期刊
APPLIED SURFACE SCIENCE
卷 647, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2023.158970
关键词
Bimetallic complexes; N-doping; Thermal decomposition; Ammonium perchlorate
The addition of Ni-Co-pzdc catalyst effectively improves the thermal decomposition properties of ammonium perchlorate (AP). Various characterization tools were used to investigate the morphological and structural features of the resulting materials. The thermal decomposition behaviors of the two products were studied, and the results showed excellent catalytic activities for both substances.
The addition of a catalyst to ammonium perchlorate (AP) can effectively improve its thermal decomposition properties. The heterobimetallic complex Ni-Co-pzdc (2,3-pyrazinedicarboxylic acid) was synthesized via in situ substitution, and the N-doped Ni-Co-pzdc derivative was prepared by using it as a sacrificial template. A series of characterization tools were used to investigate the morphological and structural features of the resulting materials, and the thermal decomposition behaviors of the two products were investigated by homogeneous mixing with AP, respectively, and the activation energies were calculated by using Kissinger, Kissinger-Akahira-Sunose (KAS), and Flynn-Wall-Ozawa (FWO), and the results showed that both substances possessed excellent catalytic activities.
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