Modulating the Schottky barrier of Pt/PbTiO3 for efficient piezo-photocatalytic hydrogen evolution

Charge recombination severely restricts the photocatalytic efficiencies of materials. Loading cocatalysts on the surface of host photocatalysts is a promising strategy for charge separation, which, however, suffers from the large Schottky barrier at the cocatalyst/host interface. Herein, a series of Pt/PbTiO3 compounds were constructed as a proof-of-concept utilizing the piezoelectric field of PbTiO3 under acoustic vibrations to modulate the height of the interfacial Schottky barrier. These hybrid systems achieved highly efficient piezo-photocatalytic H-2 evolution under simultaneous ultrasonication and light illumination. The manipulation of the height of the Schottky barrier by the piezoelectric effect was validated by the I-V characteristics collected from conductive AFM. It is proposed that the acoustic-wave-induced piezoelectric field increased the electron flow from PbTiO3 to Pt over the modulated Schottky barrier, which promoted the spatial separation of photo-generated charge carriers and consequently enhanced the H-2 evolution. These findings will extend the fundamental understanding of the synergistic piezo-photocatalysis mechanism and provide a new opportunity toward the rational design of novel materials systems for clean energy conversion.

Automated summary

Loading cocatalysts on the host photocatalyst surface is an effective strategy for charge separation, but suffers from a large Schottky barrier at the interface. In this study, a series of Pt/PbTiO3 compounds were constructed to modulate the interfacial Schottky barrier height using the piezoelectric field of PbTiO3 under acoustic vibrations, achieving highly efficient piezo-photocatalytic H2 evolution. The manipulation of the Schottky barrier height was validated by conductive AFM measurements, and the enhanced H2 evolution was attributed to the increased electron flow and spatial separation of charge carriers induced by the acoustic-wave-induced piezoelectric field. These findings will contribute to the understanding of the synergistic piezo-photocatalysis mechanism and the rational design of clean energy conversion materials.