4.8 Review

Colloquium: Quantum anomalous Hall effect

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Robust microscale structural superlubricity between graphite and nanostructured surface

Xuanyu Huang et al.

Summary: This study achieves robust structural superlubricity state between microscale graphite flakes and nanostructured silicon surfaces under ambient conditions. The friction is always less than 1 mu N, the differential friction coefficient is on the order of 10(-4), without observable wear. This is attributed to the edge warping of graphite flake on the nanostructured surface under concentrated force, which eliminates the edge interaction between the graphite flake and the substrate.

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Jin Wang et al.

Summary: A freestanding twisted bilayer graphene (TBG) is unstable below a critical twist angle, accompanied by buckling distortion and collapse of bending rigidity. However, as temperature rises, the bending anomaly fades while the buckling persists. Surprisingly, the electronic properties show a lack of zone boundary splittings due to effective single-valley physics.

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Summary: A comprehensive review on the recent advances in 2D materials and their heterostructures is presented. These materials, discovered through extensive experimental and theoretical efforts, have shown potential applications in high-frequency electronics and broadband optoelectronics. The review focuses on the engineering of 2D heterostructures and 3D-bulk hybrid systems, highlighting their quantum mechanical responses and discussing future trends for electronics and optoelectronics.

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Fluctuation of Interfacial Electronic Properties Induces Friction Tuning under an Electric Field

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Summary: This study investigates the tuning of friction by an electric current in a conductive atomic force microscopy experiment, revealing two main mechanisms: electric-field-induced electron density redistribution and current-induced electron transfer. The proposed electronic level friction model provides theoretical guidance for designing and controlling tribosystems, offering a new perspective in understanding the origin of friction.

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Negative or Positive? Loading Area Dependent Correlation Between Friction and Normal Load in Structural Superlubricity

Kehan Wang et al.

Summary: By conducting molecular dynamics simulations, it has been discovered that friction in structural superlubricity systems can be controlled by modifying the size of the loading area. A theoretical model has been proposed to explain the correlation between the size of the loading area and friction.

FRONTIERS IN CHEMISTRY (2022)

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Robustness of structural superlubricity beyond rigid models

Shizhe Feng et al.

Summary: This study investigates the size dependence of superlubricity between single-crystal graphite flakes. Molecular dynamics simulations show that the friction force is reduced by one order of magnitude through the nucleation and propagation of dislocations and solitons. Theoretical models are developed to illustrate and predict the interfacial elastoplastic behaviors.

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LAMMPS-a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales

Aidan P. Thompson et al.

Summary: LAMMPS, a classical molecular dynamics simulator released as an open source code in 2004, has gained popularity for its wide variety of particle interaction models, platform compatibility, and user control over simulation details. With contributions from numerous developers, it has grown from 50,000 lines of code to a million today, showcasing new capabilities like dynamic load balancing and quantum-accuracy machine learning interatomic potentials.

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UItra-low friction and edge-pinning effect in large-lattice-mismatch van der Waals heterostructures

Mengzhou Liao et al.

Summary: MoS2/graphite and MoS2/h-BN interfaces exhibit ultra-low friction coefficients, with edges and interface steps being the main contributors to friction forces; two-dimensional heterostructures offer twist-angle-independent ultra-low friction due to weak interlayer van der Waals interactions and natural lattice mismatch, but the effects of domain edges on friction processes in finite-size interfaces remain unclear.

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Domino-like stacking order switching in twisted monolayer-multilayer graphene

Shuai Zhang et al.

Summary: In this study, two metastable reconstruction states with distinct stacking orders and strain soliton structures were identified in small-angle twisted graphene using conductive atomic force microscopy. The switching mechanism between these two states was found to propagate spontaneously in a domino-like fashion. The fine structure of the bistable states is critical for understanding the unique properties of van der Waals structures with tiny twists.

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100 km wear-free sliding achieved by microscale superlubric graphite/DLC heterojunctions under ambient conditions

Deli Peng et al.

Summary: This study reports experimental observations of wear-free sliding for a micrometer-sized graphite flake on a diamond-like-carbon (DLC) surface, achieving ultra-low coefficients of friction (COFs) of the order of 10 (-3). The underlying mechanism is revealed to be the combination of interfacial van der Waals (vdW) interaction, atomic-smooth interfaces, and the low normal stiffness of the graphite flake. The results broaden the scope of superlubricity and promote its wider application in the future.

NATIONAL SCIENCE REVIEW (2022)

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Structural superlubricity with a contaminant-rich interface

Kunqi Wang et al.

Summary: This paper experimentally demonstrates the occurrence of structural superlubricity with a contaminant-rich interface, and finds that contaminants can increase the friction of an incommensurate contact and decrease the friction of a commensurate contact, challenging the current understanding of the mechanism of structural superlubricity.

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Stick-Slip Dynamics of Moir′e Superstructures in Polycrystalline 2D Material Interfaces

Xiang Gao et al.

Summary: A new frictional mechanism based on collective stick-slip motion of moire superstructures across polycrystalline two-dimensional material interfaces is predicted. This phenomenon is expected to occur in various large-scale layered material interfaces, such as h-BN/graphene.

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Moire-Pattern Evolution Couples Rotational and Translational Friction at Crystalline Interfaces

Xin Cao et al.

Summary: Compared to translational friction, rotational friction has received less attention. In this study, we experimentally and theoretically investigate the rotational depinning and orientational dynamics of two-dimensional colloidal crystalline clusters on periodically corrugated surfaces under the influence of magnetically exerted torques. Our results show that the traversal of locally commensurate areas of the moiré pattern through the edges of clusters, hindered by potential barriers during cluster rotation, controls its rotational depinning. The experimentally measured depinning thresholds collapse onto a universal theoretical curve, suggesting the possibility of a superlow-statictorque state for large clusters. We also find a cluster-size-independent rotation-translation depinning transition when lattice-matched clusters are driven jointly by a torque and a force.

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Sliding Friction and Superlubricity of Colloidal AFM Probes Coated by Tribo-Induced Graphitic Transfer Layers br

Renato Buzio et al.

Summary: This study investigates sliding friction phenomena in graphite contacts using colloidal probe atomic force microscopy (AFM). The results show that after the formation of a transfer layer, friction depends on the energy landscape experienced by the topographically highest tribo-induced nanoasperity.

LANGMUIR (2022)

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A first-principles study on the superlubricity of two-dimensional graphene/ZrS2 heterostructure

Peipei Xu et al.

Summary: Understanding and controlling nano friction is crucial for the practical application of nanotechnology. In this study, electronic structures and atomic-scale friction of the graphene/ZrS2 heterostructure were simulated using first-principles calculations. The results showed that the graphene/ZrS2 structure has lower friction force and coefficient compared to other structures, making it a potential direction for designing new lubricant materials with reduced friction.

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Superconductivity, superfluidity and quantum geometry in twisted multilayer systems

Paivi Torma et al.

Summary: This article introduces the impact of quantum geometry on superconductivity and superfluidity in flat-band systems such as twisted graphene. It also compares ultracold gases as a complementary platform and discusses the prospects of twisted multilayer systems in achieving room-temperature superconductivity.

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Rotational Friction Correlated with Moire Patterns in Strained Bilayer Graphene: Implications for Nanoscale Lubrication

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Summary: This study investigates the rotational friction between graphene layers using molecular dynamics simulations, revealing that the emergence of Moire patterns can lead to superlubricity. Further analysis shows that the incommensurate interface of Moire patterns can tune the local energy, resulting in ultralow interlayer energy barriers. Adjusting the size of Moire patterns to match that of graphene flakes can significantly reduce torque in bilayer systems with biaxially stretched substrates.

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Infinite Approaching Superlubricity by Three-Dimensional Printed Structures

Yu Zhao et al.

Summary: The rapid development of 3D printing technology has provided great opportunities for designing various multiscale lubrication structures. Recent research has focused on constructing multifunctional 3D structures with refined dimensions, from micronanoscale to macroscale, to approach superlubricity. Emphasis is placed on the design, lubrication performance, material requirements, merits, drawbacks, and applications of various 3D printing techniques for structural lubrication.

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Graphite superlubricity enabled by triboinduced nanocontacts

Renato Buzio et al.

Summary: This study investigates the frictional response of micrometric silica beads sliding on graphite under ambient conditions using colloidal probe atomic force microscopy. The experiment reveals that tribotransferred graphene flakes act as lubricious nanoasperities, reducing the true contact area and governing mechanical dissipation. The load-driven atomic-scale transition from superlubric sliding to stick-slip behavior is consistent with the Prandtl-Tomlinson model.

CARBON (2021)

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Superior lubrication and electrical stability of graphene as highly effective solid lubricant at sliding electrical contact interface

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Summary: Graphene as a solid lubricant at electrical contact interfaces exhibits ultra-low friction, ultra-high current stability, and effective wear resistance.

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Registry-Dependent Potential for Interfaces of Gold with Graphitic Systems

Wengen Ouyang et al.

Summary: A semi-anisotropic interfacial potential (SAIP) has been proposed to describe the interaction between gold and 2D carbon allotropes. The potential accurately reproduces DFT+D3 calculations for graphene, benzene, and C-60 fullerene adsorbed on the Au(111) surface, showing a noticeable improvement in the state-of-the-art description of Au-C interfaces. Its functional form is also suitable for describing interfacial interactions between other 2D and bulk materials.

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Tunable strongly coupled superconductivity in magic-angle twisted trilayer graphene

Jeong Min Park et al.

Summary: Moire superlattices have become a platform for studying correlated physics and superconductivity with unprecedented tunability. This study on magic-angle twisted trilayer graphene reveals a better tunability of electronic structure and superconducting properties than magic-angle twisted bilayer graphene, with implications for the understanding of strongly coupled superconductivity. The results suggest that the system can be electrically tuned close to the crossover to a two-dimensional Bose-Einstein condensate, indicating the potential for revolutionizing applications of superconductivity.

NATURE (2021)

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Superlubric polycrystalline graphene interfaces

Xiang Gao et al.

Summary: The investigation of corrugated grain boundaries on the frictional properties of extended planar graphitic contacts reveals a nonmonotonic behavior in friction due to dynamic buckling effects. The resulting negative differential friction coefficients can reduce linear scaling of grain-boundary friction with surface area and restore structural superlubricity at increasing length scales. Achieving ultra-low friction at macroscopic scales is highly desirable.

NATURE COMMUNICATIONS (2021)

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Strain fields in twisted bilayer graphene

Nathanael P. Kazmierczak et al.

Summary: Twisted bilayer graphene exhibits two-regime reconstruction mechanics based on twist angle, with applied heterostrain accumulating anisotropically in saddle-point regions to generate distinctive striped strain phases. Nanoscale spatial fluctuations in twist angle and uniaxial heterostrain were statistically evaluated, revealing the prevalence of short-range disorder in moire heterostructures. This study provides insights into the twist-angle-dependent electronic behavior and structural relaxation, disorder, and strain in moire materials.

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Microscale Schottky superlubric generator with high direct-current density and ultralong life

Xuanyu Huang et al.

Summary: The article introduces a microscale generator - the Schottky superlubric generator (S-SLG), which can generate high current and power densities while maintaining stable high electrical current density over a long lifetime. Experimental results demonstrate the enduring and virtually unlimited persistence of the S-SLG.

NATURE COMMUNICATIONS (2021)

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Computational Prediction of Superlubric Layered Heterojunctions

Enlai Gao et al.

Summary: This study proposes criteria for predicting superlubricity between heterojunctions based on in-plane stiffness requirements of layered materials and interfacial interactions. By screening first-principles calculation data, 61 heterojunctions with potential superlubricity features were identified out of 208 candidates, providing a universal route for accelerating the discovery of new superlubric heterojunctions.

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Directional anisotropy of friction in microscale superlubric graphite/hBN heterojunctions

Yiming Song et al.

Summary: In this study, the dependence of friction on sliding directions in microscale heterogeneous contacts between single crystalline hBN and graphite is experimentally examined. The results demonstrate the consistency of microscale superlubric translational motion along all sliding directions, with frictional anisotropy resulting from changes in the corrugation of the sliding potential energy surface. These findings validate the robustness of structural superlubricity against sliding directions and offer an effective approach to precise friction control.

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Zhanghui Wu et al.

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Periodic overlayers and moire patterns: theoretical studies of geometric properties

Klaus Hermann

JOURNAL OF PHYSICS-CONDENSED MATTER (2012)

Article Chemistry, Multidisciplinary

Shear Modulus of Monolayer Graphene Prepared by Chemical Vapor Deposition

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NANO LETTERS (2012)

Article Chemistry, Physical

Observation of kinks and antikinks in colloidal monolayers driven across ordered surfaces

Thomas Bohlein et al.

NATURE MATERIALS (2012)

News Item Chemistry, Physical

COLLOIDAL FRICTION Kinks in motion

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NATURE MATERIALS (2012)

Article Chemistry, Physical

The shear mode of multilayer graphene

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NATURE MATERIALS (2012)

Article Materials Science, Multidisciplinary

Interlayer binding energy of graphite: A mesoscopic determination from deformation

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PHYSICAL REVIEW B (2012)

Article Physics, Multidisciplinary

Observation of Microscale Superlubricity in Graphite

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PHYSICAL REVIEW LETTERS (2012)

Article Engineering, Chemical

Collective Effects at Frictional Interfaces

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TRIBOLOGY LETTERS (2012)

Article Chemistry, Multidisciplinary

Growth Mechanism of Hexagonal-Shape Graphene Flakes with Zigzag Edges

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ACS NANO (2011)

Article Nanoscience & Nanotechnology

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NANOTECHNOLOGY (2011)

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Velocity dependence of kinetic friction in the Prandtl-Tomlinson model

Martin H. Mueser

PHYSICAL REVIEW B (2011)

Article Engineering, Chemical

Analytical Models for Atomic Friction

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TRIBOLOGY LETTERS (2011)

Review Physics, Applied

Physics of ice friction

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JOURNAL OF APPLIED PHYSICS (2010)

Article Chemistry, Multidisciplinary

Localization of Dirac Electrons in Rotated Graphene Bilayers

G. Trambly de laissardiere et al.

NANO LETTERS (2010)

Article Chemistry, Physical

Ballistic nanofriction

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NATURE MATERIALS (2010)

Article Materials Science, Multidisciplinary

Parameter-free dissipation in simulated sliding friction

A. Benassi et al.

PHYSICAL REVIEW B (2010)

Article Materials Science, Multidisciplinary

Topological defects in graphene: Dislocations and grain boundaries

Oleg V. Yazyev et al.

PHYSICAL REVIEW B (2010)

Article Multidisciplinary Sciences

Frictional Characteristics of Atomically Thin Sheets

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SCIENCE (2010)

Review Chemistry, Multidisciplinary

Graphene: The New Two-Dimensional Nanomaterial

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Article Physics, Condensed Matter

Atomistic simulations of the sliding friction of graphene flakes

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EUROPEAN PHYSICAL JOURNAL B (2009)

Article Physics, Multidisciplinary

Friction and Dissipation in Epitaxial Graphene Films

T. Filleter et al.

PHYSICAL REVIEW LETTERS (2009)

Article Physics, Multidisciplinary

Quasi-Free-Standing Epitaxial Graphene on SiC Obtained by Hydrogen Intercalation

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PHYSICAL REVIEW LETTERS (2009)

Article Physics, Multidisciplinary

Torque and twist against superlubricity

Alexander E. Filippov et al.

PHYSICAL REVIEW LETTERS (2008)

Article Chemistry, Physical

The rise of graphene

A. K. Geim et al.

NATURE MATERIALS (2007)

Article Multidisciplinary Sciences

The breakdown of continuum models for mechanical contacts

BQ Luan et al.

NATURE (2005)

Article Physics, Fluids & Plasmas

Thermally induced suppression of friction at the atomic scale

SY Krylov et al.

PHYSICAL REVIEW E (2005)

Article Physics, Multidisciplinary

Structural lubricity:: Role of dimension and symmetry

MH Müser

EUROPHYSICS LETTERS (2004)

Article Physics, Multidisciplinary

Superlubricity of graphite

M Dienwiebel et al.

PHYSICAL REVIEW LETTERS (2004)

Article Chemistry, Physical

Frictional forces and Amontons' law: From the molecular to the macroscopic scale

JP Gao et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2004)

Article Multidisciplinary Sciences

Direct evidence for atomic defects in graphene layers

A Hashimoto et al.

NATURE (2004)

Article Physics, Multidisciplinary

Nonmonotonic velocity dependence of atomic friction

P Reimann et al.

PHYSICAL REVIEW LETTERS (2004)

Article Multidisciplinary Sciences

Bonding changes in compressed superhard graphite

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SCIENCE (2003)

Article Physics, Multidisciplinary

Interaction potential and hopping dynamics governing sliding friction

E Riedo et al.

PHYSICAL REVIEW LETTERS (2003)

Article Chemistry, Physical

Dynamic force spectroscopy: a Fokker-Planck approach

OK Dudko et al.

CHEMICAL PHYSICS LETTERS (2002)

Article Physics, Condensed Matter

A second-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons

DW Brenner et al.

JOURNAL OF PHYSICS-CONDENSED MATTER (2002)

Article Physics, Multidisciplinary

Multiwalled carbon nanotubes as gigahertz oscillators

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PHYSICAL REVIEW LETTERS (2002)

Article Engineering, Mechanical

On the nature of tribological contact in automotive brakes

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Article Physics, Multidisciplinary

Thermal effects on atomic friction -: art. no. 174301

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PHYSICAL REVIEW LETTERS (2001)

Article Physics, Multidisciplinary

Simple microscopic theory of Amontons's laws for static friction

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PHYSICAL REVIEW LETTERS (2001)

Article Physics, Multidisciplinary

Onset of sliding friction in incommensurate systems

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PHYSICAL REVIEW LETTERS (2000)

Article Chemistry, Physical

A reactive potential for hydrocarbons with intermolecular interactions

SJ Stuart et al.

JOURNAL OF CHEMICAL PHYSICS (2000)

Article Physics, Multidisciplinary

Velocity dependence of atomic friction

E Gnecco et al.

PHYSICAL REVIEW LETTERS (2000)