Selective synthesis of two-dimensional semiconductive coordination polymers with silver-sulfur network

Two-dimensional Ag(i) coordination polymers containing a sulfur coordination atom, [Ag(tzdt)](n) (KGF-24), and [Ag(tzdt)(TFA)](n) (KGF-25) (Htzdt = 1,3-thiazolidine-2-thione, TFA = trifluoroacetate), were synthesized and characterized. Time-resolved microwave conductivity measurements and first-principles calculations revealed that KGF-24 and KGF-25 exhibit charge mobility along their (-Ag-S-)(n) network.

Automated summary

Two-dimensional Ag(i) coordination polymers with a sulfur coordination atom, KGF-24 and KGF-25, were synthesized and characterized. Time-resolved microwave conductivity measurements and first-principles calculations showed that they exhibit charge mobility along their (-Ag-S-)(n) network.