition; magnitude of confinement pressure is dependent on the pore diameter, structure, and tortuosity. Experimental evidence suggested that PCM-LWA will exhibit gradual expulsion of enthalpy of fusion over a larger temperature range (i.e., similar to-5 degrees C to 4.28 degrees C) in comparison to MPCM (i.e., similar to 4.28 degrees C).

Automated summary

Incorporation techniques of phase change materials in cementitious composites have a significant influence on thermal properties. This study investigated the thermal behavior of low-temperature PCM when subjected to varying temperature change rates and pore confinement inside the porous network of lightweight aggregates. The results showed that ramp rates affect the nucleation and crystallization growth process during the phase transition, and the pore structure of the aggregates affects the supercooling phenomenon and confinement pressure of the PCM.