期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 43, 期 1, 页码 1-16出版社
SCIENCE PRESS
DOI: 10.6023/cjoc202205033
关键词
transition metals; catalysis; keto carbonyl; C-H bond functionalization; organic synthesis
In the past two decades, transition-metal-catalyzed keto carbonyl-directed C-H bond activation has been extensively studied, with noble metals like ruthenium, rhodium, palladium, and iridium as catalysts, as well as inexpensive 3d metals such as manganese, iron, and cobalt. This review summarizes the recent advances in transition-metal-catalyzed keto carbonyl-directed C-H bond functionalization reactions from 2014 to 2021, including various reaction categories such as alkylation, alkenylation, amidation, arylation, cyclization, and more.
In the past two decades, transition-metal-catalyzed keto carbonyl-directed C-H bond activation has evloved as a powerful and convenient tool for the construction of C-C and C-X (X=N, F, O) bonds at the unconventional reaction sites of ketones. Among them, keto carbonyl-directed C-H bond activation reactions catalyzed by noble metals, involving ruthenium, rhodium, palladium and iridium, have been widely explored, whilst inexpensive 3d metals, such as manganese, iron and cobalt, have gradually emerged as hotspot catalysts in keto carbonyl-directed C-H activation reactions recently. In this review, advances on transition-metal-catalyzed keto carbonyl-directed C-H bond functionalization reactions from 2014 to 2021 are summarized, which are devided by reaction categories such as alkylation, alkenylation, amidation, arylation, cyclization, and so on.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据