期刊
OPTICS EXPRESS
卷 31, 期 3, 页码 3549-3564出版社
Optica Publishing Group
DOI: 10.1364/OE.477990Journal
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Laser induced breakdown spectroscopy is a promising method for the rapid analysis of Li and its isotopes. However, challenges arise from spectral broadening, fine and hyperfine structures, and self-reversal effects. This study investigates the impact of ambient gases on line broadening and self-reversal of Li isotopes in laser produced plasmas. The results show that lower pressures and optimized plasma conditions can improve the accuracy of isotopic analysis.
Laser induced breakdown spectroscopy is a promising, rapid analysis method for the detection and quantification of Li and its isotopes needed in geochemical, nuclear, and energy storage applications. However, spectral broadening in laser produced plasmas, presence of fine and hyperfine structures, and self-reversal effects make Li isotopic analysis via laser induced breakdown spectroscopy challenging. The present study explores the influence of Ar, N2, and He ambient gases over the pressure range of 0.05 -100 Torr on line broadening and self-reversal of the Li I transition with the greatest isotopic shift in the VIS spectral region (i.e., approximate to 670.8 nm, approximate to 15.8 pm isotopic shift). We perform spatially and temporally resolved optical emission spectroscopy of plasmas produced via laser ablation of LiAlO2 substrates. Our results show that the self-reversal and linewidth is reduced at lower pressures for all gases, and using optimized plasma conditions with chemometric methods, the 6Li/7Li isotopic ratios can be predicted.(c) 2023 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement
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