期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 28, 页码 4213-4216出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc00942d
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This study presents the direct synthesis of trifluoromethyl N,N-aminals from nitrogen containing heterocycles using argon plasma in a continuous flow microreactor without any additives or metal catalysts. The transformation of these compounds to N-trifluoroethyl amines is also reported.
Trifluoromethyl N,N-aminals are important precursors allowing access to fluorinated building blocks. In this work, the direct synthesis of trifluoromethyl N,N-aminals from nitrogen containing heterocycles is reported using argon plasma in a continuous flow microreactor without any additives or metal catalysts. Their transformation to N-trifluoroethyl amines is also reported.
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