Influence of Cu insertion on the thermoelectric properties of the quaternary cluster compounds Cu3M2Mo15Se19 (M = In, K) and Cu4In2Mo15Se19

Article Chemistry, Physical

Controlling Defect Chemistry in InTe by Saturation Annealing

Shantanu Misra et al.

Summary: Controlling the concentration of inherent In vacancies in InTe samples through saturation annealing has been shown to optimize its thermoelectric properties.

ACS APPLIED ENERGY MATERIALS (2022)

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Review Energy & Fuels

Keynote Review of Latest Advances in Thermoelectric Generation Materials, Devices, and Technologies 2022

Terry Hendricks et al.

Summary: Tremendous advances have been made in thermoelectric generation materials, devices, fabrication techniques, and technologies in the past decade through global research and development. This article aims to elucidate and highlight some of these advances and lay the foundations for future research and advancements.

ENERGIES (2022)

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Article Chemistry, Physical

Evolution of Thermoelectric Properties in the Triple Cation Zintl Phase: Yb13-xCaxBaMgSb11 (x=1-6)

Christopher J. Perez et al.

Summary: The band structure of Yb14MgSb11 can be adjusted by substituting Ca and Ba ions in different crystallographic positions. The carrier concentration and thermoelectric properties can be modified by changing the x value, with an improvement in the thermoelectric performance observed at higher temperatures. The stiffening lattice with increased x leads to changes in thermal conductivity and eventually results in a peak figure of merit at x = 4, providing a more power dense material compared to Yb14MnSb11.

CHEMISTRY OF MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Synthesis, crystal structure and transport properties of the cluster compounds Tl2Mo15S19 and Ag3Tl2Mo15S19

Patrick Gougeon et al.

Summary: The syntheses and crystal structures of two novel cluster compounds were reported, with silver insertion improving the thermoelectric properties but resulting in a moderate ZT value. This study highlights the potential of Ag3Tl2Mo15S19 as a promising material for thermoelectric applications.

MATERIALS RESEARCH BULLETIN (2021)

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Article Chemistry, Physical

Demonstration of ultrahigh thermoelectric efficiency of ∼7.3% in Mg3Sb2/MgAgSb module for low-temperature energy harvesting

Zihang Liu et al.

Summary: Researchers have made significant advancements in thermoelectric materials by adding minor amounts of Cu to the Mg3Sb1.5Bi0.5 system, leading to improved thermoelectric performance and reduced thermal conductivity. Through grain-boundary engineering, the detrimental effects of thermally activated electrical conductivity were successfully eliminated. The fabricated thermoelectric module, when combined with a p-type alpha-MgAgSb-based material, showed promising potential for low-temperature thermoelectric harvesting.

JOULE (2021)

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Article Materials Science, Multidisciplinary

Enhanced thermoelectric performance of InTe through Pb doping

Shantanu Misra et al.

Summary: Pb doping in InTe semiconductor enhances thermoelectric performance by reducing lattice thermal conductivity and increasing power factor, resulting in improved thermoelectric properties.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Materials Science, Multidisciplinary

Tl0.6Mo3S5, an original large tunnel-like molybdenum sulfide with Mo zigzag chains and disordered Tl cations

Patrick Gougeon et al.

Summary: Tl0.6Mo3S5 is a novel material with large tunnels, crystallizing in a monoclinic structure according to single-crystal X-ray diffraction data. Low-temperature transport measurements show that it behaves as a narrow-band-gap n-type semiconductor, with high thermal conductivity values at 300 K.

MATERIALS ADVANCES (2021)

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Article Chemistry, Multidisciplinary

A material catalogue with glass-like thermal conductivity mediated by crystallographic occupancy for thermoelectric application

Zihang Liu et al.

Summary: This study introduced a new crystallographic parameter for identifying materials with low lattice thermal conductivity, leading to the discovery and synthesis of two compounds with very low κ(lat). By exploring the relationship between crystallography and thermal properties in crystalline materials, the impact of partial occupancy on complex lattice dynamics was revealed, providing new avenues for discovering materials with low κ(lat).

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Materials Science, Multidisciplinary

Synthesis and physical properties of single-crystalline InTe: towards high thermoelectric performance

Shantanu Misra et al.

Summary: Chalcogenide semiconductors and semimetals, including tetragonal InTe, are promising candidates for thermoelectric applications due to their high thermoelectric performance near 800 K. An investigation of InTe single crystals grown over a wide temperature range revealed anisotropic transport coefficients and a semiconductor ground state despite previous suggestions of a semimetallic nature. The extremely low lattice thermal conductivity of InTe, combined with a relatively high power factor, resulted in a maximum dimensionless thermoelectric figure of merit of 0.61 at 780 K along the [110] direction, laying a solid foundation for future doping strategies in high-temperature thermoelectric applications.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Review Energy & Fuels

A comprehensive review of Thermoelectric Generators: Technologies and common applications

Nesrine Jaziri et al.

ENERGY REPORTS (2020)

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Article Chemistry, Physical

Crystal Structure and Atomic Vacancy Optimized Thermoelectric Properties in Gadolinium Selenides

Feiyu Qin et al.

CHEMISTRY OF MATERIALS (2020)

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Article Physics, Multidisciplinary

Reduced phase space of heat-carrying acoustic phonons in single-crystalline InTe

Shantanu Misra et al.

PHYSICAL REVIEW RESEARCH (2020)

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Article Materials Science, Multidisciplinary

Realising the potential of thermoelectric technology: a Roadmap

Robert Freer et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Article Materials Science, Multidisciplinary

Coexistence of a charge density wave and superconductivity in the cluster compound K2Mo15Se19

Christophe Candolfi et al.

PHYSICAL REVIEW B (2020)

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Article Chemistry, Physical

Unravelling the Beneficial Influence of Ag insertion on the Thermoelectric Properties of the Cluster Compound K2Mo15Se19

Gilles Daigre et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Chemistry, Inorganic & Nuclear

Electronic Band Structure and Transport Properties of the Cluster Compound Ag3Tl2Mo15Se19

Patrick Gougeon et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Physical

Synthesis and Characterization of Vacancy-Doped Neodymium Telluride for Thermoelectric Applications

Steven J. Gomez et al.

CHEMISTRY OF MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Ultralow Thermal Conductivity in Chain-like TlSe Due to Inherent Tl+ Rattling

Moinak Dutta et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Materials Science, Multidisciplinary

Thermoelectric Devices: A Review of Devices, Architectures, and Contact Optimization

Ran He et al.

ADVANCED MATERIALS TECHNOLOGIES (2018)

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Article Chemistry, Multidisciplinary

Lanthanide Contraction as a Design Factor for High-Performance Half-Heusler Thermoelectric Materials

Yintu Liu et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Physical

Influence of S and Te substitutions on the thermoelectric properties of the cluster compound Ag3.8Mo9Se11

P. Masschelein et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2018)

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Article Nanoscience & Nanotechnology

Structure Change and Rattling Dynamics in Cu12Sb4S13 Tetrahedrite: an NMR Study

Nader Ghassemi et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Physical

Praseodymium Telluride: A High-Temperature, High-ZT Thermoelectric Material

Dean Cheikh et al.

JOULE (2018)

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Article Chemistry, Physical

Effect of Ag Doping on Electronic Structure of Cluster Compounds AgxMo9Se11 (x=3.4, 3.9)

S. M. Butorin et al.

ACS APPLIED ENERGY MATERIALS (2018)

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Article Materials Science, Multidisciplinary

Lattice dynamics of the cluster chain compounds M2Mo6Se6 (M = K, Rb, Cs, In, and Tl)

Liam Gannon et al.

PHYSICAL REVIEW B (2018)

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Article Chemistry, Inorganic & Nuclear

Synthesis, Crystal Structure, and Transport Properties of the Hexagonal Mo9 Cluster Compound Ag3RbMo9Se11

Patrick Gougeon et al.

INORGANIC CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Intrinsic Rattler-Induced Low Thermal Conductivity in Zintl Type TlInTe2

Manoj K. Jana et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Materials Science, Multidisciplinary

Towards the prediction of the transport properties of cluster-based molybdenum chalcogenides

Rabih Al Rahal Al Orabi et al.

JOURNAL OF MATERIALS CHEMISTRY C (2017)

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Article Chemistry, Inorganic & Nuclear

Cu Insertion Into the Mo12 Cluster Compound Cs2Mo12Se14: Synthesis, Crystal and Electronic Structures, and Physical Properties

Rabih Al Rahal Al Orabi et al.

INORGANIC CHEMISTRY (2016)

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Article Chemistry, Inorganic & Nuclear

Synthesis, crystal structure and high-temperature transport properties of the new cluster compound Rb2Mo15Se19

Gilles Daigre et al.

JOURNAL OF SOLID STATE CHEMISTRY (2016)

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Article Chemistry, Physical

High Temperature Thermoelectric Properties of Yb14MnSb11 Prepared from Reaction of MnSb with the Elements

Jason H. Grebenkemper et al.

CHEMISTRY OF MATERIALS (2015)

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Article Physics, Applied

Chevrel phases: Past, present and future

Octavio Pena

PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS (2015)

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Article Chemistry, Physical

From crystal to glass-like thermal conductivity in crystalline minerals

Y. Bouyrie et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

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Article Chemistry, Physical

On the microscopic dynamics of the 'Einstein solids' AlV2Al20 and GaV2Al20, and of YV2Al20: a benchmark system for 'rattling' excitations

Michael Marek Koza et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

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Article Instruments & Instrumentation

A round robin test of the uncertainty on the measurement of the thermoelectric dimensionless figure of merit of Co0.97Ni0.03Sb3

E. Alleno et al.

REVIEW OF SCIENTIFIC INSTRUMENTS (2015)

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Article Chemistry, Physical

Comprehensive Study of the Low-Temperature Transport and Thermodynamic Properties of the Cluster Compounds AgxMo9Se11 (3.41 ≤ x ≤ 3.78)

T. Zhou et al.

CHEMISTRY OF MATERIALS (2014)

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Article Chemistry, Inorganic & Nuclear

X-ray Characterization, Electronic Band Structure, and Thermoelectric Properties of the Cluster Compound Ag2Tl2Mo9Se11

Rabih Al Rahal Al Orabi et al.

INORGANIC CHEMISTRY (2014)

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Article Physics, Multidisciplinary

Phonon-glass electron-crystal thermoelectric clathrates: Experiments and theory

Toshiro Takabatake et al.

REVIEWS OF MODERN PHYSICS (2014)

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Article Chemistry, Physical

Improved Bulk Materials with Thermoelectric Figure-of-Merit Greater than 1: Tl10-xSnxTe6 and Tl10-xPbxTe6

Quansheng Guo et al.

ADVANCED ENERGY MATERIALS (2014)

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Article Physics, Applied

High-performance thermoelectric mineral Cu12-xNixSb4S13 tetrahedrite

Koichiro Suekuni et al.

JOURNAL OF APPLIED PHYSICS (2013)

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Article Chemistry, Physical

Synthesis, Crystal and Electronic Structures, and Thermoelectric Properties of the Novel Cluster Compound Ag3In2Mo15Se19

Patrick Gougeon et al.

CHEMISTRY OF MATERIALS (2012)

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Article Chemistry, Multidisciplinary

Stronger phonon scattering by larger differences in atomic mass and size in p-type half-Heuslers Hf1-xTixCoSb0.8Sn0.2

Xiao Yan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Article Engineering, Electrical & Electronic

Optimization of Bulk Thermoelectrics: Influence of Cu Insertion in Ag3.6Mo9Se11

Malika Colin et al.

JOURNAL OF ELECTRONIC MATERIALS (2012)

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Article Materials Science, Multidisciplinary

Localized anharmonic rattling of Al atoms in VAl10.1

D. J. Safarik et al.

PHYSICAL REVIEW B (2012)

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Article Physics, Applied

Promising thermoelectric properties in AgxMo9Se11 compounds (3.4 ≤ x ≤ 3.9)

Tong Zhou et al.

APPLIED PHYSICS LETTERS (2011)

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Article Physics, Multidisciplinary

Significance of Off-Center Rattling for Emerging Low-Lying THz Modes in Type-I Clathrates

Tsuneyoshi Nakayama et al.

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN (2011)

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Thermoelectric performance of lanthanum telluride produced via mechanical alloying

Andrew F. May et al.

PHYSICAL REVIEW B (2008)

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Article Materials Science, Multidisciplinary

Cage-size control of guest vibration and thermal conductivity in Sr8Ga16Si30-xGex

K. Suekuni et al.

PHYSICAL REVIEW B (2007)

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Article Chemistry, Physical

Yb14MnSb11:: New high efficiency thermoelectric material for power generation

SR Brown et al.

CHEMISTRY OF MATERIALS (2006)

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Article Materials Science, Multidisciplinary

Thermoelectric materials for space and automotive power generation

JH Yang et al.

MRS BULLETIN (2006)

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Article Materials Science, Multidisciplinary

Crystal structures, atomic vibration, and disorder of the type-I thermoelectric clathrates Ba8Ga16Si30, Ba8Ga16Ge30, Ba8In16Ge30, and Sr8Ga16Ge30 -: art. no. 144107

A Bentien et al.

PHYSICAL REVIEW B (2005)

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Article Materials Science, Multidisciplinary

Off-center phonon scattering sites in Eu8Ga16Ge30 and Sr8Ga16Ge30

R Baumbach et al.

PHYSICAL REVIEW B (2005)

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Article Chemistry, Physical

Disordered zinc in Zn4Sb3 with phonon-glass and electron-crystal thermoelectric properties

GJ Snyder et al.

NATURE MATERIALS (2004)

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Article Materials Science, Multidisciplinary

Transport properties of polycrystalline type-I Sn clathrates

GS Nolas et al.

PHYSICAL REVIEW B (2002)

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Article Chemistry, Multidisciplinary

Rb5Mo27Se31, a novel ternary reduced molybdenum selenide containing Mo12 and Mo15 clusters

S Picard et al.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2001)

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Article Chemistry, Inorganic & Nuclear

Rb2n(Mo9S11)(Mo6nS6n+2) (n=1 to 4):: A novel family of superconducting molybdenum cluster compounds

S Picard et al.

JOURNAL OF SOLID STATE CHEMISTRY (2000)

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Influence of Cu insertion on the thermoelectric properties of the quaternary cluster compounds Cu3M2Mo15Se19 (M = In, K) and Cu4In2Mo15Se19

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