期刊
POLYMER
卷 290, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2023.126520
关键词
Anion exchange membranes; Polybenzoxazine; Quaternary ammonium; Ion conductivity; Alkaline stability; Oxidative stability
Two kinds of benzoxazine monomers were synthesized and used to prepare polybenzoxazine anion exchange membranes (AEMs) with quaternary ammonium functionalization. The LQPBZ AEM exhibited better ion conductivity and alkaline stability.
Two kinds of benzoxazine monomers were synthesized by Mannich reaction with N,N-dimethyl-p-phenylenediamine and N,N-dimethylethylenediamine using polyformaldehyde, 4,4 '-dihydroxydiphenylmethane as raw materials. Subsequently, quaternary ammonium functionalization was realized by Menshutkin reaction. The aromatic amine-based quaternary ammonium-functionalized polybenzoxazine (AQPBZ) and aliphatic aminebased quaternary ammonium-functionalized polybenzoxazine (LQPBZ) were synthesized by ring-opening polymerization. Polybenzoxazine anion exchange membrane (AEM) was prepared by solution casting method. The AQPBZ and LQPBZ AEMs exhibit micro-phase separated morphology clearly. LQPBZ AEM displays more large ion clusters and ion conductive channels due to the flexible alkyl connection between QA group and polybenzoxazine skeleton. AQPBZ and LQPBZ AEMs have the ionic conductivity of 75.5 mS/cm and 86.3 mS/cm at 80 degrees C and 100% relative humidity, respectively. AQPBZ and LQPBZ AEMs show excellent alkaline stability. After treated with 6 M sodium hydroxide solution at 80 degrees C for 240 h, they manitained the 49.8 mS/cm and 50.2 mS/ cm, respectively. They also exhibit good oxidation stability and thermal stability. Their oxidation weight losses are 4.1% and 7.2% through Fenton test, respectively. Their Td5s are 325 degrees C and 289 degrees C, respectively.
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