期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 21, 期 12, 页码 2516-2523出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ob00170a
关键词
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An unprecedented (5 + 2)-cycloaddition reaction between ortho-hydroxyethyl phenol and internal alkyne was developed using rhodium(iii) catalysis. This reaction provided benzoxepine derivatives with high biological significance. A wide range of ortho-hydroxyethyl phenols and internal alkynes were effectively used to obtain high yields of benzoxepines.
An unprecedented (5 + 2)-cycloaddition reaction of ortho-hydroxyethyl phenol and internal alkyne was developed. This Rh(iii)-catalyzed reaction provided benzoxepine derivatives which have very high biological significance. A wide range of ortho-hydroxyethyl phenols and internal alkynes were studied to provide the benzoxepines in high yields.
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