4.6 Review

Advances in nuclear magnetic resonance spectroscopy: case of proton conductive materials

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Ion and Molecular Transport in Solid Electrolytes Studied by NMR

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Summary: This review focuses on the progress of solvation and mobility studies in solid electrolyte, particularly ion-exchange membranes and composite materials, using NMR techniques. The applications of various NMR techniques are discussed, and comparisons are made between diffusion coefficients and ionic conductivity data. The microscopic mechanism of ionic transfer is also explored.

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Summary: Proton magnetic resonance spectroscopy (H-1-MRS) is a non-invasive method to analyze the biochemical profile of brain tumors. Traditional H-1-MRS methods face challenges in spatial coverage and resolution. In recent years, more advanced metabolic imaging and spectroscopic sequences have greatly influenced the field of neuro-oncologic metabolomics. This review article summarizes the potential clinical applications of emerging techniques in studying brain tumor metabolism.

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Polymer Electrolytes for Lithium-Ion Batteries Studied by NMR Techniques

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Nikita A. Slesarenko et al.

Summary: For the first time, the correlation times and diffusion coefficients of water molecules in Li+, Na+, and Cs+ ionic forms of Nafion 117 membrane were measured using H-1 spin relaxation and pulsed field gradient NMR. The hydration numbers of Li+, Na+, and Cs+ cations were also calculated. It was found that the macroscopic transfer at high humidity is controlled by the local translational motion of water molecules.

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Article Chemistry, Physical

Mobility of Li+, Na+, Cs+ Cations in Sulfocation-Exchange Membranes Based on Polyethylene and Grafted Sulfonated Polystyrene Studied by NMR Relaxation

V. I. Volkov et al.

Summary: The mobility of alkaline metal cations Li+, Na+, Cs+ in polyethylene and sulfonated grafted polystyrene membranes was studied using NMR relaxation technique. The interaction between nuclear quadrupole moment and electric field gradient generated by cation hydrated water molecules and sulfonate groups was found to contribute to spin relaxation. The translational cation mobility was calculated from the temperature dependences of spin-lattice (T1) and spin-spin (T2) relaxation, and it was observed that cation mobility followed the order Li+ < Na+ < Cs+. Comparison of diffusion coefficients calculated from NMR relaxation with macroscopic diffusion coefficients measured by other techniques revealed that membrane conductivity is limited by ion transfer in narrow pores with low functional group concentration.

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Highly Proton-Conducting Membranes Based on Poly(arylene ether)s with Densely Sulfonated and Partially Fluorinated Multiphenyl for Fuel Cell Applications

Tzu-Sheng Huang et al.

Summary: The study successfully synthesized a series of partially fluorinated sulfonated poly(arylene ether) membranes with good mechanical properties and high proton conductivity, which showed excellent performance in fuel cells. The membranes demonstrated significant dimensional and oxidative stability while maintaining outstanding cell performance.

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Review Biochemistry & Molecular Biology

Molecular and Ionic Diffusion in Ion Exchange Membranes and Biological Systems (Cells and Proteins) Studied by NMR

Vitaliy Volkov et al.

Summary: The results of NMR, especially PFG NMR investigations, summarize the direct investigation of partial self-diffusion processes in different materials and the widespread application of this technique in areas such as lithium batteries and fuel cells. Additionally, the exchange processes in biological cells and molecular association of proteins were discussed as another field of application for PFG NMR.

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Carbon nanotube, graphene oxide and montmorillonite as conductive fillers in polymer electrolyte membrane for fuel cell: an overview

Maryam Taufiq Musa et al.

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Nuclear Magnetic Resonance: A Spectroscopic Probe to Understand the Electronic Structure and Reactivity of Molecules and Materials

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Summary: Chemical shift can be used to identify and characterize the electronic structure and reactivity of molecules and materials, particularly in the areas of organometallic compounds and inorganic materials relevant to catalysis.

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Conceptual Membraneless Fuel Cell Device Based On Ionic Liquid|Water Interface

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Use of Solid-State NMR Spectroscopy for the Characterization of Molecular Structure and Dynamics in Solid Polymer and Hybrid Electrolytes

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Summary: Solid-state NMR spectroscopy is an established experimental technique used to characterize the structural and dynamic properties of materials, including lithium and sodium-based solid electrolytes. This review discusses various solid-state NMR experiments commonly used in polymer and hybrid electrolyte systems, providing examples and discussing the strengths and weaknesses of each technique. It aims to assist in selecting appropriate solid-state NMR experiments for analyzing these systems.

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Mitigation of water and electrolyte imbalance in all-vanadium redox flow batteries

Jeongmin Shin et al.

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A New Solid-State Proton Conductor: The Salt Hydrate Based on Imidazolium and 12-Tungstophosphate

Anna Martinelli et al.

Summary: The study presents a novel solid-state proton conductor obtained through acid-base chemistry, showing higher proton conductivity and densely packed solid structure. Computational results suggest that the proton transfer primarily involves imidazole and water molecules, with the Keggin anion contributing to lowering the energy barrier.

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