相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。
Article
Chemistry, Multidisciplinary
Cheng-Bin Jin et al.
Summary: Lithium (Li)-metal batteries suffer severe capacity deterioration at extreme temperatures due to increased kinetic barrier of interfacial processes. This study quantitatively probes the interfacial kinetics in three different electrolytes and reveals that desolvation is the limiting step dominating the cell impedance and capacity at low temperature. The use of a 1,3-dioxolane-based electrolyte with tamed solvent-solute interaction facilitates fast desolvation and enables practical Li|LiNi0.5Co0.2Mn0.3O2 cells at -40 degrees C to retain 66% of room-temperature capacity and withstand fast charging rates. The barrier of desolvation dictated by solvent-solute interaction environments is quantitatively uncovered, and regulating this interaction emerges as a promising solution to low-temperature batteries.
ADVANCED MATERIALS
(2023)
Article
Electrochemistry
Lin Wang et al.
Summary: Polymer electrolytes are crucial for addressing the challenges of lithium metal batteries. A newly developed three-dimensional semi-interpenetrating network-based single-ion-conducting fiber-gel composite polymer electrolyte demonstrates high ionic conductivity, stability, and flame retardancy, facilitating the development of high-energy-density and safe lithium metal batteries.
Review
Chemistry, Multidisciplinary
Sebastian P. Kuehn et al.
Summary: The development of high-performing lithium-based batteries requires a thorough understanding of the reactivity at the electrode-liquid electrolyte interface and its impact on overall performance and safety. This review focuses on lithium-based cell chemistries and highlights the less understood electrolyte decomposition chemistry and the physicochemical and electrochemical properties of cathode electrolyte interphase (CEI) formation and evolution at the positive electrode material surface and sub-surfaces.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Liwei Dong et al.
Summary: In this study, a new electrolyte system based on fluoroalkyl ether THE and ether electrolytes has been designed to enhance the performance of lithium metal batteries, including long-cycle and high-rate capabilities. The electrolyte not only reduces Li+ interaction and solvation in ether electrolytes, but also enables solvation-free Li+ transfer with significantly improved transference at the electrolyte/anode interface. Additionally, the electrolyte suppresses dendrite formation and stabilizes the solid electrolyte interphase layer, leading to exceptional cyclic performances over 5000 cycles at 10 C.
Article
Chemistry, Physical
Shengdong Zhu et al.
Summary: The research utilizes a mix of DOL and TTE solvents to enhance the stability and electrochemical performance of the lithium metal anode, improving the electrochemical stability of the electrolyte, resulting in better lithium plating-stripping effect.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Liang Deng et al.
Summary: This study constructed a weakly-solvating architecture for the Na3V2(PO4)(2)F-3 cathode, accelerating the kinetics of charge-transfer reactions and improving the capacity retention and energy density of the battery at low temperatures.
ENERGY STORAGE MATERIALS
(2022)
Article
Multidisciplinary Sciences
Zhipeng Jiang et al.
Summary: Developing low cost, high-voltage electrolytes is important for improving the energy density and usability of lithium metal batteries (LMBs). Low concentration electrolytes have advantages in terms of cost and viscosity, but their compatibility with high-voltage LMBs is limited. In this study, a diluted low concentration electrolyte was developed by replacing a solvating cosolvent with a non-solvating cosolvent, which improved the interaction between BF4- and Li+ ions and optimized the interfacial chemistry. This electrolyte showed outstanding cycling stability and rate performance in high-loading Li-LiCoO2 full cells.
Article
Chemistry, Multidisciplinary
Zhicheng Wang et al.
Summary: This study successfully addresses the limitations of commercial carbonate electrolytes by fabricating a novel ultralow-concentration electrolyte with low cost, non-flammability, wide temperature operation window, and high electrochemical window. It also suppresses Li dendrite growth. The Li metal battery using this electrolyte shows outstanding performance under high voltage and wide temperature range.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Engineering, Environmental
Tingting Feng et al.
Summary: This study investigates the use of localized high-concentration electrolytes (LHCEs) to improve the low-temperature operation of high-voltage lithium-ion batteries. A new short-chain fluorinated diluent is used to prepare a stable LHCE, allowing the battery to operate with high current density at low temperatures.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Electrochemistry
Liu Hong et al.
Summary: Lithium metal batteries (LMBs) are a promising energy storage technology due to their high capacity and low potential. However, the growth of lithium dendrites limits their commercial application. In this study, a novel electrolyte was designed to inhibit dendrite growth at low temperatures while maintaining good performance at room temperature.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Applied
Jie Wang et al.
Summary: The study shows that the TMSB additive affects the Li+ solvation structure beneficial for the cycle performance of lithium-ion batteries by forming a thin and dense CEI film, which improves the transfer of Li+ ions and enhances the performance of the batteries.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Energy & Fuels
Shiyou Li et al.
Summary: This study compares the properties of interfacial films formed by electrolytes with different concentrations on the surface of LiFePO4 (LFP) cathode material. It finds that the fundamental cause for the undesirable electrochemical performances of the low-concentration electrolyte is the low content of LiF components in the interface film, rather than the low ionic conductivity of the electrolyte itself.
Article
Multidisciplinary Sciences
Zhi Chang et al.
Summary: Thin separators can improve the energy densities of batteries but also increase the risk of short circuits. In this study, an improved thin metal-organic frameworks separator is reported to enhance the resistance to dendrite formation and cycling stability of high-voltage lithium batteries in carbonate electrolytes.
NATURE COMMUNICATIONS
(2022)
Editorial Material
Chemistry, Physical
Yong-Sheng Hu et al.
ACS ENERGY LETTERS
(2022)
Article
Multidisciplinary Sciences
Ziyang Lu et al.
Summary: The desolvation process plays a crucial role in the diffusion kinetics of sodium ions and the formation of a solid electrolyte interface (SEI). Researchers have found that a 3A zeolite molecular sieve film on the hard carbon anode can effectively reduce the activation energy of the direct desolvation process, leading to improved performance.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Chemistry, Physical
Mingsheng Qin et al.
Summary: A PC-based electrolyte with wide-temperature range has been developed by tuning the interactions between lithium ions and propylene carbonate, successfully mitigating the problem of graphite exfoliation caused by co-intercalation. This electrolyte shows compatibility with both graphite and high-nickel cathode, exhibiting an expanded liquid range.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Ting Chen et al.
Summary: This study achieves a LiF-rich SEI and a uniform and dense plating/stripping process by reducing the electrolyte concentration without changing the solvation structure, thereby enhancing the cycling stability of lithium-metal batteries.
Article
Multidisciplinary Sciences
Linshan Peng et al.
Summary: The solvation structures of Li+ have a significant impact on the performance of batteries. Lower salt concentration can lead to unstable solid electrolyte interface (SEI), but solvents with low solvating power can enhance battery kinetics and reduce electrolyte consumption.
Article
Chemistry, Physical
Kyle S. Jiang et al.
Summary: This study investigates the correlation between the structural features of sulfonyl/sulfamoyl fluoride additives and the cycle performance of lithium-ion batteries. The results show that, in addition to coordination, the reactivity of the solvent and the structural features of the additives strongly regulate the cycling efficiency.
ACS ENERGY LETTERS
(2022)
Article
Chemistry, Physical
Jiaming Zhang et al.
Summary: This study proposes a brand-new ultralow concentration mixed ether electrolyte for lithium metal batteries, which improves Coulombic efficiency and safety. The unique solvent structure design leads to over 99.3% lithium deposition/stripping efficiency and superior electrochemical performance.
ENERGY STORAGE MATERIALS
(2022)
Review
Electrochemistry
Yao Wang et al.
Summary: As an emerging battery chemistry, the anion shuttle battery (ASB) is considered a sustainable alternative for gigawatt-scale energy storage due to its resource abundance, low cost, safety, and energy density. However, challenges such as short lifetime, limited capacity, and low efficiency hinder its practical applications. Therefore, it is necessary to design and explore new electrolyte systems with high stability and compatibility for anion electrochemical reactions.
Article
Chemistry, Multidisciplinary
Xin Zhou et al.
Summary: In this study, a fluorinated nitrile compound FEON was introduced as an electrolyte solvent for high-energy density Li|NCM batteries. The optimized FEON-based electrolyte showed better cycling performance compared to a commercial carbonate electrolyte. Molecular dynamics simulation and spectroscopy measurements revealed the solvation structure and decomposition of FEON, which enriched the solid electrolyte interphase on the lithium metal anode. These results demonstrate the promising potential of fluorinated nitrile electrolytes for high energy density Li|NCM batteries.
Article
Chemistry, Multidisciplinary
Jisheng Mo et al.
Summary: A low-concentration all-fluorinated electrolyte has been developed, which exhibits excellent stability and nonflammability for lithium anodes by controlling the solvation structure and interfacial chemistry.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Yin Quan et al.
Summary: The electrochemical performance of low concentration electrolytes is improved through dual interfacial modification of the FEC solvent and the LiODFB additive. The clever design of the multi-layer cathode electrolyte interphase suppresses excessive electrolyte decomposition, improves Li+ diffusion, and enhances the cycling stability of the cathodes.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Physical
Dichang Guan et al.
Summary: In this study, a nonflammable low-concentration electrolyte (LCE) based on the Li+-solvation sheath structure was developed. The addition of nonflammable cosolvent TTE enhanced the oxidation stability of the LCE, resulting in improved rate and cycling performances of lithium-ion batteries. This work provides a new insight into the development of electrolytes for practical applications.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Yu-Xing Yao et al.
Summary: The research reveals a weakly solvating electrolyte that improves the performance of Li-ion batteries by forming unique anion-derived interfaces, demonstrating fast-charging and long-term cycling characteristics.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Shihan Qi et al.
Summary: The study designed alkyl-triphenyl-phosphonium bromides as electrolyte additives to enhance the stability of metallic Li anode under the guidance of multi-factor principle. The additives show positive influences on suppressing Li dendrite growth and stabilizing the unstable interphase between metallic Li anode/electrolyte.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Li-Li Jiang et al.
Summary: By utilizing a localized high-concentration electrolyte, a uniform and robust solid electrolyte interphase can be achieved on the graphite surface, leading to fast-charging performance and excellent cycling stability of lithium-ion batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Cheng Jiang et al.
Summary: A novel strategy was proposed to regulate the solvation sheath for improving Li anodes performance, resulting in the formation of robust solid-electrolyte interphase, reduced amount of free solvent molecules, and enhanced stability of electrolytes. This strategy led to improved lithium deposition and impressive electrochemical performance under low coulombic efficiency conditions in experiments.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Chemistry, Physical
Jian Tan et al.
Summary: Rechargeable lithium batteries have transformed energy storage technology, but their further commercialization is hindered by short lifetime and safety issues, mainly due to the unstable solid-electrolyte interphase (SEI) and uncontrolled lithium dendrite growth. Research on SEI worldwide has focused on its debated structure and composition, particularly the role of the main component LiF. This review covers the development history of the SEI model, fundamental understanding of SEI, categorization of anode materials generating LiF in SEI, characterization techniques of SEI layers, transport mechanism of Li+ ions within SEI, physical properties of LiF, and analysis of LiF sources, offering insights for future research directions to promote large-scale applications of lithium metal batteries.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Rui Jiang et al.
Summary: A new additive, BSTFA, is introduced in this study to stabilize the electrolyte and fabricate a highly conductive interface in sodium metal batteries, improving their performance.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Thuy Duong Pham et al.
Summary: The study introduces 1,2-diethoxyethane (DEE) as a new electrolytic solvent for lithium metal batteries (LMBs), which shows improved cycling stability and Coulombic efficiencies. The use of DEE helps in reducing dendrite growth, preventing unwanted side-reactions, and creating possibilities for high-energy-density rechargeable LMBs.
Article
Chemistry, Multidisciplinary
Tao Li et al.
Summary: By regulating the electrolyte structure of anions using TPFPB anion acceptors, a stable anion-derived SEI was constructed to improve the stability and cycling performance of lithium metal batteries under practical conditions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Zhenxing Wang et al.
Summary: The sluggish evolution of lithium ions' solvation sheath can lead to dendrite formation and capacity loss in lithium batteries, especially at low temperatures. However, by using an ion-dipole strategy to regulate the fluorination degree of solvating agents, it is possible to accelerate the evolution of Li+ solvation sheath and improve battery performance. The DFEC-based electrolyte demonstrates significantly faster ion desolvation rate at low temperatures, allowing for better capacity retention in LiNi0.8Co0.1Mn0.1O2||lithium cells after cycling. This work provides a new technique towards rational design of electrolyte engineering for low-temperature lithium batteries.
ADVANCED ENERGY MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Caiyun Wang et al.
Summary: The reversible plating and stripping of magnesium has been achieved in conventional carbonate electrolytes through cooperative solvation/surface engineering. The addition of strongly electronegative Cl from the-MgCl2 additive impairs the Mg2+ desolvation barrier to accelerate redox kinetics, while a Mg2+-conducting polymer coating on the Mg surface ensures efficient Mg2+ migration and effective electrolyte isolation.
NANO-MICRO LETTERS
(2021)
Article
Electrochemistry
Georgios Nikiforidis et al.
Summary: This study demonstrates the compatibility of low-concentration Li salt electrolytes with promising cathode and anode materials, showcasing excellent performance in terms of high specific capacities, high coulombic efficiencies, high capacity retention, modest energy density, and extended calendar life.
BATTERIES & SUPERCAPS
(2021)
Article
Chemistry, Physical
Keisuke Shigenobu et al.
Summary: By investigating the effects of Li+-solvent and Li+-anion interactions on Li+ transference numbers in liquid electrolytes, insight into the design principles of single-ion conducting liquid electrolytes has been gained, which contributed to improving Li+ ion transport efficiency.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Review
Chemistry, Multidisciplinary
Chong Yan et al.
ADVANCED FUNCTIONAL MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Nan Wu et al.
ADVANCED FUNCTIONAL MATERIALS
(2020)
Article
Chemistry, Physical
Seon Hwa Lee et al.
ADVANCED ENERGY MATERIALS
(2020)
Article
Nanoscience & Nanotechnology
Si Liu et al.
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Chemistry, Multidisciplinary
Yang Yang et al.
CHEMICAL COMMUNICATIONS
(2020)
Article
Chemistry, Physical
Tingzheng Hou et al.
Article
Chemistry, Multidisciplinary
Li Wang et al.
Review
Chemistry, Multidisciplinary
Lidan Xing et al.
ACCOUNTS OF CHEMICAL RESEARCH
(2018)
Article
Nanoscience & Nanotechnology
Pengcheng Shi et al.
ACS APPLIED MATERIALS & INTERFACES
(2018)
Article
Chemistry, Multidisciplinary
Xue-Qiang Zhang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2018)
Article
Electrochemistry
T. Richard Jow et al.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2018)
Article
Chemistry, Multidisciplinary
Chong Yan et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2018)
Article
Chemistry, Physical
Cai Shen et al.
Article
Chemistry, Multidisciplinary
Xiaofei Hu et al.
Article
Electrochemistry
Eibar Flores et al.
ELECTROCHIMICA ACTA
(2017)
Article
Electrochemistry
ZH Chen et al.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2006)
