4.7 Article

Concurrent tandem catalysis enabled by nanomechanical motion in heteroleptic four-component dual-catalyst machinery

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CHEMICAL COMMUNICATIONS
卷 59, 期 33, 页码 4915-4918

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc00637a

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When the basic ligand 3 was added to the heteroleptic three-component slider-on-deck [Ag-3(1)(2)](3+), it acted as a moderate brake pad (k(298) = 45 kHz). The resulting motion in the four-component slider-on-deck [Ag-3(1)(2)(3)](3+) allowed both ligand 3 and silver(i) to be continuously exposed and become catalytically active in a tandem Michael addition/hydroalkoxylation.
When the basic ligand 3 was added to the heteroleptic three-component slider-on-deck [Ag-3(1)(2)](3+) (sliding frequency k(298) = 57 kHz), it operated as a moderate brake pad (k(298) = 45 kHz). Due to motion in the resulting four-component slider-on-deck [Ag-3(1)(2)(3)](3+), both ligand 3 and silver(i) were continuously exposed and became catalytically active in a concurrent tandem Michael addition/hydroalkoxylation.

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