This study investigates the effects of spin-symmetry pairing and atomic spin-orbit coupling on superconductivity in a two-band superconductor with two nearly degenerate orbitals. It discovered that the spin-orbit coupling can lead to the realization of topological chiral or helical Majorana edge states without external magnetic fields or Zeeman fields, and a spin-polarized superconducting state when time-reversal symmetry is spontaneously broken.
The gap functions for a single-band model for unconventional superconductivity are distinguished by their unitary or nonunitary forms. Here we generalize this classification to a two-band superconductor with two nearly degenerate orbitals. We focus on spin-singlet pairings and investigate the effects of the atomic spin-orbit coupling (SOC) on superconductivity, which is a driving force behind the discovery of a new spin-orbit coupled nonunitary superconductor. Multiorbital effects such as orbital hybridization and strain-induced anisotropy will also be considered. The spin-orbit coupled nonunitary superconductor has three main features. First, the atomic SOC locks the electron spins to be out-of-plane, leading to a new Type II Ising superconductor with a large in-plane upper critical field beyond the conventional Pauli limit. Second, it provides a promising platform to realize the topological chiral or helical Majorana edge state even without external magnetic fields or Zeeman fields. More surprisingly, a spin-polarized superconducting state could be generated by spin-singlet nonunitary pairings when time-reversal symmetry is spontaneously broken, which serves as a smoking gun to detect this exotic state by measuring the spin-resolved density of states. Our work indicates the essential roles of orbital-triplet pairings in both unconventional and topological superconductivity.
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