Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition

Article Chemistry, Multidisciplinary

Triple-decker complexes incorporating three distinct deck architectures

Xiaofei Sun et al.

Summary: The reactivity of dilithioplumbole with P-4 and pentaphosphaferrocene is studied, resulting in the formation of metal compounds with specific structures.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Forging a Cage into a Chain: Stepwise Transformation of P4 by Silylenes to a Si3P4 Motif

Xiaofei Sun et al.

Summary: By stepwise activation of white phosphorus using two different silylene precursors, we have discovered a route to access a seven-membered chain structure that incorporates three silicon and four phosphorus atoms. The isolation and analysis of stable analogues of the reactive intermediates provide insights into the synthesis, stability and structural features of the chain species.

CCS CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Structurally characterised intermediate of the oxidative addition of a heteroleptic germylene to gallanediyle

Anna Buecker et al.

Summary: Bond activation reactions using main group metal complexes have been studied, and different products have been obtained by reacting with heteroleptic tetrylenes. The characterized compounds were analyzed by various experimental techniques.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Recent advances in cooperative activation of CO2 and N2O by bimetallic coordination complexes or binuclear reaction pathways

Soumen Sinhababu et al.

Summary: The gaseous small molecules, CO2 and N2O, play important roles in climate change and ozone layer depletion. This perspective reviews recent advances in the cooperative activation of CO2 and N2O, which are challenging due to their inertness.

DALTON TRANSACTIONS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Photochemically Activated Dimagnesium(I) Compounds: Reagents for the Reduction and Selective C-H Bond Activation of Inert Arenes

Dafydd D. L. Jones et al.

Summary: The study reported the photochemical activation of dimagnesium(I) compounds with inert arenes, leading to high yielding, regioselective reactions. Computational studies suggested that all reactions proceed via photochemically generated magnesium(I) radicals, which reduce the arene substrate before C-H or C-F bond activation processes occur.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Multi-Talented Gallaphosphene for Ga-P-Ga Heteroallyl Cation Generation, CO2 Storage, and C(sp3)-H Bond Activation

Mahendra K. Sharma et al.

Summary: The synthesized Gallaphosphene displayed diverse chemical properties during reactions, including different reaction pathways and products with different substrates.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Multidisciplinary Sciences

Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus

Stephan Reichl et al.

Summary: The study presents an efficient method for preparing asymmetric phosphines from white phosphorus, utilizing a transition metal-mediated reaction that allows for recycling and avoids the use of hazardous chemicals.

NATURE COMMUNICATIONS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

d/f-Polypnictides Derived by Non-Classical Ln2+ Compounds: Synthesis, Small Molecule Activation and Optical Properties

Niklas Reinfandt et al.

Summary: The study successfully establishes a more complex and comprehensive research method on the reduction chemistry of lanthanides by using a variety of new reducing agents, resulting in multiple new compounds. Activation of P-4 was achieved, leading to the selective expansion of P-5 rings and successful activation of P-4 in lanthanide element polypnictide complexes. Additionally, the first systematic femtosecond (fs)-spectroscopy investigations of d/f-polypnictides were presented, showcasing the advantages of accessing a broader series of lanthanide compounds.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Reactivity of Cu(I) Nacnac Complexes Toward Polypnictogen Compounds

Maria Haimerl et al.

Summary: The article investigates the reaction of nacnac Cu(I) compound with complexes containing aromatic cyclo-E-n ligands, resulting in the formation of various heterometallic complexes. These complexes were characterized comprehensively and their dynamic behavior in solution was studied using VT NMR spectroscopy, with electronic structures elucidated by DFT calculations.

INORGANIC CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Au-Containing Coordination Polymers Based on Polyphosphorus Ligand Complexes

Helena Brake et al.

Summary: The self-assembly processes of pentaphosphaferrocenes with Au salts of different anions have been reported, leading to various molecular coordination products and the first coordination polymers based on polyphosphorus ligand complexes and Au salts. The study also isolated a 2D coordination polymer comprising metal vacancies. The coordination of Au centers in the products is either linear or trigonal planar, with highly dynamic processes observed in solution.

INORGANIC CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Structural Diversity of Molecular Alkaline-Earth-Metal Polyphosphides: From Supramolecular Wheel to Zintl Ion

Ravi Yadav et al.

Summary: A series of molecular group 2 polyphosphides were synthesized using different group 2 reagents to activate polyphosphorus sources. Unique Mg/Fe-supramolecular wheel and first examples of molecular calcium-polyphosphides were obtained in the study.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Substituted aromatic pentaphosphole ligands - a journey across the p-block

Christoph Riesinger et al.

Summary: The functionalization of pentaphosphaferrocene with cationic group 13-17 electrophiles is a general synthetic strategy towards diverse P-E bond formation. The reaction products include dinuclear or mononuclear complexes of hetero-bis-pentaphosphole or hetero-pentaphosphole ligands, with X-ray crystallographic characterization revealing twisted conformations of the cyclo-P5R ligands in the compounds. DFT calculations confirm the aromatic character of the pentaphosphole ligands and shed light on the bonding situation in these compounds.

CHEMICAL SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Main group bimetallic partnerships for cooperative catalysis

Jose M. Gil-Negrete et al.

Summary: Over the past decade, s-block metal catalysis has evolved from being a mysterious curiosity to a well-established field towards sustainable synthesis, with earth-abundant metals showing excellent catalytic performance. Bimetallic reagents have attracted widespread interest for providing enhanced reactivities and selectivities, although most efforts have focused on stoichiometric transformations.

CHEMICAL SCIENCE (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Paramagnetic Metal-Metal Bonded Heterometallic Complexes

Jill A. Chipman et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

A General Pathway to Heterobimetallic Triple-Decker Complexes

Martin Piesch et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Highly Selective Substitution and Insertion Reactions of Silylenes in a Metal-Coordinated Polyphosphide

Ravi Yadav et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

NHCs as Neutral Donors towards Polyphosphorus Complexes

Felix Riedlberger et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stabilization of Pentaphospholes as η5-Coordinating Ligands

Christoph Riesinger et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent

Yuwen Wang et al.

Nature Chemistry (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Chemoselective synthesis of heterobimetallic bis-NHC complexes

Patrick D. Dutschke et al.

DALTON TRANSACTIONS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Homocoupling of CO and isocyanide mediated by a C,C′-bis(silylenyl)-substituted ortho-carborane

Yun Xiong et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization

Ravi Yadav et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

Stuart D. Robertson et al.

CHEMICAL REVIEWS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules

Yuwen Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

A General Route to Metal-Substituted Dipnictenes of the Type [L(X)M](2)E-2

Lars Tuscher et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

添加到收藏夹

Article Multidisciplinary Sciences

Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds

Kuangbiao Liao et al.

NATURE (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Arsenic-Rich Polyarsenides Stabilized by Cp*Fe Fragments

Monika Schmidt et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Molecular Polyarsenides of the Rare-Earth Elements

Nicholas Arleth et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Modular Click Preparation of Bifunctional Polymeric Heterometallic Catalysts

Wenlong Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Review Multidisciplinary Sciences

The broadening reach of frustrated Lewis pair chemistry

Douglas W. Stephan

SCIENCE (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Giant Rugby Ball [{CpBnFe(η5-P5)}24Cu96Br96] Derived from, Pentaphosphaferrocene and CuBr2

Claudia Heindl et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Nano-sized Supramolecule Beyond the Fullerene Topology

Fabian Dielmann et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ferrocene and Pentaphosphaferrocene: A Comparative Study Regarding Redox Chemistry

Mikhail V. Butovskiy et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Interconversion of Quadruply and Quintuply Bonded Molybdenum Complexes by Reductive Elimination and Oxidative Addition of Dihydrogen

Mario Carrasco et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

P-P bond formation via reductive dimerization of [Cp*Fe(eta(5)-P-5)] by divalent samarocenes

Tianshu Li et al.

CHEMICAL COMMUNICATIONS (2013)

添加到收藏夹

Article Multidisciplinary Sciences

Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex

Katherine P. Kornecki et al.

SCIENCE (2013)

添加到收藏夹

Review Chemistry, Multidisciplinary

Cooperative bimetallic catalysis in asymmetric transformations

Jongwoo Park et al.

CHEMICAL SOCIETY REVIEWS (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Zwitterionic Si-C-Si-P and Si-P-Si-P Four-Membered Rings with Two-Coordinate Phosphorus Atoms

Sakya S. Sen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mixed-Metal Lanthanide-Iron Triple-Decker Complexes with a cyclo-P-5 Building Block

Tianshu Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

A P4 Chain and Cage from Silylene-Activated White Phosphorus

Shabana Khan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

添加到收藏夹

Review Chemistry, Multidisciplinary

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

Douglas W. Stephan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Structures and Properties of Spherical 90-Vertex Fullerene-Like Nanoballs

Manfred Scheer et al.

CHEMISTRY-A EUROPEAN JOURNAL (2010)

添加到收藏夹

Article Chemistry, Physical

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

Stefan Grimme et al.

JOURNAL OF CHEMICAL PHYSICS (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs

Cornelia M. Moemming et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Molecular Double-Bond Covalent Radii for Elements Li-E112

Pekka Pyykko et al.

CHEMISTRY-A EUROPEAN JOURNAL (2009)

添加到收藏夹

Article Multidisciplinary Sciences

Stable magnesium(I) compounds with Mg-Mg bonds

Shaun P. Green et al.

SCIENCE (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

Consecutive insertion of a silylene into the P-4 tetrahedron: Facile access to strained SiP4 and Si2P4 cage compounds

Yun Xiong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

添加到收藏夹

Article Chemistry, Physical

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy

F Weigend et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2005)

添加到收藏夹

Article Multidisciplinary Sciences

Synthesis of inorganic fullerene-like molecules

JF Bai et al.

SCIENCE (2003)

添加到收藏夹

Article Chemistry, Multidisciplinary

Coordination chemistry umpolung: A gallane ligand on a phosphine Lewis acceptor

N Burford et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)

添加到收藏夹

Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition

相关参考文献

导出引文

分享论文