A new organic-inorganic hybrid compound, [C12H17N2](2)ZnBr4, was synthesized and studied using single-crystal X-ray diffraction, optical absorption, and complex impedance spectroscopy. The compound has a centrosymmetric crystal structure in the P2(1)/n space group at room temperature, consisting of [ZnBr4](2-) anions and (C12H17N2)(+) cations. The crystal packing is stabilized by hydrogen bonding and the compound exhibits semiconductor properties with a band gap of 3.94 eV.
A new organic-inorganic hybrid, namely the [C12H17N2](2)ZnBr4 compound, has been synthesized and studied by single-crystal X-ray diffraction and optical and complex impedance spectroscopy. It crystallized in the centrosymmetric P2(1)/n space group at room temperature. The asymmetric unit is constituted by [ZnBr4](2-) anions, showing slightly distorted tetrahedral geometry, surrounded by four organic (C12H17N2)(+) cations. The crystal packing is stabilized by N-HMIDLINE HORIZONTAL ELLIPSISBr and C-HMIDLINE HORIZONTAL ELLIPSISBr hydrogen bonds arranged in a three-dimensional network. The optical absorption measurement confirms the semiconductor nature with a band gap of around 3.94 eV. Additionally, the analysis of Nyquist plots (-Z '' vs. Z ') shows that the electrical properties of the material are heavily dependent on frequency and temperature, indicating a relaxation phenomenon and semiconductor-type behavior. Reduction in Z ' was observed as a function of temperature and frequency which indicates an increase in ac conductivity and the negative temperature coefficient of resistance. The frequency dependent plots of (-Z '') show that the electrical relaxation is non-Debye in nature. The ac conductivity spectrum obeys Jonscher's universal power law. The Correlated barrier hopping model CBH has been suggested to agree with the conduction mechanism of sigma(ac) for the [C12H17N2](2)ZnBr4 compound.
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