期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 32, 页码 4774-4777出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc06790k
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The sandwich polyoxometalate [WCo3(H2O)(2)(CoW9O34)(2)](12-) (Co-WCo3) heterogenized with poly(vinyl butyl imidazolium) cations (PVIM+) acts as a stable electrochemical water oxidation catalyst in 1 M KOH with 0.28 V@10 mA cm(-2) overpotential and TOF of 6.16 s(-1). Various in situ spectroelectrochemical studies and control experiments provide the details of the catalytic activities and long-term stability of the catalyst.
Sandwich polyoxometalate [WCo3(H2O)(2)(CoW9O34)(2)](12-) (Co-WCo3) heterogenized with poly(vinyl butyl imidazolium) cations (PVIM+) acts as a stable electrochemical water oxidation catalyst in 1 M KOH with 0.28 V@10 mA cm(-2) overpotential and TOF of 6.16 s(-1). Various in situ spectroelectrochemical studies and control experiments provide the details of the catalytic activities and long-term stability of the catalyst.
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