Selective Cu and Ni-MOFs as pre-catalysts for the hydrogenation of furfural to furfuryl alcohol

Article Chemistry, Multidisciplinary

Chiral Lanthanum Metal-Organic Framework with Gated CO2 Sorption and Concerted Framework Flexibility

Francoise M. Amombo Noa et al.

Summary: A new metal-organic framework (MOF) CTH-17 with a new topology and high-temperature stability is prepared. CTH-17 exhibits a gate-opening effect for carbon dioxide adsorption, showing potential applications.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Applied

Pore size effect of 1,3,6,8-tetrakis(4-carboxyphenyl)pyrene-based metal-organic frameworks for enhanced SF6 adsorption with high selectivity

Michelle Ahlen et al.

Summary: This study presents four highly porous metal-organic frameworks with good SF6 sorption properties, chemical stability, and cyclic sorption stability, making them potential efficient sorbents for SF6 in industrial applications.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

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Article Chemistry, Applied

Efficient hydrogenation of furfural to fufuryl alcohol over hierarchical MOF immobilized metal catalysts

Ruiqi Fang et al.

Summary: By utilizing hierarchical porous H-UiO-66 as a support, a series of transition-metal catalysts were synthesized for efficient conversion of furfural to furfuryl alcohol. The unique nanoarchitecture of the catalyst resulted in low mass diffusion resistance, high accessibility of metal active sites, and high durability in the liquid phase reaction, achieving nearly quantitative yield of furfuryl alcohol within 3 hours.

CATALYSIS TODAY (2021)

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Article Biotechnology & Applied Microbiology

Metal-organic frameworks derived magneticFe3O4/C for catalytic transfer hydrogenation of furfural to furfuryl alcohol

Shanshan Jiang et al.

Summary: Fe-based metal organic frameworks and carbon-loaded Fe3O4 materials were prepared and used as catalysts for the catalytic transfer hydrogenation of furfural. The Fe3O4/C catalyst showed good stability and reusability under different experimental conditions.

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

Docking of CuI and AgI in Metal-Organic Frameworks for Adsorption and Separation of Xenon

Haoze Wang et al.

Summary: In this study, a metal docking strategy was introduced using the spatial arrangement of organic struts in a MOF. The resulting metalated MOFs showed high capacity and selectivity for Xe adsorption, with Ag-MOF-303 exhibiting exceptional performance. Coordination geometries of Cu-I and Ag-I were examined using advanced spectroscopy techniques.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Redox property switching in MOFs with open metal sites for improved catalytic hydrogenation performance

Longlong Geng et al.

Summary: In this study, a decompression-thermalization strategy was used to tune the redox and catalytic hydrogenation properties of a Cu-containing metal-organic framework (MOF). The generation of open metal sites (OMSs) significantly improved the catalytic performance in hydrogenation reactions, with experimental and theoretical results showing that OMSs endow Cu species with unique electronic properties.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Materials Science, Multidisciplinary

Aqueous phase catalytic hydrogenation of furfural to furfuryl alcohol over in-situ synthesized Cu-Zn/SiO2 catalysts

Jinxin Zhang et al.

Summary: The study focused on synthesizing Cu-based catalysts supported on SiO2 for the hydrogenation of furfural to furfuryl alcohol, with the in-situ synthesized Cu-Zn/SiO2-IS catalyst showing excellent performance. The addition of Zn species not only improved the reduction of CuO and dispersion of metal Cu, but also effectively prevented decarbonylation, leading to higher selectivity for furfuryl alcohol. The in-situ synthesized catalyst has great potential for industrial applications.

MATERIALS CHEMISTRY AND PHYSICS (2021)

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Article Crystallography

X-Ray Photoelectron Spectroscopy Depth Profiling of As-Grown and Annealed Titanium Nitride Thin Films

Monzer Maarouf et al.

Summary: In this study, titanium nitride thin films were grown on Si(001) and fused silica substrates by radio frequency reactive magnetron sputtering, followed by post-growth annealing at different temperatures in nitrogen ambient. The films annealed at temperatures above 300 degrees C showed higher surface roughness, smaller grain size, better crystallinity, and decreased bandgap. Hall effect measurements indicated n-type conductivity in all films, with high carrier concentration that slightly increased with annealing temperature. X-ray photoelectron spectroscopy confirmed the formation of Ti-N bond and the presence of chemisorbed oxygen in the films, with annealing in nitrogen ambient resulting in increased nitrogen vacancies and non-stoichiometric TiN films.

CRYSTALS (2021)

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Article Chemistry, Physical

X-ray Photoelectron Spectroscopic Study of Some Organic and Inorganic Modified Clay Minerals

J. Theo Kloprogge et al.

Summary: XPS analysis of layered clay systems with intercalated inorganic and organic compounds reveals valuable insights into the structure, coordination, and oxidative transformations of these compounds. By studying the shifts in binding energies and multiplet splitting, XPS can track changes in oxidation states and coordination environments within the materials.

MATERIALS (2021)

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Article Chemistry, Physical

Core-Shell Fe2O3@La1-xSrxFeO3-δ Material for Catalytic Oxidations: Coverage of Iron Oxide Core, Oxygen Storage Capacity and Reactivity of Surface Oxygens

Hen Ohayon Dahan et al.

Summary: A series of Fe2O3@LSF core-shell materials were prepared by infiltration of LSF precursors gel into nanocrystalline hematite aggregates, with the coverage of LSF shell on iron oxide core being influenced by the type and amount of complexants. The reactivity and distribution of surface oxygen species in the core-shell materials were studied under different coverage conditions, showing an increase in lattice oxygen storage capacity with complete coverage by perovskite shell.

MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Stable, Efficient, Copper Coordination Polymer-Derived Heterostructured Catalyst for Oxygen Evolution under pH-Universal Conditions

Ligang Wang et al.

Summary: The construction of heterostructured interface in Cu/CuCN electrocatalysts leads to superior activity and stability in pH-universal media, displaying lower overpotentials and higher intrinsic activity compared to previous catalysts. The presence of CuO species at the heterointerface during basic OER contributes to the enhanced OER performance, indicating abundant active sites accelerating conversion kinetics.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Applied

The activation of Co-MOF-74 with open metal sites and their corresponding CO/N2 adsorptive separation performance

Xiaowu Liang et al.

Summary: In this study, the activation behavior and CO/N-2 adsorptive separation performance of Co-MOF-74, a metal organic framework containing open metal sites, were investigated. Through TG-MS and NMR analysis, it was found that high temperature activation effectively removed guest molecules, leading to improved CO adsorption performance.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Multidisciplinary Sciences

The same chemical state of carbon gives rise to two peaks in X-ray photoelectron spectroscopy

G. Greczynski et al.

Summary: Chemical state analysis in X-ray photoelectron spectroscopy (XPS) relies on assigning well-defined binding energy values to core level electrons originating from atoms in particular bonding configurations. Here, direct evidence is presented for the violation of this paradigm, as the C 1s peak due to C-C/C-H bonded atoms from adventitious carbon (AdC) layers splits into two distinctly different contributions. This finding exposes fundamental problems with the reliability of reported XPS data and suggests discontinuing the use of adventitious carbon in XPS.

SCIENTIFIC REPORTS (2021)

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Article Geochemistry & Geophysics

Towards Sustainability Pathway with Bio-Derived Platinum and Palladium Catalyst for Furfural Hydrogenation-A Novel Greener Approach in Catalysis

Babatunde J. Akinbile et al.

Summary: This study demonstrates the utilization of novel bio-ore catalysts recovered from plant phytomining process for selective hydrogenation of furfural to furfuryl alcohol, achieving high yields and excellent catalytic activities. The produced bio-ore catalysts show promising potential as recyclable catalysts for multiple cycles of reaction.

MINERALS (2021)

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Article Chemistry, Multidisciplinary

A unified topology approach to dot-, rod-, and sheet-MOFs

Francoise M. Amombo Noa et al.

Summary: This study introduces a novel type of MOF structure - sheet-MOFs, and demonstrates examples of dot-MOFs, rod-MOFs, and sheet-MOFs based on structures containing Y3+, Ce3+, or Gd3+. It suggests that the stability of MOFs follows the trend dot < rod < sheet, and highlights the potential of sheet-MOFs as an additional strategy for making robust MOFs.

CHEM (2021)

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Article Chemistry, Multidisciplinary

Crystalline Cu(ii) metal-organic frameworks based on a carboxamide pincer ligand and an NCONCON-Pd(ii) pincer complex

Siphelele S. P. Malaza et al.

Summary: Two new metal-organic frameworks, Cu-MOF and Pd@Cu-MOF, were prepared with copper(ii) paddlewheel secondary building units, exhibiting microporous structures and BET surface areas of 12 m(2) g(-1) and 33 m(2) g(-1) respectively. Gas adsorption experiments showed low uptake of carbon dioxide due to crystal-to-crystal transformation of the MOFs during activation.

CRYSTENGCOMM (2021)

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Article Chemistry, Inorganic & Nuclear

Dimension Control in Mixed Linker Metal-Organic Frameworks via Adjusting the Linker Shapes

Farnoosh Zarekarizi et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Physical

Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol under Mild Conditions over Zr-MOFs: Exploring the Role of Metal Node Coordination and Modification

Anil H. Valekar et al.

ACS CATALYSIS (2020)

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Article Nanoscience & Nanotechnology

Leveraging Cu/CuFe2O4-Catalyzed Biomass-Derived Furfural Hydrodeoxygenation: A Nanoscale Metal-Organic-Framework Template Is the Prime Key

Paramita Koley et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Inorganic & Nuclear

Palladium(II) Immobilized on Metal-Organic Frameworks for Catalytic Conversion of Carbon Dioxide to Formate

Piwai Tshuma et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Increased Photocatalytic Activity of Post Synthetically Modified Coordination Polymer Derived from Bis-pyridyldiamide

Moyna Das et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

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Article Chemistry, Physical

Deconvoluting the XPS spectra for nitrogen-doped chars: An analysis from first principles

Michael Ayiania et al.

CARBON (2020)

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Article Chemistry, Inorganic & Nuclear

Pd(II) and Pt(II) catalysed selective synthesis of furfuryl alcohol: Solvent effects and insights into the mechanism

Pamela S. Moyo et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Phosphorus-modified zirconium metal organic frameworks for catalytic transfer hydrogenation of furfural

Yue Wang et al.

NEW JOURNAL OF CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Cyclometalation of lanthanum(iii) based MOF for catalytic hydrogenation of carbon dioxide to formate

Piwai Tshuma et al.

RSC ADVANCES (2020)

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Article Chemistry, Multidisciplinary

Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal-Organic Framework

Ali M. Abdel-Mageed et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Physical

Efficient and Selective Ni/Al2O3-C Catalyst Derived from Metal-Organic Frameworks for the Hydrogenation of Furfural to Furfuryl Alcohol

Feng Hu et al.

CATALYSIS LETTERS (2019)

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Article Chemistry, Multidisciplinary

Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal-Organic Frameworks

Deependra M. Shakya et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Base‐Promoted Formation of an Annelated Pyrrolo‐1,4‐oxazine Ensemble from 1 H ‐pyrrol‐2‐ylmethanol and Propargyl Chloride: A Theoretical and Experimental Study

D. Sc. Nadezhda M. Vitkovskaya et al.

ChemPlusChem (2019)

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Article Chemistry, Multidisciplinary

Heterogeneous Nickel Catalysts Derived from 2D Metal-Organic Frameworks for Regulating the Selectivity of Furfural Hydrogenation

Pengfei Guo et al.

ACS OMEGA (2019)

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Article Nanoscience & Nanotechnology

Metal-Organic-Framework-Derived Co/Cu-Carbon Nanoparticle Catalysts for Furfural Hydrogenation

Kristina W. Golub et al.

ACS APPLIED NANO MATERIALS (2019)

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Review Chemistry, Multidisciplinary

Catalytic oxidation of carbohydrates into organic acids and furan chemicals

Zehui Zhang et al.

CHEMICAL SOCIETY REVIEWS (2018)

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Article Chemistry, Inorganic & Nuclear

Highly selective and efficient solvent-free transformation of bio-derived levulinic acid to gamma-valerolactone by Ru(II) arene catalyst precursors

Novisi K. Oklu et al.

INORGANICA CHIMICA ACTA (2018)

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Article Chemistry, Inorganic & Nuclear

1-D and 2-D phosphine coordination materials based on a palladium(II) PCP pincer metalloligand

Junpeng He et al.

POLYHEDRON (2018)

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Article Chemistry, Physical

Homogeneous polymetallic ruthenium(II)∧zinc(II) complexes: robust catalysts for the efficient hydrogenation of levulinic acid to γ-valerolactone

Gershon Amenuvor et al.

CATALYSIS SCIENCE & TECHNOLOGY (2018)

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Article Chemistry, Physical

The Role of Noble Metal Catalysts in Conversion of Biomass and Bio-derived Intermediates to Fuels and Chemicals A review of promising approaches on plant based biomass as a renewable alternative feedstock

Banothile C. E. Makhubela et al.

JOHNSON MATTHEY TECHNOLOGY REVIEW (2018)

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Article Chemistry, Physical

Palladium Niacin Complex Immobilized on Starch-Coated Maghemite Nanoparticles as an Efficient Homo- and Cross-coupling Catalyst for the Synthesis of Symmetrical and Unsymmetrical Biaryls

Elham Rezapour et al.

CATALYSIS LETTERS (2018)

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Review Chemistry, Physical

Catalytic Processes from Biomass-Derived Hexoses and Pentoses: A Recent Literature Overview

Jesus Esteban et al.

CATALYSTS (2018)

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Review Chemistry, Physical

Best Practices for the Synthesis, Activation, and Characterization of Metal-Organic Frameworks

Ashlee J. Howarth et al.

CHEMISTRY OF MATERIALS (2017)

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Article Chemistry, Physical

Metal-organic frameworks derived bimetallic Cu-Co catalyst for efficient and selective hydrogenation of biomass-derived furfural to furfuryl alcohol

Yuan Wang et al.

MOLECULAR CATALYSIS (2017)

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Article Chemistry, Applied

The influence of metal selection on catalyst activity for the liquid phase hydrogenation of furfural to furfuryl alcohol

A. O'Driscoll et al.

CATALYSIS TODAY (2017)

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Article Chemistry, Physical

Facile fabrication of Cu(II)-porphyrin MOF thin films from tetrakis(4-carboxyphenyl) porphyrin and Cu(OH)2 nanoneedle array

Duong Duc La et al.

APPLIED SURFACE SCIENCE (2017)

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Article Chemistry, Multidisciplinary

Lanthanide-Based Coordination Polymers for the Size-Selective Detection of Nitroaromatics

Sumit Srivastava et al.

CRYSTAL GROWTH & DESIGN (2017)

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Review Chemistry, Applied

Metal-organic-framework-based catalysts for hydrogenation reactions

Zhijie Chen et al.

CHINESE JOURNAL OF CATALYSIS (2017)

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Article Chemistry, Applied

One-step conversion of xylose to furfuryl alcohol on sulfated zirconia-supported Pt catalyst-Balance between acid and metal sites

Rafael F. Perez et al.

CATALYSIS TODAY (2017)

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Article Engineering, Environmental

CuNi@C catalysts with high activity derived from metal-organic frameworks precursor for conversion of furfural to cyclopentanone

Yuan Wang et al.

CHEMICAL ENGINEERING JOURNAL (2016)

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Article Chemistry, Multidisciplinary

Preparation and Properties of Metal Organic Framework/Activated Carbon Composite Materials

Ohad Fleker et al.

LANGMUIR (2016)

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Article Multidisciplinary Sciences

Metal-organic frameworks as selectivity regulators for hydrogenation reactions

Meiting Zhao et al.

NATURE (2016)

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Review Chemistry, Multidisciplinary

Bronsted Acidity in Metal-Organic Frameworks

Juncong Jiang et al.

CHEMICAL REVIEWS (2015)

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Article Chemistry, Multidisciplinary

Selective Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of a Recyclable Cobalt/SBA-15 Catalyst

Maite Audemar et al.

CHEMSUSCHEM (2015)

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Article Chemistry, Physical

Selective liquid phase hydrogenation of furfural to furfuryl alcohol by Ru/Zr-MOFs

Qingqing Yuan et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2015)

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Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

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Review Chemistry, Multidisciplinary

Solvent-Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal-Organic Frameworks

Olga Karagiaridi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Article Materials Science, Multidisciplinary

Synthesis, structure and electrochemical behavior of a 3D crystalline copper(II) metal-organic framework

Hong-Ye Bai et al.

FUNCTIONAL MATERIALS LETTERS (2014)

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Review Chemistry, Multidisciplinary

Conversion of biomass platform molecules into fuel additives and liquid hydrocarbon fuels

Maria J. Climent et al.

GREEN CHEMISTRY (2014)

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Article Chemistry, Inorganic & Nuclear

Synthesis and Characterization of Metal-Organic Framework-74 Containing 2, 4, 6, 8, and 10 Different Metals

Lisa J. Wang et al.

INORGANIC CHEMISTRY (2014)

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Article Crystallography

catena-Poly[[[ aquacopper( II)]-bis[μ-N,N'-bis(pyridin-4-yl)isophthalamide]-[aquacopper(II)]-di-μ-sulfato] dimethyl-formamide disolvate]

Er-Peng Zhang et al.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE (2013)

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Article Chemistry, Physical

Liquid phase chemo-selective catalytic hydrogenation of furfural to furfuryl alcohol

Rajesh V. Sharma et al.

APPLIED CATALYSIS A-GENERAL (2013)

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Review Multidisciplinary Sciences

The Chemistry and Applications of Metal-Organic Frameworks

Hiroyasu Furukawa et al.

SCIENCE (2013)

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Article Chemistry, Inorganic & Nuclear

Entangled coordination polymers with mixed N- and O-donor organic linkers: A case of module-matching priority

Li-Wei Han et al.

DALTON TRANSACTIONS (2012)

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Article Chemistry, Physical

Interpenetrated metal-organic frameworks and their uptake of CO2 at relatively low pressures

Qingxia Yao et al.

JOURNAL OF MATERIALS CHEMISTRY (2012)

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Article Chemistry, Inorganic & Nuclear

Thioamide, urea and thiourea bridged rhenium(I) complexes as luminescent anion receptors

Maurice O. Odago et al.

INORGANICA CHIMICA ACTA (2011)

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Article Chemistry, Inorganic & Nuclear

Reversible color changes of metal(II)-N-1,N-3-di(pyridin-4-yl)isophthalamide complexes via desolvation and solvation

Yun Gong et al.

DALTON TRANSACTIONS (2010)

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Article Biochemical Research Methods

Structure validation in chemical crystallography

Anthony L. Spek

ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY (2009)

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Article Chemistry, Multidisciplinary

Metal-organic frameworks derived from bis-pyridyl-bis-amide ligands : Effect of positional isomerism of the ligands, hydrogen bonding backbone, counter anions on the supramolecular structures and selective crystallization of the sulfate anion

N. N. Adarsh et al.

CRYSTENGCOMM (2009)

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Review Green & Sustainable Science & Technology

Biomass-based energy fuel through biochemical routes: A review

R. C. Saxena et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2009)

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Article Chemistry, Multidisciplinary

Three-dimensional porous coordination polymer functionalized with amide groups based on tridentate ligand: Selective sorption and catalysis

Shinpei Hasegawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

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Article Chemistry, Multidisciplinary

An unprecedented twofold interpenetrating (3,4)-connected 3-D metal-organic framework

Seunghee Hong et al.

CHEMICAL COMMUNICATIONS (2007)

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Article Chemistry, Physical

New interpretations of XPS spectra of nickel metal and oxides

Andrew P. Grosvenor et al.

SURFACE SCIENCE (2006)

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Review Chemistry, Applied

Metal-organic frameworks: a new class of porous materials

JLC Rowsell et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2004)

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Article Chemistry, Inorganic & Nuclear

Self-assembly in palladium(II) and platinum(II) chemistry: The biomimetic approach

ZQ Qin et al.

INORGANIC CHEMISTRY (2003)

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Article Chemistry, Inorganic & Nuclear

X-ray photoelectron spectroscopic study of non-stoichiometric nickel and nickel-copper spinel manganites

C Drouet et al.

INTERNATIONAL JOURNAL OF INORGANIC MATERIALS (2000)

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Selective Cu and Ni-MOFs as pre-catalysts for the hydrogenation of furfural to furfuryl alcohol

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