期刊
NEW JOURNAL OF CHEMISTRY
卷 47, 期 10, 页码 4818-4831出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj06220h
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This study presents a pyrene-appended low-molecular-weight organogelator that exhibits mechano-thermo-responsive gelation, superhydrophobic surface formation, and dual-channel cyanide sensing. The gelator is capable of qualitative and quantitative sensing in various environments, with a detection limit as low as 5.42 nM. The importance of functional supramolecular materials for achieving a dual-channel sensory response in practical applications is highlighted.
A pyrene-appended low-molecular-weight organogelator (LMWG) [2-(4-nitrophenyl)-3-(pyren-1-yl)acrylonitrile] (CN1) is presented which exhibits mechano-thermo-responsive gelation, superhydrophobic surface formation and naked-eye colorimetric and fluorogenic dual-channel cyanide sensing from different real-world water and food samples based on gelation-induced enhanced emission (GIEE). Attaching pyrene and 4-nitrophenyl acetonitrile enables CN1 to orient into a J-type aggregate, where restricted intramolecular rotation (RIR) results in GIEE without supportive gelling units. In the presence of cyanide ions (CN-), the cyanovinyl unit in the GIEEgen triggers a selective Michael-type nucleophilic addition, leading to qualitative and quantitative sensing both in solutions [detection limit (DL): 5.42 +/- 0.256 nM], gels (DL = 0.48 +/- 0.01 mu M) and thin films (134.24 pg cm(-2)). Importantly, in the absence of self-assembly, the complete hindrance of optical sensing is noticed for the CN1 congener [2-(4-fluorophenyl)-3-(pyren-1-yl)acrylonitrile] (F1), which emphasizes the importance of the functional supramolecular material for achieving a dual-channel sensory response towards GIEE-driven day-to-day practical applications.
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